• Title/Summary/Keyword: 전기삼투압

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향류식 역삼투 농축공정을 이용한 NaCl 용액의 농축연구

  • 조한욱
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.04b
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    • pp.3-10
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    • 1997
  • 제염농축공정은 증류, 증발법을 일반적으로 사용하나, 에너지 절약차원에서 전기투석 (Electro dialysis)장치를 증발기 선단에 도입한 복합공정을 국내에서도 사용하고 있는 실정이다. 그러나, 전기투석장치는 전기적인 소모와 막의 재생, 교체처리비가 문제점이 되므로 역삼투 장치를 제염농축 공정 최선단에 도입한 복합공정을 이용할 경우 전기 투석 및 증발 복합공정에 비해 40%의 에너지 절감 효과를 기대할 수 있다. 이와 같은 장점에도 불구하고 역삼투 공정은 공급용액의 삼투압보다 큰 적용압력을 막표면에 가하여 물질분리를 수행하므로 농축공정에서 유발되는 배제액 농도의 상승은 삼투압의 증가를 일으켜 실적적용압력의 효과를 떨어뜨리게 되며 결과적으로 농축효과를 감소시키게 된다. 본 연구에서는 효과적인 염농축 공정을 위하여 막모듈 투과부에 고농도 삼투압 감소액(osmotic sink solution)을 향류식(막투과흐름을 맞받아치며 흐르는 방식)으로 유입시키는 향류식 역삼투 (counter-current reverse osmosis, CCRO) 나권형 모듈을 고안 제작하였으며, 제작된 모듈을 기존 역삼투 공정과 향류식 염삼투 공정에 적용하여 염농축도의 성능을 상호 비교하고 염농축에 관계되는 공급농도, 공급유량, 투과유량, 배제유량, 향류 유입유량, 압력구배, 삼투압차 및 농축단수 등의 인자들을 이용하여 두 공정에 대한 염농축 분리조작의 제반조건과 제작된 모듈 내의 농축관련 특성을 실험 및 수치적으로 비교, 고찰하였다.

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Development of Osmotic Infusion Pump (삼투압 약물주입 펌프의 개발)

  • Kim, Dong Sun;Choi, Seong Wook
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.6
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    • pp.471-475
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    • 2015
  • Because of increasing demand, a small portable drug injector that uses osmotic pressure for its operation force is developed, and its performance is evaluated. The osmotic drug injector can be small and lightweight because it does not require heavy batteries and an actuator, unlike previous electromechanical drug injectors. Moreover, its injection pressure can be sustained longer than that of previous elastic drug injectors. The new device is composed of a drug sac, osmotic pressure chamber, semipermeable membrane, and solvent chamber. To evaluate its performance, an in-vitro experiment was designed to measure the outflow and the injection pressure with respect to time. The experimental results show that the new drug infuser can continuously deliver 20 ml drug over a period of 20 h. The maximum injecting pressure was over 400 mmHg. Which prevents backflow caused by changes in the outlet pressure resulting from changes to the position of the device and the patient's posture.

Electrochemical Characteristics of Fine Soils in the Application of Electrokinetic Remediation (동전기력 복원공정 적용에 따른 세립토양의 전기화학적 특성 변화)

  • 고석오
    • Journal of Soil and Groundwater Environment
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    • v.7 no.3
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    • pp.85-94
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    • 2002
  • Overall objective of this study was to evaluate the electrochemical characteristics of fine soils during the electrokinetic(EK) remediation. Zeta potential of kaolinite as a function of solution pH and surfactant concentration was investigated to make a relationship with electroosmotic flow direction and rate. During the EK experiments, pH of pore solution, electroosmotic permeability($k_e$), electric conductivity($\delta_e$) and voltage distribution was measured, respectively, The point of zero charge(PZC) of kaolinite was estimated to be about 4.2 and the zeta potential of kaolinite above PZC was more negative as solution pH increased. Sorption of surfactants on the kaolinite altered the zeta potential of kaolinite. resulting from the variation of electrochemical characteristics of kaolinite surface. hs the EK experiment progressed, low pH was predominant over most of the kaolinite specimen and thus resulted in very low mass and charge flow. The $k_e$ and $\delta_e$ was also affected by the variation of voltage drop across the EK column with time. Results from this study implied that zeta potential of kaolinite affected by the pH variation of pore solution and voltage distribution in soil column played important role in the determination of mass and charge flow during EK process. It was also suggested that pH adjustment or addition of suitable sorbates could alter the electrochemical characteristics of soil surface and thus maintain high mass and charge flow rate with time.

Change in Protein and Carbohydrate Contents in Diapausing and Non-diapausing Pupae of the Oriental Tobacco Budworm, Heliothis assulta Guenee (담배나방 휴면용과 비휴면용의 단백질과 탄수화물의 변화)

  • 조국호;부경생
    • Korean journal of applied entomology
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    • v.29 no.4
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    • pp.286-293
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    • 1990
  • Studies were carried out to investigate the change in protiens and carbohydrates from diapausing pupae of the Oriental tobacco budworm, Heliothis assulta Guenee. The oxygen consumption rate of non-diapausing pupae through the whole pupal period showed an U-shaped curve, while that of diapausing pupae decreased to a mean level of 20$\mu$1/g/hr. But the rate of oxygen consumption increased in diapausing pupae before their emergence. The body weight of diapausing pupae showed almost no change during 12 days after pupation. The total contents of major carbohydrates and soluble proteins were higher in diapausing pupae than those in non-diapausing pupae and the change in carbohydrate and protein contents was more dynamic in non-diapausing pupae than that of diapausing pupae. the electrophoretic band patterns of proteins were similar in both of diapausing and non-diapausing pupae. Diapausing pupae increased their haemolmph osmolarity further when they were exposed to low temperatures.

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Stomach Cancer Cell Lysis in PBS with Conductivity and Osmotic-Pressure Control (용액 전도도 및 삼투압 조절된 PBS에서의 위암 세포 전기 분해)

  • Kim, Min-Soo;Lee, Kook-Nyung;Cho, Su-Hyung;Kim, Byung-Gee;Kim, Yong-Kweon
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.2137-2139
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    • 2004
  • Cancer cell lysis at pulsed DC is realized using micromachined electrodes. In this research, quantitative analyses are performed on cell lysis results. The cell volume increasing at the pulses applied are analyzed in different medium conditions on osmotic pressure and conductivity, and the cell lysis procedures are studied in detail experimentally. Phosphate buffered saline (PBS) is used as the medium. To change the conductivity of PBS, NaCl concentration of PBS is adjusted, and inositol is used with PBS to control the effects of the osmotic pressure to cell lysis performance.

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MXene Based Composite Membrane for Water Purification and Power Generation: A Review (정수 및 발전을 위한 맥신(MXene) 복합막에 관한 고찰)

  • Seohyun Kim;Rajkumar Patel
    • Membrane Journal
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    • v.33 no.4
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    • pp.181-190
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    • 2023
  • Wastewater purification is one of the most important techniques for controlling environmental pollution and fulfilling the demand for freshwater supply. Various technologies, such as different types of distillations and reverse osmosis processes, need higher energy input. Capacitive deionization (CDI) is an alternative method in which power consumption is deficient and works on the supercapacitor principle. Research is going on to improve the electrode materials to improve the efficiency of the process. A reverse electrodialysis (RED) is the most commonly used desalination technology and osmotic power generator. Among many studies conducted to enhance the efficiency of RED, MXene, as an ion exchange membrane (IEM) and 2D nanofluidic channels in IEM, is rising as a promising way to improve the physical and electrochemical properties of RED. It is used alone and other polymeric materials are mixed with MXene to enhance the performance of the membrane further. The maximum desalination performances of MXene with preconditioning, Ti3C2Tx, Nafion, and hetero-structures were respectively measured, proving the potential of MXene for a promising material in the desalination industry. In terms of osmotic power generating via RED, adopting MXene as asymmetric nanofluidic ion channels in IEM significantly improved the maximum osmotic output power density, most of them surpassing the commercialization benchmark, 5 Wm-2. By connecting the number of unit cells, the output voltage reaches the point where it can directly power the electronic devices without any intermediate aid. The studies around MXene have significantly increased in recent years, yet there is more to be revealed about the application of MXene in the membrane and osmotic power-generating industry. This review discusses the electrodialysis process based on MXene composite membrane.

Simulation and Validation of Methanol Crossover in DMFCs (직접메탄올 연료전지의 메탄올 크로스오버에 대한 시뮬레이션 및 검증)

  • Ko, Johan;Ju, Hyunchul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.126.1-126.1
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    • 2010
  • In direct methanol fuel cells(DMFCs), it is well known that methanol crossover severely reduces the cell performance and the cell efficiency. There are a number of design and operating parameters that influence the methanol crossover. This indicates that a DMFC demands a high degree of optimization. For the successful design and operation of a DMFC system, a better understanding of methanol crossover phenomena is essential. The main objective of this study is to examine methanol-crossover phenomena in DMFCs. In this study, 1D DMFC model previously developed by Ko et al. is used. The simulation results were compared with methanol-crossover data that were measured by Eccarius et al. The numerical predictions agree well with the methanol crossover data and the model successfully captures key experimental trends.

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Efficient Dewatering of the Sewage Sludge by Electrodewatering System (전기탈수방법에 의한 하수 슬러지 탈수 특성)

  • Park, Chan-Jung;Lee, Jung-Eun;Ahn, Young-Chull;Shin, Hee-Soo;Lee, Jae-Keun
    • Proceedings of the KSME Conference
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    • 2000.11b
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    • pp.526-531
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    • 2000
  • Application of electrodewatering (EDW) to mechanical dewatering system was studied to decrease water content in the sludge generated from waste water treatment process. Experiments realized the reduction of water content in the sewage sludge. EDW enhancing the conventional filtration by an electric field is an emerging technology with the potential to improve dewatering. In this study, a piston filter press was constructed, the digested sludges were dewatered by EDW under conditions of DC electric field and constant pressure in the piston filter press. Constant electric field from $0{\sim}120\;V/cm$ and constant pressure $98.1{\sim}392.4\;kPa$ were used. The results showed that as electric field was increased the dewatering rates increased and as pressure was increased the dewatering rates decreased. Also as polymer was added the dewatering rates increased. This experiments produced final sludge cake with water content of 60 wt% using EDW, compared with 80 wt% using pressure filtration alone.

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The Study on permeability enhancement in smear zone using electro-osmotic pressure (전기 삼투압을 이용한 교란영역의 투수성 개선에 관한 연구)

  • Ahn, Byung-Wook;Noh, Hee-Jeon;Kim, Hyun-Ki;Cho, Nam-Jun
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.435-441
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    • 2008
  • More time is required for consolidating soft clay when its hydraulic conductivity around the vertical drains is reduced by soil disturbance. One of the methods to be proposed to solve such problem is the electro-osmotic flow application. This study presents the experimental results of model tests using a modified oedometer and a large-scale cylinder with a sand drain. Results show that the development of negative excessive pore water pressure due to the DC electrical field in saturated clay can be transformed to additional loads causing more consolidation settlement.

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Soft Ground Improvement using Electrokinetic Geosynthetics (복합동전기토목섬유를 이용한 연약지반개량)

  • Lee, Myung-Ho;Han, Jung-Geun;Lee, Jai-Young
    • Journal of the Korean Geosynthetics Society
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    • v.6 no.3
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    • pp.25-30
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    • 2007
  • The major reason to employ electrokinetic geosynthetics is to take advantage of its ability to densify very low permeability materials in shorter time periods than ordinary seepage consolidation. A number of laboratory scale experiments was carried out with acrylic column using natural clayey soil. The testing results indicate that (1) the electrically induced settlement was faster than the gravitational one, (2) the higher the voltage, the faster the dewatering but the less final settlement, and (3) the pH extended as low as 3 in the anode section and as high as 11 near the cathode.

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