• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.840-843
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• 2009

폐자동차의 최종처분 과정에서 발생하는 자동차 파쇄 폐기물(Automobile Shredder Dust)은 대부분이 고분자 화합물로 높은 발열량을 가지고 있다. 또한 할로겐족 원소가 포함된 난연성 고분자류가 많아 다이옥신의 생성 우려가 높은 고분자류와 다이옥신 생성의 촉매 역할을 할 수 있는 금속성분이 많이 함유되어 있어 가스화용융시스템에 적용하여 처리하기에 매우 적합한 폐기물이다. 본 연구에서는 ASR의 가스화 용융 시설에서 고농도 CO를 함유한 합성가스를 수성가스전환반응(Water Gas Shift reaction, WGS)을 이용하여 수소의 수율을 높이는 기술을 제시하였다. 가스화 용융 설비에서 배출되는 합성가스 조성을 기준으로 적합한 고정층 WGS 반응기를 설계하고, 고온 촉매(KATALCO 71-5M)와 저온 촉매(KATALCO 83-3X)를 사용하여 실험하였다. 수성가스 반응 후의 가스 조성은 온도가 상승할수록 일산화탄소가 줄어들고 이에 따라 수소와 이산화탄소 발생량이 증가 되어 고온 촉매를 사용했을 경우 일산화탄소 전환율 ($1-CO_{out}/CO_{in}$)은 55.6에서 95.8%까지 상승하였다. 동일한 온도조건에서는 촉매에 관계없이 $CO/H_2$가 감소할수록 전환율도 감소하는 경향을 보였지만 동일한 합성가스 조성에서 일산화탄소 전환율을 비교하면 저온 촉매가 고온 촉매보다 매우 우수함을 알 수 있었다.

• Resources Recycling
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• v.14 no.3
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• pp.6-15
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• 2005

The overall area of Taiwan is 36,006 km$^2$ and population was about 22,535,000 persons in 2003. The population density became 625persons/km$^2$. The economic of Taiwan progress since 1970. Gross national production in 2004 increased by 2.3 trillion or 493% relative to 1981. The number of automobiles in 1981 was 821,862, and increase to 6,389,186 in 2004. The number of motorcycles in 1981 were 4,591,547 and increase to 12,793,950 in 2004. The vehicle growth rate of automobile and motorcycle was 677% and 178% respectively. The recycling end-of-life vehicles(ELVs) is specified in the Waste Disposal Act. Its main content is the system of asking the vehicle manufacturer and importing agents, who are responsible for recycling of the ELVs. The recycling task on ELVs was startedinitially in 1993. It is required that the manufacturers and importing agents deposit certain ratios of Waste Vehicle Disposal Fees proportional to the number of vehicle they manufacture and import into Taiwan under sales. This report will introduce the current status of ELVs recycling in Taiwan, and the future direction, as well as measures proceeding for the EPA- Fund Management Committee(RMFC) operating in the fiture.

• New & Renewable Energy
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• v.5 no.2
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• pp.9-14
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• 2009

Automobile Shredder Residue (ASR) is very appropriate in a gasification melting system. Gasification melting system, because of high reaction temperature over than $1,350^{\circ}C$, can reduce harmful materials. To use the gasification processes for hydrogen production, the high concentration of CO in syngas must be converted into hydrogen gas by using water gas shift reaction. In this study, the characteristics of shift reaction of the high temperature catalyst (KATALCO 71-5M) and the low temperature catalyst (KATALCO 83-3X) in the fixed - bed reactor has been determined by using simulation gas which is equal with the syngas composition of gasification melting process. The carbon monoxide composition has been decreased as the WGS reaction temperature has increased. And the occurrence quantity of the hydrogen and the carbon dioxide increased. When using the high temperature catalyst, the carbon monoxide conversion ratio ($1-CO_{out}/CO_{in}$) rose up to 95.8 from 55.6. Compared with average conversion ratio from the identical synthesis gas composition, the low temperature catalyst was better than the high temperature catalyst.

• Journal of the Society of Disaster Information
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• v.9 no.4
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• pp.476-483
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• 2013

In this study, discharged nylon fibers were added to asphalt concretes to be compared with fatigue life and analyzed in economic point of view. A four point bending fatigue test was conducted, and as a result, nylon fiber reinforced asphalt concretes that showed a 10percent increase in fatigue life compared to ordinary asphalt concrete. The economic analysis confirmed that the maintenance cost was decreased by 540 million won throughout the analyzing period. It is thought discharged nylon fiber reinforced asphalt will cause more economic and social effects than was shown by life cycle cost analysis.

• Journal of Korea Society of Waste Management
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• v.35 no.7
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• pp.660-669
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• 2018

Domestic automotive shredder residue (ASR) recycling facilities must comply with 60% of the energy recovery criteria calculated by the waste control act, based on resource circulation of electrical and electronic equipment and vehicles. The method of calculating energy recovery criteria was newly enacted on November 6, 2017, and it has been judged that it is necessary to consider applicability. In this study, the energy recovery efficiency of 7 units was calculated by past and present calculation methods. Furthermore, this study attempts to find applicability and a method of increasing the energy recovery efficiency by taking advantage of available potentials. An analysis of the calculation results showed that the average values calculated by past methods, present methods, and the method that includes available potentials are 76.35%, 70.68%, and 78.24%, respectively. Therefore, the new calculation method for energy recovery efficiency is also applicable to domestic automotive shredder residue recycling facilities.

• Resources Recycling
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• v.28 no.6
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• pp.96-105
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• 2019

Automobile shredder residue (ASR) is the final waste produced when end-of-life vehicles (ELVs) are shredded. ASR can be separated using mineral-processing operations such as comminution, air classification, magnetic separation, and/or electrostatic separation. In this work, trajectory analyses of conductors (copper) and non-conductors (glass) in the ASR have been carried out using induction electrostatic separator for predicting or improving the ASR-separation efficiency. From results of trajectory analysis for conductors, the trajectories of copper wire by observation versus simulation for coarse particles of 0.5 and 0.25 mm showed consistent congruity. The observed 0.06 mm fine-particles trajectory was deflected toward the (-) attractive electrode owing to the charge-density effects due to the particle characteristics and relative humidity. In the case of non-conductors, the actual trajectory of dielectric glass deflected toward the (-) electrode, showing characteristics similar to those of conductive particles. The analyses of stereoscopic microscope and SEM & EDS found heterologous materials (fine ferrous particles and conductive organics) on the glass surface. This demonstrates the glass decreasing separation efficiency for non-ferrous metals during electrostatic separation for the recycling of ASR. Future work will require a pretreatment process for eliminating impurities from the glass and advanced trajectory-simulation processes.