• Title/Summary/Keyword: 저장기

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경주시 양남 제4기 역질 해안단구 퇴적층 풍화단면내 앨로패인(allophane) 교결층의 기원

  • 정기영;배진한;정창식
    • Proceedings of the Mineralogical Society of Korea Conference
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    • 2001.06a
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    • pp.115-115
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    • 2001
  • 경주시 양남면의 4기 단층으로 추정되는 수렴단층에 의해 절단되는 해안단구 퇴적층 풍화단면에서 저결정질 광물인 앨로패인 교결층을 기재하였다. 이들은 자갈퇴적층 내에 협재하는 수조의 모래층에 한정되어 형성되어 있으며, 3-17 cm 두께로 연장성이 매우 좋다. 편광현미경 관찰에 의하면 모래층에는 사장석편들이 다량 함유되어 있으며 앨로패인은 광학적 등방성의 치밀한 점토집합체들로서 사장석 입자를 선택적으로 교대하거나 자갈과 모래입자들을 피복하고 있다. 앨로패인은 광학적 이방성인 상하위층의 고령토질 점토피복물과 명확히 구분된다. 앨로패인의 전자현미분석에 의하면, Al/Si 원자비가 1.3-1.7 범위이고 평균값은 1.5이다. X선회절분석 결과 3.49$\AA$과 2.26$\AA$에서 두 개의 넓은 회절대가 관찰된다. 주사 및 투과전자현미경관찰에 의하면 앨로패인을 특정한 입자형태 없이 치밀한 겔상태를 이루고 있다. 열분석에 의하면 96$^{\circ}C$에서 큰 흡열피크와 992$^{\circ}C$에서 발열피크가 관찰되며, 총 45% 정도의 중량감소를 보인다. 사장석의 평균조성은 An$_{87}$이며, 사장석내 유리포유물의 전자현미분석결과는 화산암 화학분류도에서 현무암 영역에 도시된다. 이 지역의 기반암은 현무암질 라필리응회암이나 사장석편을 제외하고 벤토나이트화되어 있다. 따라서 해빈환경에서 사장석이 벤토나이트에서 분리되어 퇴적한 것으로 보인다. 앨로패인 교결층은 해수면 강하로 단구퇴적층이 지표로 노출된 후, Al의 함량이 높고 비교적 풍화에 약한 사장석이 선택적으로 풍화되어 생성되었다. 앨로패인으로 피복된 모래층 내의 자갈은 풍화반응이 지체되어 상하위층의 자갈과 비교하여 풍화도에 있어서 현저한 차이를 보인다.. 파이프 중심에서 외곽부로 갈수록 전기석의 함량은 줄어들고 있고 장석들이 알바이트ㆍ칼스베드 쌍정을 보이며, 흑운모가 각섬석보다는 우세하게 나타나고 있다. 전기석은 주상 결정, 자형 내지 반자형의 입자로 다색성을 보이며, 결정 중심에서 가장자리로 갈수록 파란색과 황갈색의 광학적 누대구조를 관찰할 수 있다. 일광광산에서 산출되는 전기석에 대한 현미경 관찰은 열수기원임을 지시하고 있다. 야외조사와 현미경 관찰의 예비조사에 의하면 일광광산의 전기석이 형성된 환경은 다른2가지 화학적인 저장소의 혼합 효과의 결과로 생성되어진 것으로 예상된다. 일광의 화강암류를 만든 마그마는 전기석을 형성할 만큼의 Fe-Mg성분이 충분하지 않았을 것이다. 화강암 내에 흑운모와 각섬석의 결정작용에 의해 마그마의 Fe-Mg성분이 고갈되어지고 이로 인해 그 함량이 감소하며 상대적으로 마그마 내에 남은 붕소(B$_2$O$_3$)는 열수로 용리되고 흑운모, 각섬석과 평형을 유지하며 열수에 남아있게 된다. 잔류용융체에 남은 붕소의 함량은 전기석을 만들기에 충분함에도 불구하고, Fe-Mg 함량이 부족하여 마그마 기원의 전기석 결정을 만들 수가 없다가 광맥이 형성된 시기에 또 다른 열수가 공급되면서 이전의 평형이 깨지고 기존의 흑운모와 같은 염기성 광물이 붕소(B)를 함유한 새로운 열수와 반응하여 전기석을 형성한 것으로 예상한다. 앞으로 전암과 광물에 대해 지화학적 연구를 통해 화강암류와 전기석과의 지화학적 연관성, 주성분 원소와 열수의 특성과의 상관관계, 전기석의 기원(마그마 기원인지 열수기원인지)이 보다 정확하게 파악될 것이다. 마그마 진화에 따른 전기석의 성분변화와 기원을 이용하여 일광광산의 동광화대를 형성한 마그마 계에서 열수계로 이어지는 지질학적 과정을 이해할 수 있을 것이며, 암석 성인론적 지시자로서

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Characteristics of CaCO3 Sorbent Particles for the In-furnace Desulfurization (로 내 탈황을 위한 CaCO3 흡착제 입자의 분위기 기체와 체류 시간의 변화에 따른 특성)

  • Lee, Kang-Soo;Jung, Jae-Hee;Keel, Sang-In;Lee, Hyung-Keun;Kim, Sang-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.2
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    • pp.121-127
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    • 2010
  • The in-furnace desulfurization technique is applied to the $O_2/CO_2$ combustion system for the carbon capture and storage (CCS) process because this combustion system does not need an additional chamber for the desulfurization. $CaCO_3$ sorbent particles, which have a wide range in size from a few nanometers to several tens of micrometers, are used for this process. In this study, an experimental system which can simulate the $O_2/CO_2$ combustion system was developed. $CaCO_3$ sorbent particles were exposed to the high temperature reactor at $1200^{\circ}C$ with various residence times (0.33-1.46 s) in air and $CO_2$ atmospheric conditions, respectively. The sorbent particles were then sampled at the inlet and outlet of the reactor and analyzed qualitatively/quantitatively using SMPS, XRD, TGA, and SEM. The results showed that the residence time and atmospheric condition in a high temperature reactor can affect the characteristics of the $CaCO_3$ sorbent particles used in the in-furnace desulfurization technique, such as the calcination rate and reaction mechanism.

Study on Characteristic of CO2 Hydrate Formation Using Micro-sized Ice (미세직경 얼음을 이용한 CO2 하이드레이트 제조특성 연구)

  • Lee, Jong-Hyub;Kang, Seong-Pil
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.690-695
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    • 2012
  • Gas hydrate is an inclusion compound consisting of water and low molecular weight gases, which are incorporated into the lattice structure of water. Owing to its promising aspect to application technologies, gas hydrate has been widely studied recently, especially $CO_2$ hydrate for the CCS (Carbon Capture and Storage) issue. The key point of $CO_2$ hydrate technology for the CCS is how to produce gas hydrate in an efficient and economic way. In this study, we have tried to study the characteristic of gas hydrate formation using micro-sized ice through an ultrasonic nozzle which generate 2.4 MHz frequency wave. $CO_2$ as a carrier gas brings micro-sized mist into low-temperature reactor, where the mist and carrier gas forms $CO_2$ hydrate under $-55^{\circ}C$ and atmospheric pressure condition and some part of the mist also remains unreacted micro-sized ice. Formed gas hydrate was average 10.7 of diameter at average. The starting ice particle was set to constant pressure to form $CO_2$ hydrate and the consumed amount of $CO_2$ gas was simultaneously measured to calculate the conversion of ice into gas hydrate. Results showed that the gas hydrate formation was highly suitable because of its extremely high gas-solid contact area, and the formation rate was also very high. Self-preservation effect of $CO_2$ hydrate was confirmed by the measurement of $CO_2$ hydrate powder at normal and at pressed state, which resulted that this kind of gas storage and transport could be feasible using $CO_2$ hydrate formation.

Study on miscibility, morphology, thermal and mechanical properties of elastomeric impact modifier reinforced Poly(lactide)/Cellulose ester blends (충격보강제로 강인화된 PLA와 cellulose ester 블렌드의 상용성 및 모폴로지, 열적, 기계적 특성에 관한 연구)

  • Park, Jun-Seo;Nam, Byeong-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.7
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    • pp.4081-4086
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    • 2014
  • Cellulose acetate butyrate (CAB) is a biodegradable resin with excellent optical properties, but it is difficult to apply film process. In this study, an attempt was made to improve the processability of CAB using polyactic acid and the mechanical properties using an impact modifier. Polylacitc acid (PLA)/Cellulose acetate butyrate (CAB) blends with an impact modifier were prepared using a twin screw extruder. The temperature range was $140^{\circ}C$ to $200^{\circ}C$, and the screw speed was fixed to 200 rpm. To evaluate the miscibility of impact modified CAB/PLA, the glass transition behavior and morphology were observed by DSC and FE-SEM. The mechanical properties were investigated by dynamic mechanical analysis (DMA) and a Universal Testing Machine (UTM). In addition, the effect of an impact modifier in the polymer matrix was determined using a notched Izod impact strength tester. Finally, the PLA/CAB/impact modifier 75/25/10 ratio was found to be a compatible system. In the 10wt.% impact modifier, the sample had a 4 times higher izod impact strength than the non-toughening composition.

Digital Logic Extraction from QCA Designs (QCA 설계에서 디지털 논리 자동 추출)

  • Oh, Youn-Bo;Kim, Kyo-Sun
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.46 no.1
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    • pp.107-116
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    • 2009
  • Quantum-dot Cellular Automata (QCA) is one of the most promising next generation nanoelectronic devices which will inherit the throne of CMOS which is the domineering implementation technology for large scale low power digital systems. In late 1990s, the basic operations of the QCA cell were already demonstrated on a hardware implementation. Also, design tools and simulators were developed. Nevertheless, its design technology is not quite ready for ultra large scale designs. This paper proposes a new approach which enables the QCA designs to inherit the verification methodologies and tools of CMOS designs, as well. First, a set of disciplinary rules strictly restrict the cell arrangement not to deviate from the predefined structures but to guarantee the deterministic digital behaviors is proposed. After the gate and interconnect structures of. the QCA design are identified, the signal integrity requirements including the input path balancing of majority gates, and the prevention of the noise amplification are checked. And then the digital logic is extracted and stored in the OpenAccess common engineering database which provides a connection to a large pool of CMOS design verification tools. Towards validating the proposed approach, we designed a 2-bit adder, a bit-serial adder, and an ALU bit-slice. For each design, the digital logic is extracted, translated into the Verilog net list, and then simulated using a commercial software.

Studies of the Translocation and Metabolites of Radioisotope Phosphate(32P) Applied on Foliar under the Low Temperature Condition (저온처리(低溫處理) 수도체에 대한 엽면시비인산(葉面施肥燐酸)(32P) 의 체내 전유 및 대사산물(代謝産物)에 관(關)한 연구(硏究))

  • Hwang, Young-Soo;Ryu, In-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.17 no.1
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    • pp.39-45
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    • 1984
  • The effects of foliar application of phosphate was investigated in the light of plant physiological point of view. The phosphate applied on the foliar both in meiosis and heading time was penetrated considerably into the rice. The amount of P absorbed by foliar application at high temperature was higher than that at low temperature but still considerable amount of P was absorbed at low temperature. The phosphate applied on younger flag leaf was absorbed more vigorously than the second and third leaves. The absorbed P on leaf was translocated to the panicle, especially on the brown rice starch, then moved to another panicle wherever the phosphate was needed. The major fraction of absorbed P under high temperature condition was T.C.A. soluble-Ba insoluble phosphate of mainly phytic form but Ba soluble-EtOH insoluble fraction, sugar phosphate ester, was identified as dominant P under low temperature condition.

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Evaluation of Durability for Glass fabric/Phenolic Composites under Salt Water Environment (염수환경에 노출된 유리섬유직물/페놀 복합재의 내구성 평가)

  • Yoon, Sung-Ho
    • Composites Research
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    • v.18 no.4
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    • pp.27-34
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    • 2005
  • Salt water spray and immersion tests were experimentally conducted for over 6 months to investigate the durability of glass fabric/phenolic composites under salt water environment. Mechanical properties such as tensile properties, flexural properties, and shear properties were evaluated and thermal analysis properties such as storage shear modulus, loss shear moduls, and tan 6 were obtained through a DMA. A change in chemical structures was analyzed through a FTIR. According to the results, mechanical properties and thermal analysis properties were sensitive to salt water environment and these properties began to degrade in increasing in exposure times. However, tensile and flexural moduli started to decrease and then slightly increase as increasing in exposure times due to plasticization and crosslinking in matrix as well as physical swelling in composites. Beyond a certain exposure times, these properties began to decrease as further increasing in exposure times. Also the shape and location of peaks in FTIR curves were insensitive to exposure times, but the intensity of peaks would be. finally we found that the durability of glass fabric/phenolic composites were affected on salt water immersion environment rather than salt water spray environment.

GIS-based Water Pollution Analysis (GIS기반의 오폐수 분석에 관한 연구)

  • Lee, Chol-Young;Kim, Kye-Hyun;Park, Tae-Og
    • 한국공간정보시스템학회:학술대회논문집
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    • 2007.06a
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    • pp.111-116
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    • 2007
  • 현재 한강수계를 제외한 3대강 수계에서 수질오염총량관리제도가 의무제로써 시행되고 있다. 그러나 과학적 타당성과 외국의 성공사례들로 하여금 한강수계에 대해서도 수질오염총량제도를 의무제화 하려는 시도가 추진되고 있고 있는 실정이다. 이 제도가 한강수계에도 도입된다면, 한강권역에 포함되는 모든 지자체는 해당 유역에서 하천으로 유입되는 배출부하량을 할당받은 할당부하량 이하로 관리하여야만 정해진 유역의 목표수질을 달성할 수 있으며, 배출부하량 관리를 계획한데로 이행하지 못한 지자체는 범칙금 내지는 행정제재를 받게 된다. 따라서 체계적이고 과학적인 모니터링 및 분석 수단이 필요하다. 이 연구는 환경부 고시 한강기술지침에 의거하여 GIS를 이용하여 인천일대의 오폐수 발생부하량 및 배출부하량을 제시하고 과학적인 오염물질 삭감방안을 모색하는 것을 목적으로 진행되었다. 생활계, 산업계, 축산계, 양식계의 4 가지로 분류된 점오염원과 토지 이용 분류에 따른 비점오염원에 대한 각각의 발생부하량을 GIS를 통해 산정하고, 모든 오염원별로 처리경로를 고려하고 처리시설별, 방법별 삭감 효율을 반영하여 배출부하량을 산정하여 GIS상에서 제시하고 분석하였다. 인천일대는 인근지역에 비해 인구밀도가 높고 산업단지가 발달하여 생활계와 산업계 오염원에 의한 발생부하량 및 배출부하량이 많았으며, 특정 오염물에 대해서는 삭감 계획이 필요함을 확인할 수 있었다. 따라서 수질오염총량관리제도에 대비하고 실제 수질 개선을 위하여 본 연구의 결과를 바탕으로 수질관리를 위한 시스템의 보완 및 삭감계획의 수립에 관한 연구가 필요하다.알 수 있었다. 이상의 결과를 토대로 기존 압출추출방법과 초임계 추출 방법을 비교한 결과 $\gamma$-토코페롤의 농도가 1.3${\~}$1.6배 증가함을 확인할 수 있었다.게 상관성이 있어 앞으로 심도 있는 연구가 더욱 필요하다.qrt{F}}}{\pm}e_0$)에서 단정도실수 및 배정도실수의 역수 제곱근 계산에 필요한 평균 곱셈 횟수를 계산한다 이들 평균 곱셈 횟수를 종래 알고리즘과 비교하여 본 논문에서 제안한 알고리즘의 우수성을 증명한다. 본 논문에서 제안한 알고리즘은 오차가 일정한 값보다 작아질 때까지만 반복하므로 역수 제곱근 계산기의 성능을 높일 수 있다. 또한 최적의 근사 역수 제곱근 테이블을 구성할 수 있다. 본 논문의 연구 결과는 디지털 신호처리, 컴퓨터 그라픽스, 멀티미디어, 과학 기술 연산 등 부동소수점 계산기가 사용되는 분야에서 폭 넓게 사용될 수 있다.>16$\%$>0$\%$ 순으로 좋게 평가되었다. 결론적으로 감농축액의 첨가는 당과 탄닌성분을 함유함으로써 인절미의 노화를 지연시키고 저장성을 높이는데 효과가 있는 것으로 생각된다. 또한 인절미를 제조할 때 찹쌀가루에 8$\%$의 감농축액을 첨가하는 것이 감인절미의 색, 향, 단맛, 씹힘성이 적당하고 쓴맛과 떫은맛은 약하게 느끼면서 촉촉한 정도와 부드러운 정도는 강하게 느낄수 있어서 전반적인 기호도에서 가장 적절한 방법으로 사료된다.비위생 점수가 유의적으로 높은 점수를 나타내었다. 조리종사자의 위생지식 점수와 위생관리

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Growth Inhibitory Activity of Sulfur Compounds of Garlic against Pathogenic Microorganisms (마늘 황화합물의 병원성미생물 번식억제작용)

  • Kyung Kyu-Hang
    • Journal of Food Hygiene and Safety
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    • v.21 no.3
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    • pp.145-152
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    • 2006
  • Efforts have been made to explore the possibility of using garlic as an antimicrobial therapeutic agent since garlic extract and its individual sulfur compounds show antimicrobial activities against all kinds of microorganisms including bacteria, molds, yeasts and protozoa. Staphylococcus aureus has been the most studied bacteria along with many other Gram positive and negative pathogenic bacteria, including species of the genera Clostridium, Mycobacterium, Escherichia, Klebsiella, Bacillus, Salmonella and Shigella. Candida albicans has been the most studied among the eukaryotic microorganisms. A pathogenic protozoa, Giardia intestinalis, was also tested. All the microorganisms tested was inhibited by garlic extract or its sulfur components. Garlic has been known to be growth inhibitory only when fresh garlic is crushed, since allicin-generating reaction is enzyme-catalyzed. Allicin is known to be growth inhibitory through a non-specific reaction with sulfhydryl groups of enzyme proteins that are crucial to the metabolism of microorganisms. Another plausible hypothesis is that allicin inhibits specific enzymes in certain biological processes, e.g. acetyl CoA synthetase in fatty acid synthesis in microorganisms. Allicin transforms into other compounds like ajoene and various sulfides which are also inhibitory to microorganisms, but not as potent as their mother compound. It is reported recently that garlic heated at cooking temperatures is growth inhibitory especially against yeasts, and that the growth inhibitory compound is allyl alcohol thermally generated from alliin in garlic.

The Quality Characteristics of Backsulgi with Dough Ripe Stage Rice and Yellow Ripe Stage Rice (호숙기와 황숙기 멥쌀을 첨가한 백설기의 품질특성)

  • Park, So-Ra;Lee, Jeung Hee
    • Korean journal of food and cookery science
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    • v.29 no.4
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    • pp.353-359
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    • 2013
  • The effect of the addition of dough ripe stage rice (DRSR) and yellow ripe stage rice (YRSR) on the quality characteristics of Backsulgi was investigated. The DRSR and YRSR addition ratio of 30% was selected by preliminary sensory evaluation study for which backsulgi was prepared with DRSR added to full ripe stage rice (FRSR, control) as the weight ratio of 0, 20, 30 and 50%. The pasting properties of 30% added DRSR and YRSR flours, analyzed with rapid viscosity analyzer (RVA), were compared with FRSR flour. The RVA values of holding, breakdown, final viscosities were higher in 30% DRSR and YRSR flours than in control. Backsulgi prepared with 30% DRSR and YRSR showed lower moisture content along with higher greenness and yellowness than control. As a result of analysis with texture analyzer, adhesiveness, springiness, cohesiveness, chewiness and resilience were lower in backsulgis with 30% DRSR and YRSR than in control. In the sensory evaluation, backsulgis with 30% DRSR and YRSR were assessed as having more intensive green color, and more greenish and delicious taste than control. Furthermore, backsulgi with 30% DRSR showed higher score of overall acceptability than 30% YRSR (p<0.05), and not significantly different score with control (p>0.05). Therefore, the addition of 30% DRSR could give favorable color and flavor to backsulgi.