• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.12 no.3
• /
• pp.149-156
• /
• 2002

Europium-activated $Ga_2O_3$ phosphor powders were prepared by homogeneous precipitation method. The resulting powders were characterized by means of TG/DTA, XRD, FT-IR and SEM, Two kinds of powders formed were the crystalline GaOOH and the amorphous-like $\gamma$-$Ga_2O_3$ phases. When the urea concentration was below 0,5 M, rod-like micrometer-sized GaOOH powders were formed. They were transformed via $\alpha$-$Ga_2O_3$ to $\beta$-$Ga_2O_3$ phases under heat treatment. On the other hand, the nanometer-sized $\gamma$-$Ga_2O_3$ powders were formed with urea concentrations higher than 1.0 M, and they were directly changed into $\beta$-$Ga_2O_3$.Photoluminescence (PL) spectra were observed at room temperature, and PL intensities of nanometer-sized $Ga_2O_3$ : $Eu^{3+}$ powders around 610 nm were higher than those of micrometer-sized ones.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2011.05a
• /
• pp.176-176
• /
• 2011

환형수조는 점착성 퇴적물의 이송특성 연구를 위해 가장 선호되는 실험 장치로 알려져 있다. 과거 많은 연구자들은 퇴적물의 이송특성, 특히 침식/퇴적 특성 조사를 위해 주로 수로를 이용한 실험적 연구를 수행하였는데, 최초의 실험적 연구들은 주로 직선수조에서 수행되었다. 그러나 입자간의 응집이 중요한 역할을 하는 점착성 퇴적물의 경우에, 직선수조 끝단에서의 자유낙하 및 재순환 펌프의 날개에 의해 응집된 토사가 쉽게 분리될 수 있어 그 타당성이 의문시 되어 왔으며, 이러한 단점을 보완하기 위해 환형수조가 고안되었다. 환형수조는 수면과 접하여 회전하는 상부링의 마찰력에 의해 흐름이 생성되기 때문에 시간의 제약 없이 흐름조건을 동일하게 만들 수 있다는 큰 장점을 갖는다. 그러나 환형수조는 원주유속의 속도차이 및 원심력으로 인한 2차 순환류를 형성시켜 반경 방향(radial direction)에서의 바닥전단응력을 불균일하게 하는 단점을 갖는다. 이러한 2차 순환류와 바닥전단응력의 불균일을 저감시키기 위하여 환형수조의 몸체를 상부링의 회전 방향과 역방향으로 직접 회전시키는 방법이 채택되어져 왔다. 한편, 환형수조의 상부링과 몸체를 서로 역방향으로 동시에 회전시키는 양방향 회전(counter-rotation)의 적용을 위해서는 2차 순환류가 최소가 되며 바닥전단응력이 균일해지는 최적 회전속도비에 대한 분석은 필수적 사항이다. 이를 위하여, 상부링과 몸체의 회전속도에 따라 변화하는 수조내부의 흐름특성 및 평균바닥전단응력에 대한 연구가 선행되어야만 한다. 이에 본 연구에서는 전산유체역학을 이용하여 전북대에 설치된 환형수조의 상부링과 몸체의 회전속도에 따라 변화하는 수조내부에서의 흐름특성 및 바닥전단응력에 대한 분석이 수행되었다. 또한, 이를 기초로, 환형수조의 최적 회전속도비 산출을 위한 연구가 수행 중에 있다. 이러한 결과들은 추후 환형수조를 이용한 점착성 퇴적물의 침식/퇴적 등과 같은 이송특성 연구시, 퇴적물에 작용하는 흐름조건의 정밀산정을 위한 기초자료로 활용될 수 있을 것이다.

• Polymer(Korea)
• /
• v.28 no.2
• /
• pp.154-161
• /
• 2004

Modified poly(4-vinylpyridine) was obtained by partial quarternization of nitrogen atoms in pyridine rings of poly(4-vinylpyridine) with methyl group. By means of laser light scattering and fluorescence, it was found that this modified polymer chains were aggregated in the aqueous solution and its structure was core-shell type. The hydrophobic parts of the chains were densely condensed in core part and the hydrophilic part of quarternized amino with positive charge formed the shell part. In the mixed system of modified poly(4-vinylpyridine) and anionic surfactant, sodium dodecyl sulfate, it was observed that a critical aggregation concentration existed and that this critical concentration was suddenly decreased above 0.1 M NaCl. The size change of aggregates was also investigated by dynamic light scattering while sodium dodecyl sulfate was added into polymer solution upto the critical aggregation concentration.

• Membrane Journal
• /
• v.18 no.1
• /
• pp.53-64
• /
• 2008

Fouling behavior of polyethylene capillary membranes was examined by measuring the flux of bentonite colloidal suspensions through the cross flow micro filtration. The membrane fouling was due to the three mechanisms: the cake formation on the membrane surface, the standard pore blocking and the complete pore blocking by particles. These mechanisms were simultaneously responsible for the membrane fouling, being significantly governed by the cake filtration. In the total fouling at $1.0kg/cm^2$ TMP condition, the complete blocking was 3.36%, the standard blocking 3.18% and the cake filtration 96.05%. For 1000 ppm feed solution, the complete blocking was 1.71% compared with the standard blocking of 1.90% and the cake filtration of 96.39%. And 96.14% of the total fouling was generated at the initial period of filtration. The cake filtration effect was larger on $0.34{\mu}m$ pore membrane than on $0.24{\mu}m$ pore membrane. With the increase in cross flow velocity, the component fouling decreased by 10.20%, and the ratio of pore blocking to total fouling increased.

• Korean Journal of Materials Research
• /
• v.11 no.1
• /
• pp.61-66
• /
• 2001

$TiO_2$films for photocatalytic reaction were synthesized by anodizing process. The photocatalytic efficiencies of anodized $TiO_2$were evaluated by the rate of decomposition of aniline blue. The properties of photocatalysis on anodic $TiO_2$films have been observed, but the efficiencies of photocatalytic reaction depended on the conditions of films formation. The microstructure of the anodic film formed in $H_2SO_4$ solution differed from that of $TiO_2$films formed in $H_2SO_4+H_3PO_4$ solution. It has been shown that the appropriate applied-voltage for anodizing of titanium for photocatalysis was 180V in both aqueous solutions.

• Proceedings of the Korea Society of Environmental Toocicology Conference
• /
• 2003.10a
• /
• pp.151-151
• /
• 2003

토양에 방치된 농업용 폐비닐은 거의 분해가 되지 않으며, 수분과 공기의 유통을 차단하고 토양 내 미생물들의 흐름을 막아 토양을 더욱 황폐화시키게 된다. 불법적인 소각 때는 산불의 위험에다 다이옥신, 염소 및 염화수소가스 등을 배출해 대기오염을 유발시킨다. 폐비닐을 열분해과정으로 처리하여 아주 작은 입자로 미분쇄하고 겔상태로 용융된 원료물질속으로 완전히 균일하게 혼합하여 골재로 활용하는 과정에서 가스상과 액상의 여러 가지 중간생성물질이 발생하게 되며, 농약의 살포에 의한 잔류농약 둥 인체에 유해가능한 요소들이 있을 수 있다. 본 연구에서는 개발공정이나 제품에서 인체에 영향을 미칠 수 있는 물질에 대하여 유해성을 평가하고 용응 겔 및 가스와 오일에 함유된 화학성분을 분석하였기에 보고하고자 한다 시험동물의 혈액생화학적 검사에서는 농업용 폐비닐물질 및 열분해 파생물질의 혈청 Cholesterol, 혈청 Alanine aminotranseferse와 Aspartate aminotransferse, Albumin 수치, LDH, Glucose, Uric acid, A/C 비 등의 생화학적 활성도를 측정한 결과들에서는 농업용 폐비닐물질을 투여한 시험군에서 나타난 결과와 비교하여 열분해 파생물질을 투여한 시험군에서 나타난 결과가 감소된 통계결과를 보였다. 이 결과들은 농업용 폐비닐물질을 투여한 시험군보다 열분해 파생물질을 투여한 시험군의 외부독성물질 투여에 의한 생체독성의 영향과 생체에 가해진 스트레스강도가 작았음을 의미하는 것이다. 잔류농약분석에서는 시료로부터 농약을 추출하는 용매추출과정, 시료추출물 중 공존하는 방해성분을 제거하는 정제과정, 폐비닐물질 및 열분해 파생물질 성분을 100mg/kg 이상군의 투여 후 시험동물의 부검시 모든 투여군에서 독성소견이 인정되지 않았다. 이와 같은 결과로 열분해 및 연소과정에서 발생하는 파생물질의 분석결과를 응용하여 대기오염을 방지하고 인체 유해물질을 차단하는 공해 방지 설계의 기초자료를 제안하고자 한다.

• Journal of Korean Society for Atmospheric Environment
• /
• v.11 no.1
• /
• pp.37-44
• /
• 1995

Concentration of particulate nitrate classified by formation mechanism and particle diameter in ambient air was determined from Feb. to Oct. 1993. Sampling was carried out using a two-stage Andersen air sampler at the top of a five-story building located at Kon-Kuk University in seoul. Concentration of N $H_{4}$N $O_{3}$ in TSP was measured by pyrolysis of sample filters at 160.deg.C for 1hr. concentration of N $H_{4}$N $O_{3}$ was higher in winter time compared with that in summmer time. Also, concentration of N $H_{4}$N $O_{3}$ was higher in fine particles compared with that in coarse particle. The range of N $H_{4}$N $O_{3}$ concentration was between 2.9 and 9.9.mu.g/ $m^{3}$. Weight fraction of N $H_{4}$N $O_{3}$ in total particulate nitrate was 31.1 .sim. 59.5%, and weight fraction of N $H_{4}$N $O_{3}$ in TSP was 2.1 .sim. 11.2%. Concentration of NaN $O_{3}$, which originated from sea salt, was highest in spring time and lowest in summer time,and the concentration range was between 0.1 and 0.7.mu.g/ $m^{3}$. NaN $O_{3}$/TSP ratio was very low (0.1 .sim. 0.4%) indicating that the portion of NaN $O_{3}$in TSP was negligible. Concentration of particulate nitrate originated from soil was 2.4 .sim. 2.9.mu.g/ $m^{3}$. Weight fraction of that in total particulate nitrate was 14.0 .sim. 37.1%.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.37 no.3
• /
• pp.313-318
• /
• 2013

Magnetic abrasive polishing is an advanced deburring process for nonmagnetic materials and micropattern products that have non-machinability characteristics. Despite these advantages, there are some problems with using MAP for deburring. MAP has introduced geometric errors into microgrooves because of an over-cutting force caused by uncontrolled magnetic abrasives in the MAP tool. Thus, in this study, to solve this problem, an EP (electrolyte polishing)-MAP hybrid polishing process was developed for deburring microgrooves in an STS316 material. In addition, an evaluation of EP-MAP for the deburring of microgrooves was carried out by profiling the burrs. The results of the experiment showed geometric errors after the deburring process using MAP. However, in the case of EP-MAP, no geometric error was observed after the process because of the lower material removal rate in EP-MAP.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.35 no.12
• /
• pp.1641-1646
• /
• 2011

The second-generation magnetic abrasive polishing is one of the nontraditional machining technologies newly developed. Because of the flexibility effect in magnetic abrasive polishing, the precise and mirror like surface can be obtained during this process. In this study, magnetic abrasive polishing process was applied in small grooved surface. As a result, it was seen that the flexible magnetic abrasive tool was effective to remove burrs on the edge of the groove. However, the efficiency of magnetic abrasive polishing at the slot was very low according to increasing depth and width of slot. So, correlation between geometric parameters, such as the depth and width, and surface roughness was evaluated and the minimum width for suitable polishing was found by experimental results.

• Korean Journal of Materials Research
• /
• v.5 no.8
• /
• pp.905-912
• /
• 1995

Influences of the starting salts on the phase and morphology of the Pb(Zr, T)O$_3$powders prepared by ultrasonic spray pyrolysis were studied. The Phases of the Powders Prepared from the combination of metal nitrate(or oxynitrate), acetate(or oxyacetate), and alkoxide were the Pb(Zr, Ti)O$_3$with or without minor PbTiO$_3$. The pores on the surface of the spherical particles increased with the nitrate content in the starting solution and their formation was thought to result from the decomposition characteristics of metal nitrate. Pb acetate, Zr oxyacetate, Ti oxynitrate, and Ti (isopropoxide+acetylacetonate) was suitable as the starting salts for the preparation of Pb(Zr, Ti)O$_3$powders by ultrasonic spray pyrolysis in the viewpoint of the phase and morphology of the powders.