• Title/Summary/Keyword: 전기변색

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Effect of concentration of H2SO4 on electrochemical properties of equipped Al sacrificial anode to prevent the corrosion and discolor of silver surface (은의 표면 부식 및 변색을 방지하기 위해 설치된 Al 희생양극의 전기화학적 특성에 미치는 황산 농도의 영향)

  • Shin, Byung-Hyun;Chung, Won-Sub
    • Journal of the Korean institute of surface engineering
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    • v.54 no.1
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    • pp.12-17
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    • 2021
  • Among the various precious metals, silver is used in various fields because of its low price than other precious metals. However, the surface of silver remains after rain in the atmosphere containing sulfur ions and chlorine ions, causing silver corrosion and discoloration. Existing documents have developed a anode to prevent corrosion but that are concentrated on secondary batteries. This study tried to prevent corrosion and discoloration of silver by using an Al sacrificial anode. Sulfuric acid decreased the potential of silver and increased the current density at active polarization and OCP. The amount of corrosion of silver with the Al sacrificial anode was reduced from 0.5 % to 6.5%. When silver is used for decoration outside, corrosion and discoloration of silver can be suppressed by installing an Al anode.

Experimental study for removing silver sulfide from silver objects by Nd:YAG laser cleaning (은제품의 황화은 부식층 제거를 위한 Nd:YAG 레이저클리닝 실험 연구)

  • Lee, Hyeyoun;Cho, Namchul
    • Journal of Conservation Science
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    • v.30 no.1
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    • pp.95-101
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    • 2014
  • Silver objects tarnish with black from reaction with sulfurous acid or hydrogen sulfide of atmospheric. Blackening of silver objects results from formation of silver sulfide($Ag_2O$) on the surface. Silver sulfide usually is usually removed by conservation treatment. There are several cleaning methods such as chemical, electrochemical and micro-abrasion cleaning, but all of them consume silver. This study investigated the safe and effective parameter of laser cleaning by test on silver coupons. Laser cleaning is a selective process for the removal of specific substances. At first, laser cleaning applied to plain silver coupons, which were not corroded, to find out the safe range of laser energy density. From results, plain silver coupons were not changed at 1064nm below $4.00J/cm^2$ and at 532nm below $2.39J/cm^2$. The corrosion layer(silver sulfide) of artifical corroded silver coupons was removed at 1064nm with $2.39J/cm^2$ by 5~10 pulses and at 532nm with $1.19J/cm^2$ by 5~10 pulses. The removal thickness of corrosion layer was about 13-25nm per a laser pulse using AES analysis. In addition, laser cleaning tested the tarnish silver rings based on the results of silver coupons. As a result of test, the black surface were clean successfully and gave luster of silver, which showed the application possibility of laser cleaning for silver objects.

A Studies on the Characteristics of Reliability Test by Automotive Touch Screen Silver Pastes (자동차 터치스크린용 실버페이스트 종류에 따른 신뢰성 테스트 특성 연구)

  • Kim, Jung-won;Choi, Ung-se
    • Journal of IKEEE
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    • v.20 no.2
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    • pp.205-208
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    • 2016
  • In this paper, different types of touch screen silver pastes for bonding in conductive pattern formed over the ito film by bonding each sample of 5 was dried. The dry conditions, the oxidation of the ito film is a condition that does not occur. Reliability testing constant temp and humidity, cold-hot impact test is in progress. Each test will check the status of five sheets conductive pattern bonding. Conductive pattern bonding, after each 240,480,615 hours to check the status of silver pattern bonding. Reliability testing these through different silver pastes can see that the change in the adhesion and conductivity deterioration of the quality can be prevented, and reliability testing low temperature curing from the surface of silver pastes that can come as soon as the discoloration was unknown.

The Properties of Dielectric Breakdown and Thermal Stresses below 22.9[kV] Class XLPE Power Cable (22.9[kV]이하 XLPE 전력케이블의 열 충격 시험 및 절연파괴 특성)

  • Kim, Young-Seok;Shong, Kil-Mok;Kim, Sun-Gu
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.4
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    • pp.54-60
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    • 2008
  • It is impossible to database(DB) the patterns of power cable events and cause analysis of faulted cable because the product liability(PL) law have been enforced in Korea, since 2002. In additions, simulation and pattern of power cable events are needed for DB system under accelerated deterioration. In this paper, we tested for resistance to cracking of cable below the 22.9[kV] class due to thermal stresses. This method of exam is following IEC 60811-3-1(Common test methods for insulating and sheathing materials of electric cables). From the results, The 22.9[kV] class A power cable was discolored on the surface and significantly reduced in the longitudinal direction. As the thermal weight properties of A power cable was definitely varied, we are able to guess the problem of manufacture. If the cable was defect by the manufacture, the victims would be able to claim for damage in the PL system.

The development of pH reading system based on vision system (영상 기반 pH 산도 측정 시스템 개발)

  • Moon, Ha-Jung;Lee, Dong-Hoon
    • Journal of IKEEE
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    • v.17 no.4
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    • pp.398-406
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    • 2013
  • Nuclear medicine imaging devices such as PET diagnose disease after injecting radiopharmaceuticals in human body for diagnosis. Radiopharmaceuticals should maintain the proper pH for human body safety. In general, pH paper is used to measure the pH of the radiopharmaceutical. pH of the sample compared with the standard color chart is used for measurement. However, the pH reading difference according to the experience of a rater can be generated. Also, a pH meter for measuring pH has a high sensitivity and contamination of the sensor must be avoided. In this paper, we developed the new hardware device for pH reading method and software was developed with vision algorithm to measure pH easily and simply.

Analysis of Coloring Degree of a Dental Bracket by Optical Sensor (광 소자를 이용한 치과용 브라켓의 착색 정도 연구)

  • Lee, Eun-Suk;Kim, Ji-Sun;Oh, Han-Byeol;Kim, A-Hee;Kim, Jun-Sik;Goh, Bong-Jun;Baek, Jin-Young;Shin, Ye-Ji;Jun, Jae-Hoon
    • Proceedings of the KIEE Conference
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    • 2015.07a
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    • pp.1407-1408
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    • 2015
  • 현재에는 과거와 달리 표면상 비춰지는 외모의 중요성이 강조되어 치아 교정을 해서 미적 욕구를 충족시키려는 사람들이 증가하고 있다. 특히나 치아를 교정할 때 사용되는 치아교정용 브라켓은 부착되는 위치가 치아 앞면이기 때문에 미관상의 중요성은 치아교정장치 중 가장 크다. 이러한 이유 때문에 미적인 부분을 고려하여 치아색과 유사한 브라켓이 개발되었는데, 이 브라켓은 레진 브라켓이다. 이는 치아 교정에 도움을 주면서 심미성이 우수한 장점이 있지만 음식을 섭취할 때 음식의 색소에 의해 브라켓의 색 변화가 일어난다는 단점이 있다. 본 연구에서는 사람들이 자주 섭취하는 음식이나 음료에 치아교정용 브라켓을 착색시켜 색이 변하는 정도의 차이를 컬러센서를 이용해 측정하였다. 이렇게 측정된 브라켓의 RGB 값은 객관적이고 정량적인 값을 나타낼 수 있다. 이는 브라켓의 변색 뿐만 아니라 치아 미백 치료에도 적용되어 사용될 수 있을 것이다.

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Electrochromic Properties on $\textrm{MoO}_3$ Thin Films with Heat Treatment ($\textrm{MoO}_3$ 박막의 열처리 효과에 따른 일렉트로크로믹 특성)

  • Jo, Bong-Hui;Kim, Yeong-Ho
    • Korean Journal of Materials Research
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    • v.9 no.11
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    • pp.1144-1147
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    • 1999
  • The effect of the heat treatment on electrochromic properties of $\textrm{MoO}_3$ thin films is investigated by studing optical modulation, optical density, response time, and cyclic voltammetry. From the results of XRD analysis, heat-treated at $450^{\circ}C$ in air for 1 hour Moo3 thin films are found to be crystalline while as-deposited and heat- treated at low temperature ($\leq\;300^{\circ}C$) film are amorphous. The electrochromic devices using as-deposited $\textrm{MoO}_3$ films exhibit good electrochromic properties compared to those using the heat treated $\textrm{MoO}_3$ films. It has shown that the heat-treatment affected the reversible color change and the electrochromic properties of $\textrm{MoO}_3$ films.

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Studies on the properties of electrochromic films and the effect of migration barrier (Electrochromic 막의 특성과 물질이동 방지막의 효과에 대한 연구)

  • 황하룡;백지흠;허증수;이덕동;임정옥;장동식
    • Journal of the Korean Vacuum Society
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    • v.9 no.3
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    • pp.221-226
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    • 2000
  • After manufacturing the electrochromic device (structure: ITO glass/$WO_3$/electrolyte/$V_2O_5$/ITO;glass) by using of sol-gel process and evaporation, optical properties and migration effect were investigated. The result shows that electrochromic device with heat treated (at water vapor ambient, $500^{\circ}C$, 1 hour) sol-gel coated $WO_3$ and $V_2O_5$ films had the highest transmittance variance. Electrochromic devices are based on the reversible insertion of guest atoms into structure of the host solid. But after cyclic operation, we find that the tungsten in $WO_3$ film and the indium in ITO film were migrated with each other. For the purpose of blocking migration, tungsten barrier film is inserted between ITO and $WO_3$ film. The result of cyclic voltamogram and the Auger depth profile show that the peak separation of cyclic voltamogram is reduced to below 1/10 and we could effectively block the indium and tungsten migration that is caused by flow of Li ions.

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Crystallinity Control Effects on Vanadium Oxide Films for Enhanced Electrochromic Performances (전기변색 성능 향상을 위한 바나듐산화물 막의 결정성 제어 효과)

  • Kim, Kue-Ho;Bae, Ju-Won;Lee, Tae-Kuen;Ahn, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.29 no.6
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    • pp.385-391
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    • 2019
  • In the present study, vanadium oxide($V_2O_5$) films for electrochromic(EC) application are fabricated using sol-gel spin coating method. In order to optimize the EC performance of the $V_2O_5$ films, we adjust the amounts of polyvinylpyrrolidone(PVP) added to the solution at 0, 5, 10, and 15 wt%. Due to the effect of added PVP on the $V_2O_5$ films, the obtained films show increases of film thickness and crystallinity. Compared to other samples, optimum weight percent(10 wt%) of PVP led to superior EC performance with transmittance modulation(45.43 %), responding speeds(6.0 s at colored state and 6.2 s at bleached state), and coloration efficiency($29.8cm^2/C$). This performance improvement can be mainly attributed to the enhanced electrical conductivity and electrochemical activity due to the increased crystallinity and thickness of the $V_2O_5$ films. Therefore, $V_2O_5$ films fabricated with optimized amount of PVP can be a promising EC material for high-performance EC devices.

Research on Overheat Protection Techniques of Connection Parts of MCCB by Poor Contact (MCCB 단자 접속부의 접촉불량에 의한 과열사고 방지기법에 관한 연구)

  • Kim, Dong-Woo;Lee, Ki-Yeon;Moon, Hyun-Wook;Kim, Hyang-Kon;Cho, Chung-Seog
    • Fire Science and Engineering
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    • v.22 no.4
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    • pp.54-60
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    • 2008
  • In this study, damage characteristics of MCCB and terminal block due to poor contact were analyzed, and various poor contact detection techniques were suggested. Firstly, the detection techniques using thermocouple and infrared thermal camera were analyzed respectively. Also, thermo-cap during poor contact detected abnormal status effectively by changing its color, and the detection system using an odor detector and odor capsules was analyzed. Lastly, poor contact detection screw was made using characteristics of fusible alloy, and we applied the poor contact detection screw to terminal block. The above methods could prevent electrical fire caused by poor contact effectively if they are used properly.