• Journal of environmental and Sanitary engineering
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• v.12 no.3
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• pp.121-126
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• 1997

Carbochlorination of fly ash with phosgene and mixture CO, $Cl_{2}$ were investigated. The results obtained with pure chlorine, and/or chlorination mixtures were presented.

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 1998.11a
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• pp.329-334
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• 1998

난연성을 지닌 고분자 물질중 Chlorosulfonated Polyethylene(CSPE; Hypalon)은 Polyethylene에 염소와 황을 첨가한 것으로 염소를 첨가함으로써 기름과 화염에 대한 저항성을 향상시키고, 황 또한 기름, 화염에 대한 저항을 향상시킬 뿐 아니라 인장강도를 크게 해서 기계적 강도를 향상시킨 것이다. CSPE는 염소량의 등급에 따라 Coating재료, 호스 구조재, Wire와 Cable의 피복재료등 여러 가지 용도로 많이 쓰이고 있으며 특히 염소함량이 35%인 CSPE(Hypalon-40)의 경우 열저항과 압출 특성이 우수하기 때문에 Cable의 피복재료로 많이 쓰이고 있다.

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.453-453
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• 2023

상수관망의 수질사고와 이상상황 발생시 대응을 위해서는 급수구역에 설치되어 있는 자동수질측정기, 정밀여과장치, 재염소주입설비, 자동드레인 등의 계측·제어설비들 간의 유기적인 정보공유를 통한 제어를 필요로 한다. 스마트 상수관망 운영플랫폼은 이러한 인프라 시설의 운영방안을 고려하여 분산되어 있는 계측데이터를 통합감시 및 제어하는 시스템으로 개발되었다. 상수관망 운영플랫폼은 능동형 분석 제어기술을 도입하여, 스마트 상수관망 인프라 설비를 최적제어할 수 있도록 구현하였다. 통합운영 플랫폼은 PostgreSQL, PostGIS, GeoServer, OpenLayers 등의 기술을 활용하여 개발하였다. 플랫폼은 계측감시, 시설관리, 운영제어 등의 기능으로 구성되며, 상수도 업무지원을 위한 관망해석 및 네트워크 분석 기능을 지원한다. 본 시스템은 스마트 상수도 구축사업을 통해 구축한 유량·수질모니터링 장비와 수질관리를 위해 도입된 재염소, 자동드레인 설비의 운영상태를 실시간 조회하는 모니터링 프로그램과, 관망해석 프로그램 그리고 대상설비의 최적제어를 위한 운영관리 프로그램으로 구성되어 있다. 모니터링 프로그램은 현장에서 측정되고 있는 유량, 수압, 수질, 펌프운전 등의 상태를 실시간으로 감시하고 클라우드 데이터베이스에 저장·관리하는 기능을 수행한다. 관망해석 프로그램은 EPA_Net모형과 연계되어 관망수리·수질해석을 수행하는 부분으로 재염소설비의 염소 추가주입이나 자동드레인을 통한 배제시 나타나게되는 관의 수리·수질변화를 클라우드 컴퓨팅 환경에서 분석하고 결과를 가시화 하는 기능을 갖고 있다. 운영관리 프로그램은 재염소 주입이 필요할 경우 주입량의 산정하는 부분과 관망 파손이나 수질사고 발생시 최적 단수예상지역을 도출하는 기능을 보유하고 있다. 향후 스마트 상수관망의 능동형 수질관리를 추진하는 지자체에 도입하여 인프라운영관리 기술 확보 및 수질관리 능력 개선과 실시간 감시 및 위기 대응능력 향상에 기여할 것으로 기대된다.

• Journal of Conservation Science
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• v.26 no.4
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• pp.397-406
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• 2010

The most ideal method to measure the water-soluble $Cl^-$ ion eluted from iron artifacts is conducting the analysis on desalting solution by Ion Chromatography. But most institutes related to cultural heritages use Cl meter by reason of lack of budget and experts. This study evaluated reliability and stability between Cl meter and Ion Chromatography by doing cross-validation with results from two methods to detect $Cl^-$ ion of desalting solution. From D.I water, extremely small quantities of $Cl^-$ ion was detected by the influence of remaining water-soluble $Cl^-$ ion at the electrode of Cl meter and water-soluble $Cl^-$ which remains in Sodium sesquicarbonate, components of reagent was detected as well. The first desalting solution had the most $Cl^-$ ions, $Cl^-$ ion slightly decreased from the second to the fourth desalting solution and tend to decrease again at the stage of dealkalified in D.I water. Each Cl meter has the standard deviation according to the measured numbers and the higher concentration of $Cl^-$ ion the desalting solution has, the wider the deviation is. But when the concentration of $Cl^-$ ion is low, it was stable to use Cl meter to detect the concentration of $Cl^-$ ion from iron artifacts because there is the small deviation, It is thought that conductivity meter method is not suitable for measuring $Cl^-$ ion, because the electrical conductivity of alkaline solution is too high to measure $Cl^-$ ion.

• Journal of the Korea Concrete Institute
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• v.24 no.4
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• pp.435-444
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• 2012

High performance concrete mixes are selected and corresponding test specimens are made for the study of chloride diffusion coefficient at reference time. The concrete mixes were same designs as those used in construction of bridges located in a marine environment. Mix design variables included binder type, water-to-binder ratio, mineral admixtures to total binder weight substitution ratio, fine aggregate source, chemical water reducer admixture type for high strength and high flowability, and target slump or slump flow. The test results showed that the diffusion coefficients at reference time varied significantly according to the type of mineral admixtures and their substitution ratios. A model for diffusion coefficient at reference time considering the type of mineral admixture and the substitution ratio was developed. Diffusion coefficients from the developed model were compared with those from literature review, a previous model, and additional test results. All of the comparisons verified that the developed model can reasonably predict diffusion coefficients and the application of the model to the durability design against chloride penetration is appropriate.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.4A
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• pp.347-353
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• 2009

The qualitative factors influencing the ingress of chloride ion into concrete are water-binder (W/B) ratio, cement type, age, chloride ion concentration of given environment, wet and dry conditions, etc. Thus, an objective of this experimental research is to investigate the effects of cement types and environmental conditions on the chloride ion diffusion characteristics in concrete through the chloride ion diffusion test. For this purpose, the diffusion coefficients for chloride ion in concrete with three types of cement such as ordinary portland cement (OPC), binary blended cement (BBC), and ternary blended cement (TBC), were measured for the concrete specimens with W/B ratios of 32%, 38%, and 43%, respectively. The diffusion coefficients for chloride ion were also measured for the concrete specimens with W/B ratio of 43%, which were subjected to standard curing and field exposure conditions. It was observed from the test results that the resistance against chloride ion penetration increased with decreasing W/B ratio and those of BBC and TBC concretes were greater than that of OPC concrete. Therefore, it was revealed that the use of these cements containing mineral admixtures is required to extend the service life of RC structures exposed to chloride environment. On the other hand, it was noted that the resistance against chloride ion penetration of field exposure test specimens was slightly lower than that of standard curing test specimens due to the penetration of chloride ion under the irregular ambient temperature, splash of wave, and cycle of wet and dry.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.11a
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• pp.159-160
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• 2020

This study examined the potentials for developing a biological coating material with high chloride resistance. The bacteria strains isolated were Halomonas alkaliphile, Halomonas venusta, and Sulfidobacter mediterraneus. Test results revealed that the developed approach is very promising in reducing the chloride ion diffusion coefficient of concrete.

• Journal of Korean Society of Water and Wastewater
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• v.20 no.5
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• pp.701-707
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• 2006

Disinfectant residual should be maintained to achieve biological stability during distribution of treated water. The wide distribution of retention times associated with storage and transport of water in a network and the reactivity of disinfectants make it difficult to maintain adequate residuals at critical locations. Rechlorination at some intermediate locations may reduce the total disinfectant dose while keeping residuals within specified limits throughout the water distribution system. In order to select the adequate location of rechlorination for achieving to maintain of residual chlorine throughout the distribution system, EPANET was used in this study. EPANET was well predicted chlorine transport and residual loss in the distribution system. Location of rechlorination was selected to maintain 0.4mg/L of residual chlorine throughout a water distribution system by field investigation and model simulation. The quantity of chlorine may reduced 36.7% and provided smooth residual between 0.42 and 0.60mg/L, when rechlorination would be used continuously at strategic location within the distribution system.

• Journal of the Korea Concrete Institute
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• v.16 no.4 s.82
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• pp.485-492
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• 2004

In this study, ASTM C 1202 which is most commonly used for evaluating the penetration resistance into the concrete is reviewed. The test results by ASTM C 1202 showed that the passed charge could be underestimated as the $OH^-$ ion concentration in the concrete is lowered when the concrete is mixed with the admixtures. Therefore, the modified method using the distilled water was proposed in the paper. According to the test results, the modified method is not susceptible to $OH^-$ ion and temperature rise. In addition, the long term emersion test for the concrete mixed with the admixtures in the NaCl solution showed that the chloride diffusion coefficient tested by the modified method have higher correlation compared to the conventional ASTM method.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.525-528
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• 2008

For well-constructed concrete, its service life is a long term and it has an enough durability performance. However, for cracked concrete, it is clear that cracks should be preferential channel for the penetration of aggressive substance such as chloride ions according to author's previous researches. In order to enhance the lifetime of cracked concrete, critical issues in the performance of the concrete is the risk of chloride-induced corrosion. Even though crack width can be reduced due to the high reinforcement ratio, the question is to which extend these cracks may jeopardize the durability of cracked concrete. If the size of crack is small, surface treatment system can be considered as one of the best options to extend the service life of concrete structures exposed to marine environment simply in terms of cost effectiveness versus durability performance. Thus, it should be decided to undertake an experimental study on the effect of different types of surface treatment system, which are expected to seal the concrete and the cracks to chloride-induced corrosion in particular. In this study, it is examined the effect of surfaced treated systems on chloride penetration through microcracks. Single surface treatments of penetrant or coating and double application were considered as an experimental variation. RCM (Rapid Chloride Migration) testing is accomplished to visualize chloride penetration via cracks.