• Title/Summary/Keyword: 재생형 연료

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Developement of a PEFC electrodes under the high temperature and low humidified conditions (고온/저 가습 운전을 위한 고분자 전해질 연료전지용 전극 개발)

  • Ryu, Sung-Kwan;Choi, Young-Woo;Park, Jin-Soo;Yim, Sung-Dae;Yang, Tae-Hyun;Kim, Han-Sung;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.149-149
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    • 2009
  • Generally, Nafion ionomer is used in the polymer electrolyte fuel cell (PEFC) electrodes to achieve high power density. At the high temperature operation of PEFC, however, ionic conductivity of Nafion remarkably decreased due to the evaporation of water in Nafion polymer. Recently, many researchers have focused on using the Ionic Liquids(ILs) instead of water in Nafion polymer. ILs have intrinsic properties such as good electrochemical stability, high ionic conductivity, and non-flammability. Especially, ILs play a crucial role in proton conduction by the Grottuss mechanism and act as water in water-free Nafion polymer. However, it was found that the ILs was leached out of the polymer matrix easily. In this study, we prepared membrane electrode assemblies with various contents of ILs. The effect of ILs in the electrode of each designed was investigated by a cyclic voltammetry measurement and the cell performance obtained through a single cell test using H2/Air gases. Electrodes with different contents of ILs in catalyst layer were examined at high temperature and low humidified condition.

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Numerical analysis of the gas flow-rate uniformity in the anode flow channel of indirect internal reforming molten carbonate fuel cell (MCFC) under different pressure drop and temperature conditions (간접 내부 개질형 용융탄산염 연료전지 anode 채널에서의 압력 강하 및 온도 조건 변경에 따른 유량 균일도에 관한 수치 해석적 연구)

  • Cho, Jun-Hyun;Ha, Tae-Hun;Kim, Han-Sang;Min, Kyoung-Doug;Park, Jong-Hoon;Chang, In-Gab;Lee, Tae-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.127-130
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    • 2009
  • The uniform gas distribution between anode channels of the indirect internal reforming type molten carbonate fuel cell (MCFC) is crucial design parameter because of the electric performance and the durability problems. A three-dimensional computational fluid dynamics (CFD) analysis is performed to investigate flow characteristics in the anode channels and manifold under different pressure drop and channel temperature conditions. The combined meshes consists of hexadral meshes in the channels and polyhedral meshes in the manifold are adopted and chemical reactions inside the MCFC system are not included because of computational difficulties associated with the size and geometric complexity of the system. Results indicate that the uniformity in flow-rate is in the range of $\pm$ 0.048 % between the anode channels when the pressure drop of anode channel is about 150 Pa. A gas flow-rate uniformity decreases as the pressure drop of anode channels decreases and as the temperature difference between indirect internal reforming (IIR) channels and anode channels increases.

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Transient response of unit PEMFC with the visualization study of cathode flooding under different stoichiometries (당량비 조건에 따른 PEM 단위 연료전지의 과도 응답 특성 및 공기극 플러딩 연구)

  • Cho, Jun-Hyun;Kim, Han-Sang;Min, Kyoung-Doug
    • New & Renewable Energy
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    • v.3 no.2 s.10
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    • pp.24-30
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    • 2007
  • The transient response of PEMFC (proton exchange membrane fuel cell) is important criteria in the application of PEM fuel cell to real automotive system. In this work, using a transparent unit PEM fuel cell, the transient response and cathode flooding during load change are investigated. The cell voltage is acquired according to the current density change($0.3Acm^2$ to $0.6A/cm^2$) under various stoichiometry conditions and different flooding intensities, Also the cathode gas channel images are obtained by CCD imaging system simultaneously. The different level of undershoots appeared at the moment of load changes under different cathode stoichiometries and flooding intensities. It takes about 1s that the product water comes up onto the flow channel so that oxygen supply is temporarily blocked which causes voltage loss in that "undershoot". The correlation of the dynamic behavior with stoichiometry and cathode flooding is induced from the results of these experiments.

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Operating Conditions of Proton Exchange Membrane Fuel Cell Using Grafoil$^{TM}$ as Bipolar Plates (그라포일 분리판을 이용한 고분자 전해질 연료전지의 운전 조건에 관한 연구)

  • Park, Taehyun;Chang, Ikwhang;Lee, Yoon Ho;Lee, Juhyung;Cha, Suk-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.85.1-85.1
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    • 2011
  • In this study, Grafoil$^{TM}$ which has comparable electric resistance and chemical stability but is flexible, fragile, and cheap material was adopted as bipolar plates for proton exchange membrane fuel cell(PEMFC) having only one straight line flow channel. Because of its flexibility, pressurizations of cell with various pressures showed different operating characteristics compared to ordinary graphite-used PEMFC. While performances of both cells decreased as these were pressurized, investigation of ohmic and faradaic resistance by electrochemical impedance measurement indicated different tendency of change. Ohmic resistance of graphite-used cell increased with increasing pressure, which is reversed in Grafoil$^{TM}$-used cell. It is speculated that effective chemical reaction area is decreased with increasing pressure in case of graphite-used one, but because of flexible property of Grafoil$^{TM}$, gas diffusion layer in Grafoil$^{TM}$-used cell was well-activated. Different rate of change of faradaic resistances in both cells support this supposition. However, although optimum point of pressurization is found, it is required to investigate other operating conditions because of low performance compared to graphite-used cell.

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Study on Performance and Durability of the Proton Exchange Membrane Fuel Cell with Different Micro Porous Layer Penetration Thickness (미세다공층의 침투깊이가 다른 기체확산층이 고분자전해질 연료전지의 성능과 내구성에 미치는 영향에 관한 연구)

  • Cho, Junhyun;Park, Jaeman;Oh, Hwanyeong;Min, Kyoungdoug;Jyoung, Jy-Young;Lee, Eunsook
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.81.2-81.2
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    • 2011
  • The gas diffusion layer (GDL) consists of two main parts, the GDL backing layer, called as a substrate and the micro porous layer (MPL) coated on the GDBL. In this process, carbon particles of MPL penetrates to the GDBL consequently forms MPL penetration part. In this study, the micro porous layer (MPL) penetration thickness is determined as a design parameter of the GDL which affect pore size distribution profile through the GDL inducing different mass transfer characteristics. The pore size distribution and water permeability characteristics of the GDL are investigated and the cell performance is evaluated under fully/low humidification conditions. Transient response and voltage instability are also studied. In addition, to determine the effects of MPL penetration on the degradation, the carbon corrosion stress test is conducted. The GDL that have deep MPL penetration thickness shows better performance in high current density region because of enhanced water management, however, loss of penetrated MPL parts is shown after aging and it induces worse water management characteristics.

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EAP를 이용한 청정 에너지 수확 기술 개발

  • Kim, S.H.;Lee, S.J.;Yoon, D.H.;Yang, Y.S.;Moon, J.H.;Lim, S.C.;Park, J.A.;Kim, Z.S.
    • Electronics and Telecommunications Trends
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    • v.23 no.6
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    • pp.22-31
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    • 2008
  • 화석연료를 개발함에 따라 인류는 과거보다 풍요한 물질문명을 누리게 되었으나 그 부작용으로 지구 온난화라는 현실적 재난에 직면해 있다. 점점 뜨거워지는 지구를 식히기 위해 세계적으로 당장 시급한 대책은 화석연료의 생산, 수송 및 소비에 있어서 효율을 높이고, 에너지를 절약함으로써 온실가스를 감축하는 것이다. 하지만 궁극적으로는 신재생 에너지와 같이 온실가스를 배출하지 않는 지속 가능한 에너지원을 사용함으로써 청정한 미래형 산업 시스템이 이루어야 한다. 에너지의 해외의존도가 97%에 육박하고 있는 우리나라의 입장에서 세계적으로 연평균 전력발전량의 약 20%를 담당하고있는 수력, 풍력, 조력 발전은 에너지 자급에 의한 수급 안정성 확보 측면에서 중요한 의미를 가진다. 특히, 화력 및 원자력과 비교할 때 환경에 대한 영향이 거의 없는 청정한 에너지로서 개발이 유망한 에너지이다. 대규모 수력발전은 대형 댐의 건설로 인한 환경.생태적 문제점이 있을 수 있으나, 풍력과 조력발전은 상대적으로 환경에 미치는 영향이 작은 편이다. 본 보고서에서는 최근 연구되고 있는 신재생 에너지 중 전기활성 고분자(EAP)를 이용하여 조력이나 유력, 풍력을 이용하여 청정 에너지를 생산할 수 있는 방법에 대하여 논하고자 한다.

Current Progress of Development of $30Nm^3/hr$ Scale Hydrogen Refueling Station with Natural Gas Reformer (천연가스 개질형 $30Nm^3/hr$급 수소스테이션 연구개발 현황)

  • Lee, Young-Chul;Cho, Young-Ah;Park, Dall-Young;Choi, Chung-Hwan;Kim, Jae-Dong;Song, Taek-Yong;Cho, Byoung-Hak;Kim, Dong-Hyeok;Lee, Jung-Sung;Oh, Young-Sam;Hong, Sung-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.25-28
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    • 2006
  • 수소는 청정에너지로서 미래에너지의 대안으로 여겨지고 있기 때문에 수소에너지 관련 기술은 미래 국가 경쟁력을 좌우할 것으로 예상되며 이러한 수소에너지의 핵심인 수소스테이션 관련 기술은 국가연료전지 시장을 비롯한 수소자동차 사업 전반에 커다란 영향을 미칠 것으로 예상되고 있다. 이에 따라 전 세계적으로 수소에너지를 차세대 에너지원으로 개발하기 위하여 전력을 다하고 있으며, 수소연료전지자동차 개발과 아울러 수소스테이션 개발에 대한 인프라 구축 및 실증연구가 본격적으로 이루어지고 있다. 국내에서도 가스공사를 비롯한 에너지 관련 기업에서 수소스테이션 건설이 추진되고 있으며, 본 연구에서도 수소인프라 구축의 일환으로 추진되고 있는 수소스테이션 개발 현황에 대하여 논의하고자 한다.

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Development of In-tank Pressure Regulator and Solenoid Valve (내장형 레귤레이터 및 솔레노이드 개발)

  • Lee, Jun-Hyuk;Lim, Tae-Hoo;Kim, Kyung-Nam;Shim, Sang-Hak
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.188-191
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    • 2007
  • This paper shows the Development of In-tank pressure regulator and Solenoid Valve used in FCV(Fuel Cell Vehicle). We have developed new type of Regulator and Solenoid through analysis of the structure and characteristics of component of FCS(Fuel Cell System) from the advanced technology. Now it is possible to localize the component by making use of the development of Regulator and Solenoid made by us. Regulator and Solenoid is a equipment to control hydrogen pressure supplied into a stack. Therefore, outlet pressure, a flow of fluid and temperature are important parameters according to a inlet pressure. And leak test, endurance test and burst test should be done to guarantee the performance and safety of Regulator and Solenoid used in the fuel of high pressure. Also, Hydrogen friendly materials are applied to inner parts of the Regulator, Solenoid and weight reduction is done to cost saving in part not related to performance. As a result, we have proven the good performance and reliability in endurance of Regulator, Solenoid and will make an development in performance as well as durability to ensure industrialization.

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Enhanced Phase Angle Detect Method for Grid Connected Distributed Power System (연계형 분산전원용 개선된 위상각 검출 방법)

  • Heo, Min-Ho;Lee, Ho;Park, Sung-Jun;Kim, Kwang-Heon;Song, Sung-Geun
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.913_914
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    • 2009
  • 태양광, 풍력, 연료전지 등 신재생에너지가 분산전원으로 계통에 연계될 경우 정확한 위상각 검출과 함께 전압 및 주파수 변화에 따른 빠른 응답성이 요구된다. 본 논문에서는 개선된 Gauss-Seidal Relaxation 방식을 사용하여 수ms 이내에 정확한 위상각을 검출하는 알고리즘을 제안하고 시뮬레이션을 통해 타당성을 검증하였다.

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Dehydration and RDF Production of Organic Wastes with Pressurized Hydrothermal Treatment Process (증기가압형 처리공정을 이용한 유기성 폐기물의 건조처리 및 고형연료화)

  • Park, Se-Joon;Choi, Young-Chan;Choi, In-Kyu
    • Journal of Hydrogen and New Energy
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    • v.20 no.5
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    • pp.439-446
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    • 2009
  • This paper investigates the dehydration and RDF (Refuse Derived Fuel) production of organic wastes, livestock manure and sewerage sludge with pressurized hydrothermal treatment process. The renewable technology for the organic wastes must involve short treatment time required, reusable energy source, anti-odor and viruses, low cost for the treatment, and well-fertilization. The pressurized hydrothermal treatment process promotes to evaporate moisture in the waste after being shortly treated in a reactor, which uses steam and heat supplied by an external boiler. By the pressurized steam, the cell walls of the waste break and effectively release the internal moisture. Then, the dried waste can be mixed with waste vinyls to produce RDF with a higher heating value as high as 6,700 kcal/kg.