• Title/Summary/Keyword: 잔류분석

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Propellant utilization system on liquid-fuelled rocket (액체추진 발사체의 추진제 소진시스템)

  • Cho, Kie-Joo;Lim, Seok-Hee;Jung, Young-Suk;Oh, Seung-Hyub
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.203-206
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    • 2006
  • We have studied, for maximizing the total impulse of liquid propulsion system, Propellant Utilization System (PUS) to minimize outage of propellant. Propellant outage is mainly influenced by propellant mixture ratio during flight and real quantity of loaded propellant. If one employs cryogenic propellant, the variation of propellant density due to the temperature change has major effect on outage control. Feedback control of propellant level of each tank during flight could deplete both tanks simultaneously. To introduce this system, however, the mixture ratio control system of rocket engine is necessary.

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A study for application plan of rational residual water pressure on the tunnel linings (터널 라이닝에 작용하는 합리적인 잔류수압 적용방안 검토)

  • Jung, Kuk-Young;Kim, Ji-Yeop;Kim, Ji-Hun;Moon, Hoon-Ki
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.13 no.6
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    • pp.463-499
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    • 2011
  • Control of ground water is one of the most important factors for long-term operation of tunnel because most tunnels are located under the ground water level. In case of a drainage tunnel, there is no pore water pressure on the lining when the drainage system is properly working. After long-term operation, however, residual pore water pressure can be developed on the lining due to the deterioration of the drainage system. In this study, the water pressure distribution under obstruction condition of drainage material and conduit on the tunnel is numerically investigated using the ICFEP program and compared with the current value being applied to the residual water pressure for rational application plan of residual water pressure on the tunnel linings.

Present Status and Remedial Actions with Regard to Legal Limits of Pesticide Residues in Korea (국내 농약잔류 허용기준의 현황분석과 대처방안)

  • Lee, Su-Rae;Lee, Mi-Gyung
    • Korean Journal of Environmental Agriculture
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    • v.20 no.1
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    • pp.34-43
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    • 2001
  • For 202 pesticides with maximum residue limit(MRL) in Korea, anticipated problems were identified and remedial actions were suggested. The risk index expressed as the ratio of theoretical maximum daily intake against ADI which exceeds 80% appeared in 35 pesticides. Items showing 10-fold difference between Korea and Codex MRLs appeared in 35 pesticides and 47 food commodities. In any of the 202 pesticides, nominated crops without MRL were 33 items whereas non-nominated crops with MRL were 50 items. Under the Codex system, cases of separate MRLs among raw materials and processed products were exampled. Remedial actions to minimize the above-mentioned discrepancies were suggested respectively.

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A Study on the Welding Deformations and Residual Stresses for Circumferential Welded Cylinders (원통의 용접변형 및 잔류응력에 대한 연구)

  • K.Y. Yoo;D.S. Um
    • Journal of the Society of Naval Architects of Korea
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    • v.35 no.4
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    • pp.55-64
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    • 1998
  • Using blind hole drilling method the residual stresses and welding deflections are measured for the cylindrical shell with various heat inputs and cylinder diameters. As a result, it is verified that the axial and hoop residual stresses which are generated near the weld part of cylinders are increased, as the heat inputs and cylinder diameters are increased. And experimental results show good agreements with those of precedent researchers. In this paper, it is validated that dominant parameters, heat input Q and the dimension of cylinder h/D have some effects on the magnitude and distribution of axial and hoop residual stresses and welding deflections. The empirical equations of residual stresses and welding deflections are made by using multiple linear regression with experimental results.

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Analysis of Organochlorine Pesticide Residues in the Presence of Polychlorinated Biphenyls (PCBs) -Part II. Analysis of River Sediments and Cultivating Soils in the Peripheries of Several Industrial Estates- (Polychlorinated Biphenyls(PCBs) 존재하(存在下)에 유기염소계(有機鹽素系) 살충제의 잔류분(殘留分) 분석(分析) -제2보(第2報), 공단주변(工團周邊)의 하천(河川) 및 전답토양(田畓土壤) 분석(分析)-)

  • Park, Chang-Kyu;Park, No-Dong
    • Applied Biological Chemistry
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    • v.23 no.1
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    • pp.58-63
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    • 1980
  • Present investigation is undertaken to evaluate residues of organochlorine pesticides and PCBs in river sediments and cultivated soils by GLC. Main sampling areas chosen were three industrial estates, Suwon, Iri and Kumi. Samples consist of river sediments and cultivated soils, in Suwon, Iri and Chilgok, which are likely to be accumulated with PCBs from nearby factories. Organochlorine pesticide residues were found in all sediments and soil samples while no PCBs residue was detected in all samples analyzed. The pesticide residues were greatest in the Suwon and least in Chilgok soils. p,p'-DDT and BHC isomers $({\alpha}-,\;and\;{\gamma}-)$ were found in all soil samples. p,p'-DDT, at the range of 0.006-0.840 ppm, was the most abundant residues among organochlorine insecticides.

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Characteristics of Shear Behavior According to State of Particle Bonding and Crushing (입자 결합 및 파쇄 형태에 따른 전단거동 특성)

  • Jeong, Sun-Ah;Kim, Eun-Kyung;Lee, Seok-Won
    • Journal of the Korean Geosynthetics Society
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    • v.10 no.2
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    • pp.1-12
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    • 2011
  • In order to analyze the influence of particle bonding and crushing on the characteristics of shear behavior, especially residual shear behavior of granular soil, ring shear test was simulated by using DEM(Discrete Element Method)-based software program PFC(Particle Flow Code). Total four models including two non-crushing models and two crushing models were created in this study by using clump or cluster model built in PFC. The applicability of Lobo-crushing model proposed by Lobo-Guerrero and Vallejo(2005) was investigated. In addition, the results of ring shear test were analyzed and compared with those of direct shear test. The results showed that the modelling of ring shear test should be conducted to investigate the residual shear behavior. The Lobo-crushing model cannot be applied to investigate the residual shear strength. Finally, it can be concluded that the numerical models excluding Lobo-crushing model suggested in this study can be used extensively for other studies concerning the residual shear behavior of granular soil including soil crushing.

Monitoring and Risk Assessment of Pesticide Residues on Stalk and Stem Vegetables Marketed in Incheon Metropolitan Area (인천광역시 유통 엽경채류 농산물의 잔류농약 실태조사 및 위해성 평가)

  • Park, Byung-Kyu;Jung, Seung-Hye;Kwon, Sung-Hee;Ye, Eun-Young;Lee, Han-Jung;Seo, Soon-Jae;Joo, Kwang-Sig;Heo, Myung-Je
    • Journal of Food Hygiene and Safety
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    • v.35 no.4
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    • pp.365-374
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    • 2020
  • This study was conducted to monitor the residual pesticides on a total of 320 stalk and stem vegetables from January 2019 to December 2019 in the Incheon metropolitan area. Pesticide residues in samples were analyzed by the multi-residue method for 373 pesticides using GC-MS/MS, LC-MS/MS, GC-ECD, GC-NPD and HPLC-UVD. Risk assessment was also carried out based on the amount of stalk and stem vegetables consumed. The linearity correlation coefficient for the calibration curve was 0.9951 to 1.0000, LOD 0.002 to 0.022 mg/kg, LOQ 0.005 to 0.066 mg/kg and recovery was 82.0 to 108.0%. According to the monitoring of pesticides, 36 (11.3%) of 320 were detected with pesticide residues and 3 (0.9%) samples exceeded the maximum residual limit. The detection frequency for Chinese chives and Welsh onion was higher than that for other stalk and stem vegetables. The frequently detected pesticides were etofenprox, procymidone, fludioxonil, and pendimethalin. As a tool of risk assessment through the consumption of pesticide detectable agricultural products, the ratio of estimated daily intake (EDI) to acceptable daily intake (ADI) was calculated in the range of 0.0062-24.1423%. These results indicate that there is no particular health risk through consumption of commercial stalk and stem vegetables detected with pesticide residues.

Evaluation of QuEChERS Method for Determination of pesticide Residues Using GC/NPD and GC/ECD (GC/NPD와 GC/ECD를 이용한 잔류농약 정량 분석법으로써의 QuEChERS의 평가)

  • Cho, Tae Hee;Park, Young Hye;Park, Hye Won;Hwang, Lae Hwong;Cho, In Soon;Kim, Min Jung;Kim, Hyun Jeong;Kim, Mu Sang;Chae, Young Zoo
    • The Korean Journal of Pesticide Science
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    • v.17 no.1
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    • pp.65-71
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    • 2013
  • The modified QuEChERS method was evaluated for rapid determination of pesticide residues in spinach by gas chromatography-nitrogen phosphorous detector (NPD) and electron capture detector (ECD). Fifty GC-amenable pesticides which were most frequently detected in monitoring were selected in the current study. Matrix-matched calibration was performed. The detector response for all pesticides was linear with determination coefficients higher than 0.995. LODs for most compounds ranged between 0.001 and 0.1 ug/g, and about 90% of the compounds had LODs of less than 0.05 ug/g. LOQs ranged from 0.001 to 0.32 ug/g, which were well below the MRLs permitted for most of pesticides. In the majority of cases, the recoveries (80-120%) and relative standard deviations (RSDs) (less than 20%) were within acceptable levels except for dichlorvos, propamocarb, chlorothalonil, dichlofluanid, cyhalothrin and fenvalerate. Also, this method which is applied to routine samples showed good results when comparing with traditional multi-residue method.

Enhancement of Analytical Method for Thidiazuron Residues and Monitoring of its Residues in Agricultural Commodities (농산물 중 thidiazuron 잔류분석법 개선 및 잔류실태 조사)

  • Do, Jung-Ah;Lee, Mi-Young;Park, Hyejin;Kwon, Ji-Eun;Cho, Yoon-Jae;Chang, Moon-Ik;Oh, Jae-Ho;Hong, Jin-Hwan
    • Korean Journal of Environmental Agriculture
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    • v.32 no.3
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    • pp.207-213
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    • 2013
  • BACKGROUND: This study was conducted to develop analytical method with reproducibility, accuracy and applicability to agricultural products than the existing methods. METHODS AND RESULTS: Mean recoveries of thidiazuron ranged from 89.2 to 91.2 in hulled rices, 87.2 to 92.1 in peppers, from 76.4 to 86.9 in potatoes, from 91.2 to 95.7 in watermelons, from 86.5 to 88.5 in kiwi fruits, and from 89.5 to 94.0 in grapes, with less than 10% of relative standard deviations. In addition, the limit of quantitation was set to be 0.05 mg/kg and there were no interfering peaks in integrating the thidiazuron peak. CONCLUSION(S): These results represent that the enhanced analytical method has reliable accuracy, precision, selectivity, and sensitivity.

A Study on Detection of Residual Solvent, Ethoxyquin and Color Stability in Oleoresin Paprika Extracts (파프리카 추출물의 색소안정성과 Ethoxyquin 및 잔류용매 검출)

  • Lee, Seon-Ok;Kyung, Suk-Hun;Park, Kil-Dong;Kang, Hee-Gon;Park, Joo-Sung;Lee, See-Kyung
    • Applied Biological Chemistry
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    • v.45 no.2
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    • pp.77-83
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    • 2002
  • Effects of ethoxyquin on the color stability of oleoresin paprika extracts and amount of residual ethoxyquin, a color stabilizer, in commercial extracts were determined. The oleoresin paprika extracts dissolved in ethanol gave the highest maximum photo-absorbency at 444-458 nm, with the color index of United States product 2-6 times higher than that produced in India. The residual solvents in oleoresin paprika extracts were mainly acetone and methanol, although some other extracts also contained small amounts of hexane. HPLC analysis was determined as a proper analytical method for residual ethoxyquin assay in the oleoresin paprika extracts, particularly when hexane was used as a solvent. The residual ethoxyquins were detected in the extracts produced in US and Spain which had relatively high color indices.