• Korean Chemical Engineering Research
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• v.58 no.1
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• pp.92-97
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• 2020

In this study, the solubilities of a pharmaceutical compound, nifedipine, in three mixed solvents were determined. In addition, the nifedipine, that was dissolved in solvents (acetone, DMF, methylene chloride), was recrystallized using antisolvents (water, hexane, carbon dioxide) The external shape, size, and melting point of the crystallized nifedipine were measured. As the mixed solvents, acetone+water, DMF+water, and methylene chloride+hexane were used, and the solubility of nifedipine decreased with increasing antisolvent concentrations in the mixtures. In case of acetone+water, the solubility maximum was observed due to the density anomaly of the mixture, and this phenomenon was not observed in other systems. The crystallized nifedipine particles exhibited the bladed, equant, and prismatic habits, and the particles size was significantly reduced compared to the raw material. The average particle size of raw nifedipine was 337 ㎛, and the size of crystallized particles was in the range of 11.6~69.8 ㎛. All the crystallized nifedipine particles had the same thermal behavior and this result was not influenced by the change of solvent and antisolvent.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.745-749
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• 2011

Two-dimemsional liquid-solid multiphase fluid dynamics was used to analyze the suspension and mix of liquid fuel and solid particles in fuel tank installed mixing impeller. In this paper, the multiphase flow was modeled using Eulerian Grandular Multiphase model. Experimental measurements of the axial distribution of solids concentration in stirred tanks under 12vol% solid loading were used for comparison with the CFD simulation. Four cases for the impeller location and flow pumping direction also were reviewed under 10.5% solids loading and 700rpm in fuel mix tank. The result of quality of suspension was compared with each cases and the impeller location and operation of mixing fuel tank was established.

• Membrane Journal
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• v.26 no.6
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• pp.463-469
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• 2016

In this research, a new expectation in enhancing the PES (polyethersulfone) polymer phase inversion membrane performances with nanoparticles is proposed by using ZnO. This paper investigated the synthesis of PES phase inversion membranes including ZnO nanoparticles and evaluates the performance of these mixed matrix membranes. The PES-ZnO mixed matrix membranes were fabricated by phase inversion method using the PES-ZnO-NMP(N-methyl-1-pyrrolidone) casting solutions with low ZnO nanoparticles content of 0.375 wt%. The influence of ZnO nanoparticles on the characteristics of PES-ZnO mixed matrix membranes was investigated with scanning electron microscope observations of membrane cross-sections, contact angle measurements, tensile strength measurements, pure water flux measurements and ultrafiltration experiments of BSA solution. Those results showed that the performance advancements in comparison with the pure PES membrane without ZnO in terms of increasing hydrophilicity as well as reducing membrane fouling by adding ZnO nanoparticles even in low concentration.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.157-163
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• 2011

Combustion of magnesium dust particle were fabricated test devices and combustion experiments were carried out. The ignition delay time were measured in change of magnesium particle mass flow rate in premixed flame. According to increasing magnesium particle mass flow rate, ignition delay time were more shorter. In addition, magnesium dust combustion temperature were measured different particle sizes and o/f ratio by two wavelength pyrometry. Dust combustion flame temperature is almost similarly, through to equivalence ratio, confirm the combustion flame temperature range characteristics.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.67-67
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• 2021

하구에서의 흐름은 하천의 담수와 바다에서부터 유입되는 염수, 조석, 파랑 등으로 인해 복잡한 흐름구조와 혼합 양상을 보인다. 특히 만 내에 하천이 있을 경우 만의 해류특성은 하구에서의 혼합과 이송에 지배적인 영향을 미치며, 하천에서부터 방류되는 입자들은 만의 해류특성 따라 만에서의 체류시간과 이송이 결정된다. 잔차류 특성에 의한 순 물질 플럭스의 방향과 조석비대칭에 따른 하구에서의 퇴적 형태들이 결정되며, 이로 인해 하구에서의 퇴적물 퇴적 및 물질의 집적 위치, 하구 인근과 만에서의 환경변화에 영향을 줄 수 있다. 따라서 만 내에서의 혼합과 입자의 이송확산, 하천 담수의 영향역 등과 같은 만과 하천의 흐름 특성을 이해하는 것은 연안 및 하구의 환경 및 관리에 중요하다. 본 연구에서는 영일만과 형산강을 대상으로 계절변화에 따른 영일만 내 흐름과 형산강 하구에서의 퇴적양상에 대해 수치모의를 통해 수행하였다. 수치모델로는 천수방정식으로 준 3차원 유동해석을 하는 Delft-3D Flow와 파랑모형인 SWAN 모델을 결합하여 형산강 하구와 영일만의 유동을 해석하였다. 상류개방경계는 형산강하구 9 km, 하류개방경계는 영일만 외해 50 km로 설정하였고, 경계조건은 대상지역의 관측소 자료와 전지구 모형자료를 결합하여 구성하였다. 또한, 라그랑쥬 입자추적모델을 통해 형산강 상류에서 유입한 입자들의 영일만 내 체류 시간과 집적 위치를 평가하였다.

• Applied Chemistry for Engineering
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• v.35 no.2
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• pp.96-99
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• 2024

A sintering paste for bonding copper plates was synthesized using Cu formate nanofibers on Cu microparticles, mixed with formic acid. Copper oxide nanofibers of 10 ㎛ grown at 400 ℃ on Cu microparticles on the surface were transformed into copper formate nanofibers through the mixing of formic acid. Compared to Cu bulk particles or nanoparticles, Cu formate on Cu microparticles decomposed into metallic Cu at a lower temperature of 210 ℃, facilitating the sintering of copper paste. The growth of nanofiber on Cu microparticles allowed for an increase in the reaction rate of formation to copper formate, aggregating surface area, and decomposition rate of copper formate, resulting in fast sintering.

• Proceedings of the Korean Fiber Society Conference
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• 2003.04a
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• pp.436-437
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• 2003

고형오구의 분산안정화 작용은 고체 입자의 계면에 흡착한 계면활성제에 의한 전기적 반발력과 입체적 보호작용에 영향을 받게 된다. 특히 현재 시판세제의 조성에서 비이온계 계면활성제의 혼합이 점차 중요시되는 이때 입체적 보호작용에 의한 고형오구의 분산안정성은 의류제품의 세척성 제고에 좋은 정보가 되리라 생각된다. 따라서 본 연구는 시판되고 있는 세제 대부분이 음-비이온계 계면활성제의 혼합으로 되어 있는 점을 고려하여 음이온 계면활성제로서 D5S(sodium dodecyl benzene sulfonate), 비이온계 계면활성계 NPE(nonyl phenol polyoxyethylene ether, EO$_{10}$) 혼합용액에서 음이온과 비이온계 계면활성제의 입자에의 흡착과 고형오구의 안정성을 관련시켜 고찰하였다. (중략)

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07b
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• pp.1278-1282
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• 2004

수열처리법으로 nano-sized $CeO_2$ 입자를 $Al_3O_3$ 입자의 표면에 균일하게 코팅하여 $AL_2O_3/O_2$ composite 연마 입자를 제조하었다. 제조된 $Al_2O_3\CeO_2$ composite 입자의 뭍성을 TEM, XRD, zeta potential analyzer 및 particle size analyzer로 측징하였다. $Al_2O_3/CeO_2$ composite 입자와 구성된 슬러리와 비교 시료로서 $Al_2O_3$와 $CeO_2$ 입자를 혼합한 슬러리를 사용하여 thermal oxide film에 대한 연마특성을 평가하였다. 연마슬러리에 포함된 $A1_2O_3/CeO_2$ composite 입자와 $Al_2O_3$와 $CeO_2$ 혼합입자에서 나노 크기의 세리아 입자가 sub-micron 크기의 알루미나 입자의 표면에 균일하게 코팅되므로서 $Al_2O_3$ 단일 성분의 슬러리에 비해 removal rate(RR)는 106 nm/min, WIWNU는 $8\sim9%$, roughness는 $2.6{\AA}$의 향상된 연마 특성을 나타내었다. 알루미나 입자의 불규칙한 형상 때문에 $Al_2O3/CeO_2$ composite 슬러리와 $Al_2O_3$ 와 $CeO_2$ 혼합슬러리의 연마 특성이 비슷한 수준을 나타내었다.

• Journal of the Korean Magnetics Society
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• v.26 no.4
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• pp.129-132
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• 2016

The effect of thermal-nitrification on L1o transfomation in nano-sized FePt particles was studied. As-synthesized FePt nanoparticles by thermal decomposition method have fcc structured phase and their Hc and Ms were 247.34 Oe and 27.308 emu/g, respectively. According to the XRD analysis, phase transformation from fcc (face centered cubic) to fct (face centered tetragonal) structure was revealed by heating under $NH_3+H_2$ mixed-gas atmosphere. Also a slight shift of each (111) peak indicated phase transformation from fcc to fct structure. Hc and Ms of fct FePtN were 1058.2 Oe and 32.718 emu/g, respectively. The nano-sized FePtN magnetic particles synthesized by thermal decomposition method and mixed-gas nitrification are expected for advanced applications such as high density magnetic recording media and biomedical materials.

• Polymer(Korea)
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• v.26 no.6
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• pp.803-811
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• 2002

In this study the wear behavior of ultra high molecular polyethylene (UHMWPE) filled with kaolin particles by different methods was investigated. UHMWPE/kaolin composites were prepared by two different methods: polymerization-filling and powder mixing. Particularly in a powder mixing method. Particle dispersion and wear property according to powder mining method were examined. It was found from wear test that filling of inorganic filler into UHMWPE by polymerization filling was more effective way than by powder mixing method in improving Wear resistance of UHMWPE. It was also confirmed that abrasive wear was dominant wear mechanism and particle dispersion in the composite as well as interface property was an important factor in controlling the wear behavior of the resulting composites.