• The Journal of Natural Sciences
• /
• v.9 no.1
• /
• pp.53-56
• /
• 1997

The structure of poly-$\beta$-hydroxybutyrate (PHB) in Chlorogloea fritschii was analyzed by FT-IR spectrometry under various conditions (phosphate starves or sufficient conditions). They exhibited characteristic absorption peaks for PHB, such as C=O stretching band at 1700-1800 $cm^-1$and C-H stretching bands at about 2900 $cm^-1$, however, the intensity of C-H stretching peaks, relative to the rest of the spectrum was increased under phosphate starved condition, which suggests that C. fritschii might produce another modified PHB polymer under phosphate starved condition.

• Fire Science and Engineering
• /
• v.24 no.3
• /
• pp.20-24
• /
• 2010

When the fire occurred in building, the fire-resistance-structure has to be constructed to prevent collapse of building and to have a time for evacuation of peoples. because of the features of the fireresistance test is similar with real scale, there is no way to confirm quality of fire-resistive-structure in building construction site. Therefore the purpose of this study, a study by spectroscopic analysis using near-infrared spectroscopy (NIR), is to suggest of useful and scientific testing-methods in building construction site by identification-analysis-study for fire resistive paint.

• Journal of Sericultural and Entomological Science
• /
• v.44 no.2
• /
• pp.87-92
• /
• 2002

Dissolution of Antheraea pernyi silk fiber was carried out in a zinc chloride solution with various dissolving conditions. The solubility was significantly dependent on the concentration of zinc chloride, dissolving temperature and time. The proper conditions of dissolution were found as 8 M zinc chloride, 70$^{\circ}C$ temperature and 30 min dissolving time. Regenerated A. pernyi silk fibroin powder was obtained through dialysis. FTIR and XRD showed that regenerated A. pernyi silk powder was composed of a ${\beta}$-sheet as well as an ${\alpha}$-helix conformation.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
• /
• 2010.10a
• /
• pp.279-282
• /
• 2010

스티로폼샌드위치패널은 건식공법의 시공편리성, 경제적인 공사비용, 뛰어난 단열성능으로 공장이나 창고건축물을 중심으로 많이 사용되고 있다. 그러나 스티로폼의 여러 가지 장점에도 불구하고 화재에 취약한 단점이 있어 최근 난연성능이 보완된 난연스티로폼패널의 사용이 증가하고 있다. 최근 건축현장에서, 가짜 난연스티로폼패널 사용이 문제되고 있으나 난연성능의 현장 확인에 어려움이 있고 콘칼로리미터 등의 난연성능평가에 시간과 비용이 소요된다. 본 연구에서는 콘칼로리미터를 통해 난연성능이 확보된 난연 스티로폼패널의 심재와 일반스티로폼패널 심재를 대상으로 근-적외선 분광분석을 수행하여 난연성능의 유무에 따라 상이하게 나타나는 고유스펙트럼 흡수를 측정하였다. 각 제품마다 측정된 고유스펙트럼은 통계처리를 통하여 난연스티로폼의 진위여부를 현장에서 구별할 수 있음을 확인하였으며, 비용효율이 높은 현장평가방법으로의 적용이 가능함을 실험을 통해 입증하였다.

• Journal of Conservation Science
• /
• v.37 no.6
• /
• pp.648-658
• /
• 2021

In this study, we aimed to analyze the chemical changes that occur in Korean paper in an accelerated deterioration environment of 105℃. We selected the Korean paper produced with different types of cooking agents (plant lye, Na₂CO₃) and during different manufacturing seasons (winter, summer). The degree of deterioration of the Korean paper was confirmed by measuring the brightness, yellowness, and pH level, and the degree of change in each vibrational region of cellulose as deterioration progressed through infrared (FT-IR) spectroscopy. The FT-IR analysis showed that, as deterioration progressed, the absorbance of the amorphous region in cellulose decreased, whereas the absorbance of the crystalline region slightly increased. X-Ray diffraction (XRD) analysis and Raman spectroscopy were performed to verify the changes in the crystalline and amorphous regions in cellulose indicated by the FT-IR results. Furthermore, the crystallinity index (CI) was calculated; it showed a slight increase after deterioration; therefore, CI was confirmed to follow the same trend as that observed for absorbance in the FT-IR results. In addition, as a result of Raman spectroscopic analysis, the degree of decomposition of the amorphous region in the cellulose under the manufacturing conditions was confirmed by the fluorescence measured after the deterioration.

• Journal of the Korean Association of Geographic Information Studies
• /
• v.7 no.4
• /
• pp.143-154
• /
• 2004

The researchers, who seek geological and environmental information, depend on the remote sensing and aerial photographic datum from various commercial satellites and aircraft. However, the adverse weather conditions and the expensive equipment can restrict that the researcher can collect their data anywhere and any time. To allow for better flexibility, we have developed a compact, a multi-spectral automatic Aerial photographic system(PKNU 2). This system's Multi-spectral camera can catch the visible(RGB) and infrared(NIR) bands($3032{\times}2008$ pixels) image. Visible and infrared bands images were obtained from each camera respectively and produced Color-infrared composite images to be analyzed in the purpose of the environment monitor but that was not very good data. Moreover, it has a demerit that the stereoscopic overlap area is not satisfied with 60% due to the 12s storage time of each data, while it was possible that PKNU 2 system photographed photos of great capacity. Therefore, we have been developing the advanced PKNU 2(PKNU 3) that consists of color-infrared spectral camera can photograph the visible and near infrared bands data using one sensor at once, thermal infrared camera, two of 40 G computers to store images, and MPEG board to compress and transfer data to the computer at the real time and can attach and detach itself to a helicopter. Verification and calibration of each sensor(REDLAKE MS 4000, Raytheon IRPro) were conducted before we took the aerial photographs for obtaining more valuable data. Corrections for the spectral characteristics and radial lens distortions of sensor were carried out.

• Journal of the Korean Electrochemical Society
• /
• v.22 no.2
• /
• pp.53-59
• /
• 2019

To examine the solution structure of electrolytes, it is very important to understand ion-ion and ion-solvent interactions. In this review, we introduce the basic principle of dielectric relaxation spectroscopy (DRS) and studies of electrolyte structure. DRS is a type of impedance method, which measures the dielectric properties of electrolytes over a high frequency domain at levels of tens of GHz. Therefore, DRS provides information on the different polar chemical species present in the electrolyte, including the type and concentration of free solvents and ion pairs with dipole moments. The information of DRS is complementary to the information of conventional analytical techniques (Infrared/Raman spectroscopy, nuclear magnetic resonance (NMR), etc.) and thus enables a broad understanding of electrolyte structure.

• Journal of the Mineralogical Society of Korea
• /
• v.14 no.2
• /
• pp.119-127
• /
• 2001

FTIR spectroscopic study was undertaken on dickite and pyrophyllite with Si and Al cations in the far-infrared(Far-IR) and mid-infrared (Mid-IR) regions, respectively. Attempts were made to present bonding information and make assignments on the absorption bands of dickite in the Far-IR region. Dickites contain a small proportions or kaolinite or nacrite layers. FTIR can be used as a potential tool for characterizing the presence of mixed-layer with different polytypes of the kaolin minerals. There is no clear relationship between Hinckley index and crystallinity of dickite. Although pyrophyllite shows a strong OH stretching band at 3673-3676 $cm^{-1}$ / corresponding to an inner hydroxyl group, the weak band at $3645-3648 cm^{-1}$ seems to be due to the symmetric vibration if the symmetry of the structure is not ideal, probably due to the presence of trace Fe or mixture phases of 1Tc and 2M polytypes.

• Analytical Science and Technology
• /
• v.5 no.4
• /
• pp.455-464
• /
• 1992

Using FT-IR, we determined the depth of silylated layers produced from various gas-phase-silylation conditions was proposed by using Fourier Transform Infrared (FT-IR) spectroscopic analysis. The depth of silylated layer was determined from absorbance measurments of the significant peaks (Si-O-ph, Si-C, Si-H) of FT-IR spectra with background spectrum subtraction method. And the results were compared with thickness measurments of SEM. The results were well agree with SEM. It found to be well suited for determining silylation process window.

• Journal of the Korean Chemical Society
• /
• v.47 no.5
• /
• pp.447-459
• /
• 2003

Generalized 2D correlation spectroscopy has been applied extensively to the analysis of spectral data sets obtained during the observation of a system under some external perturbation. It is used in various fields of spectroscopy including IR, Raman, UV, fluorescence, X-ray diffraction, and X-ray absorption spectroscopy (XAS) as well as chromatography. 2D hetero-spectral correlation analysis compares two completely different types of spectra obtained for a system under the same perturbation. Because of the wide range of applications of this technique, it has become one of the standard analytical techniques for the analytical chemistry, physical chemistry, biochemistry, and so on, and for studies of polymers, biomolecules, nanomaterials, etc. In this paper, we will introduce the principle of generalized 2D correlation spectroscopy and its applications that we have studied.