• Korean Chemical Engineering Research
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• v.58 no.4
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• pp.536-540
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• 2020

The support of the PEMFC membrane plays a key role in improving mechanical durability. The e-PTFE used as a support is chemically stable, so electro-chemical degradation in the PEMFC driving process has been rarely studied. In this study, we investigated whether e-PTFE is chemically stable to radicals and hydrogen peroxide during Fenton reaction. After the Fenton reaction, the main chain of e-PTFE broke, resulting in a change in the chemical structure and morphology of the support, resulting in a decrease in tensile strength. The results of this study showed that electrochemical degradation of the membrane ionomer in the PEMFC process occurs inside the membrane by radicals and hydrogen peroxide, so that electrochemical degradation may also occur at the e-PTFE support in the cell.

• Applied Chemistry for Engineering
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• v.10 no.5
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• pp.726-730
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• 1999

To investigate the deinkability according to the ink composition, deinking chemicals and aging time, newspaper was printed with different solvent types: 30% soy-based oil ink(A), 50% soy-based oil ink(B), 45% mineral oil ink(C) and 42% linseed oil ink(D). The newspapers were aged naturally for 15, 30, 90, 180 days, and were deinked with various deinking chemicals. The brightness of the deinked pulp of newspaper was affected by the ink composition, aging time and deinking chemicals, i.e., it was decreased with increasing aging time in the order of C, A, B and D. And the brightness also decreased in the order of lipase, cellulase and conventional chemical. The deinking yield showed the same tendency as the brightness variation at a given brightness. The strength of the deinked pulps increased until 30 days, but decreased or maintained after that time. And the strength decreased in the order of C, D, B and A, and also decreased in the order of lipase, conventional chemicals and cellulase.

• The Journal of the Korea institute of electronic communication sciences
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• v.16 no.1
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• pp.53-60
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• 2021

High voltage CV cables have been widely installed underground due to their convenience and urban aesthetics. However, cable accidents have occurred frequently owing to poor construction and natural degradations. This paper proposes the method to measure the multi parameter measurement for optimum diagnostics of high voltage cable connection parts and verifies its technical usefulness. This measurement is intended to diagnose degradations of cable connection parts by using simultaneous vibration and thermography as well as partial discharge(PD). The experiment in a shielded laboratory was carried out to verify the usefulness of the multi parameter measurement. The experiment defined the degradation of the cable connection part as 12 types, and produced each degradation sample. As a result of experiment, it was possible to check the correlation of vibration signals with regard to progress in some defects. In the case of thermography, the coherence with regard to the progress of some defects was found. We figure that the proposed method would be useful also in the noise environment.

• Journal of the Korean Wood Science and Technology
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• v.31 no.4
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• pp.38-43
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• 2003

This is the second in a series of reports on the evaluation of weathering durability of waterborne preservative treated wood by accelerated weathering. The leaching of copper from ACQ-, CCA-, and CuAz-treated samples during weathering was increased by UV irradiation, when compared between full weathering and water-only weathering. The FTIR spectra of the weathered ACQ-, CCA, CuAz-treated samples at 1731 cm^-1, 1625 cm^-1, 1510 cm^-1, which are related to the fixation of copper, were different from those of unweathered controls. This result means that UV irradiation can weaken the chemical bond between lignin and copper and/or extraction of lignin-copper complex can be occured when lignin erode away by weathering.

• Journal of the Korean Society of Hazard Mitigation
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• v.2 no.1 s.4
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• pp.143-152
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• 2002

The objectives of this paper were to obtain the fundamental data to analyze the causes of deterioration of 39 freeway concrete viaducts in Seoul metropolitan area. To investigate the degree of concrete deterioration, carbonation depth, soluble chloride concentration in hardened concrete and half-cell potentials of reinforcement were measured. The number of structures which carbonation depth penetrates to reinforcement was 25% of total. The model of carbonation .ate was induced to 3.92 $\sqrt{t}$, which was 5% faster than 3.727 $\sqrt{t}$ assumed 60% water-cement ratio, R=1 in that of kishitani. After measuring chloride concentration in concrete, it was concluded that about 24% of all readings on samples from concrete exceed the critical content to minimize the risk of chloride-induced corrosion. About 31% of the freeway viaducts structures had a value lower than -350mV(vs. CSE), so it could conclude that the excessive chloride concentration was the major cause of reinforcement corrosion. Among the structures which measured half-cell potentials less than -350mV, about 50% exceeds the maximum acceptable limit of chloride concentration.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.93-96
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• 2007

Recently, much attentions have been paid on the commercialization of PEMFC, especially for the applications of residential and portable. In order to achieve the early commercialization of PEMFC, thee are two hurdles to overcome. One is cost down and the other is improvement of durability of the system components. Numerous companies have tried to reduce the production cost and the main research topics have been changed from performance to durability improvement. In this work, acceleration test were performed to find and evaluate the main reason of degradation of the MEA(membrane-electrode assembly) which is one of the core component of the PEMFC system. Based upon the test results, a way to make durable MEA was suggested. Acceleration tests were made by applying high voltage of 1.2V to the several kinds of single cells to increase the growth of catalyst particles. Cell performance, ac-impedance and electrochemically active area measurements were made atfter every 8 hours of acceleration test. Degradations of catalyst and membrane were examined by SEM, TEM and XRD. Obtained results were discussed in terms of structural stability and loss of catalyt and ionomers in the electrode layer. In addition, the way to make highly durable MEA was suggested.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2010.04a
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• pp.437-440
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• 2010

연육 연도교에 주로 건설되는 초장대교량은 시설물 특성상 이용객들의 대피공간이 제약받고 태풍, 해일 등 자연재해에 노출이 많기 때문에 다른 공공시설물보다 재난에 취약한 구조물이다. 최근 공공시설물의 건설동향은 구조물이 장대화 되어가고 있어 재난 발생시 예상 위험이 점점 더 커지고 있다. 본 연구는 국내외 장대교량의 재난사고와 재난관리 사례연구를 통해 초장대교량에서 관리되어야 할 재난을 정의하였다. 초장대교량의 재난은 자연재해와 인적재해로 구분할 수 있는데, 자연재해로는 안개, 강설, 결빙, 강풍, 지진, 해일이 있으며 인적재해로는 교통사고, 화재, 테러, 선박충돌, 구조물 파괴 및 재료열화가 있다. 또한 초장 대교량에서 발생 가능한 모든 사고의 잠재가능성을 분석하여 가상의 재난관리 시나리오를 작성하였다. 이 시나리오는 예방, 대비, 대응 및 복구로 구분되는 관리단계별 실행계획 수립에 기초를 제공하게 될 것이다.

• Proceedings of the KIEE Conference
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• 2015.07a
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• pp.1184-1184
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• 2015

현재 XLPE 절연 케이블의 상시 운전 온도는 $90^{\circ}C$나 개발된 고내열성 절연재료의 상시운전온도는 $110^{\circ}C$로 향상되었다. 개발된 고내열성 절연재료는 XLPE 절연 케이블의 상시 운전온도($90^{\circ}C$)와 비상시운전온도($110^{\circ}C$), 고내열성 절연재료의 상시운전온도($110{\circ}C$), 비상시 운전온도($130{\circ}C$)을 바탕으로 하여 열 열화 온도와 기간이 설정되었다. 열 열화는 자연순환 건조기에서 설정된 온도와 기간 동안 수행되었고, 열 열화된 고내열성 절연재료는 Mckewon전극을 이용하여 AC파괴 시험이 진행 되었다. 파괴시험데이터는 와이블 분포함수를 이용하여 통계적으로 분석되었다.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.1021-1024
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• 2008

Near infrared heating as an alternative to the conventional heating techniques for thermography -NDT is tried in this paper. A concrete specimen containing a defect was heated by the near infrared ray and the thermography-NDT technique was applied. Using a dimensinless temperature, the defects were detected. It was found that the near infrared ray could efficiently heat up the concrete specimen compared to others conventional methods like lamps, heat flow, etc.

• Proceedings of the KIEE Conference
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• 2007.04b
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• pp.55-57
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• 2007

오일 변압기 내부의 절연물은 절연지, 프레스보드, 광유 또는 식물유가 주로 사용되고 있다. 사용 기간과 과부하 조건에 따라 열화정도가 달라질 수 있으며, 내부 절연물의 열분해 및 가수분해로 인해 수분은 자연스럽게 생성될 수 있다. 생성된 수분은 절연을 약하게 하는 주된 요인으로 작용해 기기의 고장 또는 정전을 초래할 수도 있다. 본 논문에서는 변압기 내부 절연물의 주파수응답 특성과 절연상태 값을 바탕으로 변압기 내부를 전기적 소자로 등가화하였다. 그 후 등가화된 회로를 이용해 회복전압법의 원리에 따라 EMTP 프로그램을 활용해 분극특성을 모의하였다. 실제 측정 값과의 비교를 위해 보고된 문헌의 데이터를 활용하였고, RVM을 이용한 실측값과 유사한 결과를 얻게 되었다. 따라서 본 시뮬레이션에 활용된 전기적 소자값을 변경함으로서 내부 절연물의 열화정도에 대한 기대 파형을 예측할 수 있는 유용한 도구로 활용될 수 있음을 확인하였다.