• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.856-856
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• 2009

석유 및 천연가스를 대체하는 자원으로 석탄이 유망하다고 전망하고 있다. 미국에서는 6대 파괴력이 있는 기술로 청정석탄기술이 선정되었고, 한국에서도 15대 그린에너지 중 하나인 청정연료에 석탄전환기술이 포함되어 전략로드맵이 작성되고 있다. 국내에서 추진되고 있는 석탄기술은 석탄가스화를 기반으로 하고 있다. 석탄가스화는 고체연료인 석탄을 $1000^{\circ}C$ 이상의 고온에서 산소와 반응시켜 일산화탄소와 수소가 주성분인 합성가스로 전환하는 기술이다. 석탄을 가스화하면 석탄에 포함된 불순물을 쉽고 완벽하게 제거할 수 있으며 특히 CO2 제거를 값싸게 할 수 있어 청정화가 가능하다. 최근 고유가를 겪으면서 열량이 높은 고급탄의 확보가 어려워지면서 가격이 낮고 수급이 용이한 저급탄을 활용하는 기술의 수요가 발생되어 국내에서 기업을 중심으로 저급탄을 고효율로 가스화하는 기술 개발이 시도되고 있다. 정제된 석탄가스는 성분을 조절하여 촉매에 의해 메탄으로 전환시킬 수 있고, 이렇게 제조된 가스를 합성천연가스(SNG)라 한다. 값싼 저급탄을 사용하면 SNG를 천연가스보다 저렴하게 생산할 수 있다. 국내 기업이 SNG 제조 실증시설을 도입하고, 동시에 핵심기술인 SNG 합성반응공정을 개발하는 사업을 추진하고 있다. 석탄가스를 촉매반응에 의해 디젤 및 �F싸로 전환하는 석탄간접액화기술은 현재 남아공 Sasol사에서 상업적으로 운전되고 있는 기술이나 국내로의 기술이전이 거의 불가능하다. 철을 기반으로 하는 고유 촉매와 scale-up이 가능한 반응기가 핵심인 기술로 국내에서 세미-파일럿급 액화공정 기술개발이 진행중이다. 전세계적으로 석탄액화공장의 수요가 현재의 15만배럴/일에서 2030년 240만배럴/일로 증가한다고 예측된다. 따라서 200조원 이상의 플랜트 시장이 기대되며 국산 가스화, SNG 및 액화기술로 상당부분의 시장을 장악하고자 한다.

• Journal of Energy Engineering
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• v.21 no.1
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• pp.68-74
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• 2012

Sub-bituminous coals have been used increasingly in coal-fired power plants with a proportion of over 50% in the blend with bituminous coals. As a result, the unburned material in fly ash has increased and is causing problems in utilizing the fly ash as an additive for concrete production. In this study, analysis of fly ash obtained from a 500 MWe power plant was carried out and unburned material in the fly ash found to be soot. The coals used in the plant were analyzed with CPD model to investigate the sooting potential depending on the coal type and blending ratio.

• Journal of the KSME
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• v.49 no.1
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• pp.37-41
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• 2009

• Journal of Hydrogen and New Energy
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• v.26 no.6
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• pp.567-580
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• 2015

In order to select an optimum gasifier for specific low rank coal, evaluation elements were studied by analyzing characteristics of low rank coal compared with those of high rank coal and the effects of each gasifier type in accordance with the characteristics. And syngas composition calculation model was made on the basis of thermochemical equilibrium to quantify some of the evaluation elements. And then the suitable gasifier was selected for a kind of Indonesian low rank coal through this syngas composition calculation model and the evaluation elements of selecting gasifier.

• Journal of the Korean Applied Science and Technology
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• v.33 no.3
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• pp.466-473
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• 2016

In this study, the experiments on optimal CO gas synthesis were conducted using low grade coal-$CO_2$ catalyst gasification reaction. The characteristics of generated CO gas were investigated using the chemical activation method of KOH, $K_2CO_3$, $Na_2CO_3$ catalysts with Kideco and Shewha coal. The preparation process has been optimized through the analysis of experimental variables such as ratio between activating chemical agents and coal, the flow rate of gas and reaction temperature during $CO_2$ conversion reaction. The produced CO gas was analysed by Gas Chromatography (GC). The 98.6% $CO_2$ conversion for Kideco coal mixed with 20 wt% $Na_2CO_3$ and 98.9% $CO_2$ conversion for Shenhua coal mixed with 20 wt% KOH were obtained at the conditions of $T=950^{\circ}C$ and $CO_2$ flow rate of 100 cc/min. Also, the low grade coal-$CO_2$ catalytic gasification reaction showed the CO selectivities(97.8 and 98.8 %) at the same feed ratio and reaction conditions.

• Korean Chemical Engineering Research
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• v.49 no.1
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• pp.114-119
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• 2011

Thermogravimetric analysis(TGA) was carried out for pyrolysis and char-$CO_2$ gasification of low rank Indonesian ABK coal and China lignite. The pyrolysis rate was successfully described by a two-step model adopting the modified Kissinger method. The shrinking core model, when applied to char-$CO_2$ gasification gave initial activation energy of 189.1 kJ/mol and 260.5 kJ/mol for the ABK coal and China lignite, respectively. Thus, the char-$CO_2$ gasification has been successfully simulated by the shrinking core model. In particular, the activation energy of char-$CO_2$ gasification calculated in this work is similar to the results on the anthracite coal, but considerable difference exists when other models or coal types are used.

• KDI Journal of Economic Policy
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• v.10 no.2
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• pp.91-115
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• 1988

1980년대 하반기부터 한국(韓國)의 석탄산업(石炭産業)은 70년대말에서 80년대초까지와는 상이한 여건에 직면함으로써 구조적(構造的) 변화(變化)를 필요로 하고 있다. 이에 반하여 정부(政府)는 석탄정책(石炭政策)에 깊이 개입하면서도 경제여건변화(經濟與件變化)에 적절한 정책대응(政策對應)을 펴지 못하고 오히려 기업퇴출(企業退出)(exit)을 막고 산업합리화(産業合理化)를 저해함으로써 장기적으로 경제(經濟)의 효율성(效率性)을 떨어뜨리고 자원배분(資源配分)을 왜곡(歪曲)시키는 결과를 초래하였다. 본고(本稿)에서는 미래의 에너지파동(波動) 가능성(可能性)을 고려한 국내석탄정책(國內石炭政策)과 수입탄정책(輸入炭政策)에 대하여 논의하고, 개방경제하(開放經濟下)에서의 사회적(社會的) 마찰(摩擦)을 극소화하기 위한 석탄가격구조(石炭價格構造) 개선방안(改善方案)을 제시하였다. 분석결과(分析結果)에 따르면 현행(現行) 수입탄가격(輸入炭價格)은 오히려 국내탄질(國內炭質)의 저급화(低級化)를 유발시키는 저급화(低級化)를 유발시키는 왜곡현상(歪曲現象)을 초래 하고 있으므로, 앞으로는 국내탄가(國內炭價)를 석공원가기준(石公原價基準)에서 수입탄가(輸入炭價)를 기준으로 하는 결정방식으로 전환하고 수입탄가(輸入炭價)와 국내탄가(國內炭價)의 열량별(熱量別) 가격구조(價格構造)를 개선할 필요가 있다. 그리고 정부주도(政府主導)의 탄광통폐합(炭鑛統廢合)은 또다른 비효율성(非效率性)과 자원배분(資源配分)의 왜곡(歪曲)을 가져올 우려가 있으므로 가격정책(價格政策), 정부보조(政府補助) 등을 통한 간접통제방식(間接統制方式)으로 민간경제의 효율성을 유도하여 주는 것이 바람직하며, 또한 기업퇴출(企業退出)에 따른 탄광지역(炭鑛地域)의 경제활동(經濟活動) 위축(萎縮)과 실업문제(失業問題) 등에 사전적인 정책대응(政策對應) 필요하다.

• Journal of Energy Engineering
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• v.23 no.4
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• pp.207-214
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• 2014

With the depletion of high grade coal, it is indispensable to be used co-combustion of low rank coal with bituminous coal in pulverized coal-fired power plants. This study describes the detailed measurements of combustion characteristics of bituminous and subbituminous coal in a 0.7MWth pilot-scale test facility. This experimental works include the measurement of gas temperature, gas concentrations along with the reactor axial and radial distance at the condition of excess air ratio of 1.2. The solid sampling was carried out and analyzed with the combustion of bituminous coal. The main reaction zone of coal flame in a reactor was formed about 1 m from the swirl burner, and at downstream, the fully developed temperature and species distribution was observed. The sampled particles of bituminous coal in a reactor revealed the complete carbon burn-out was achieved just after an main combustion zone.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.12
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• pp.1000-1006
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• 2009

Integrated Coal Gasification Combined Cycle (IGCC) power plants have been developed to reduce carbon dioxide emissions and to increase the efficiency of electricity generation. A devolatilization process of entrained coal gasification is predicted by CPD model which could describe the devolatilization behavior of rapidly heated coal based on the chemical structure of the coal. This paper is intended to compare the mass release behavior of char, tar and gas(CO, $CO_2,\;H_2O,\;CH_4$) for three different coals. The influence of coal structure on gas evolution is examined over the pressure range of 10${\sim}$30atm.

• 한국연소학회:학술대회논문집
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• 2013.06a
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• pp.129-132
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• 2013

The low rank coal combustion and biomass-coal co-firing characteristics were reviewed on this study for the power plant construction. The importance of using low rank coal(LRC) for power plant is increasing gradually due to power generation economy and biomass co-firing is also concentrated as power source because it has carbon neutral characteristics to reduce green-house effect. The combustion characteristics of low rank coal and biomass for a 310MW coal firing power plant and a 100MW biomass and coal co-firing power plant were studied to apply into actual power plant design and optimized the furnace and burner design.