• Title/Summary/Keyword: 입자 강화 복합재료

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Thermal and Mechanical Properties with Hydrolysis of PLLA/MMT Nanocomposite (PLLA/MMT 나노복합재료의 가수분해에 따른 열적, 기계적 물성)

  • Lee Jong Hun;Lee Yun Hui;Lee Doo Sung;Lee Youn-Kwan;Nam Jae-Do
    • Polymer(Korea)
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    • v.29 no.4
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    • pp.375-379
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    • 2005
  • The morphology and therma]/viscoelastic characteristics were investigated for PLLA/MMT nanocomposite manufactured by incorporating inorganic nanosized silicate nanoplatelets into biodeuadable poly(l-lactic acid) (PLLA). The XRD difiactogram and TEM image may be regarded as a formation of homogeneously dispersed nanocomposites. The melting energy(${\Delta}H_m$) was increased during hydrolysis process because of increase of crystallinity. As MMT played a role of reinforcing agent, the storage modulus was increase in case of PLLA/MMT nanocomposite, it was well coincided with our previous results. From SEM image, many tiny pinholes formed by spinodal decomposition were observed on the surface, and the shape of nanocomposite was maintained during hydrolysis process. In this study, it was shown that the control of biodegradation rate, thermal/mechnical property was possibile by incorporating MMT.

Reheating Process of Particulates Reinforced Metal Matrix Composites for Thixoforming (Thixoforming을 위한 입자강화형 금속복합재료의 Reheating 공정)

  • 이동건;안성수;강충길
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.04a
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    • pp.218-223
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    • 2000
  • A both mixing process of electro-magnetic stirring and mechanical process technique were used to fabricate particulate metal matrix composites(PMMCs) for variation of particle size. The PMMCs were tested for their tensile test for with and without heat treatment with T6. PMMCs fabrication processing conditions for both electrical and mechanical process are also suggested. In order to thixoforming of PMMCs, fabricated billet are reheated by using the optimal coil designed as a function of length between PMMC billet and coil surface, coil diameter and billet length. The effect of reinforcement distribution on billet temperature variation are investigated with calculated solid fraction theory proposed as a function of matrix alloy and volume fraction of reinforcement.

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A Micromechanics-based Elastic Model for Particle-Reinforced Composites Containing Slightly Weakened Interfaces (미소한 손상경계면을 갖는 입자강화 복합재료의 미세역학 탄성 모델에 관한 연구)

  • Lee, Haeng-Ki;Pyo, Suk-Hoon
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2007.04a
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    • pp.441-444
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    • 2007
  • This paper presents a part of micormechanics-based elastic modeling (Lee and Pyo, 2007) of particle-reinforced composites containing slightly weakened interfaces. The Eshelby's tensor for a damaged ellipsoidal inclusion to model particles with slightly weakened interfaces is incorporated into a micormechanical formulation by Ju and Chen (1994). A damage model in accordance with the Weibull's probabilistic function is also developed to simulate the progression of weakened interface in the composites.

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Propagation of Elastic Waves in Fiber Reinforced Composites (섬유강화 복합재료 내의 탄성파 전파)

  • Kim, Jin-Yeon
    • The Journal of the Acoustical Society of Korea
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    • v.15 no.5
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    • pp.65-72
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    • 1996
  • A dynamic self-consistent method previously proposed and validated for the composites containing spherical inclusions is applied to the simplest two dimensional problems : SH wave propagation in unidirectional fiber reinforced composites. The self-consistent conditions for SH wave are derived without limitation on frequency and the wave speed and coherent attenuation are calculated for two composites. THe results of the present theory are compared with those of the multiple scattering theories and another self-consistent theory. At low volume fractions, the present theoretical results coincide with those of the multiple scattering theory using exact pair-correlation function, whereas the results based on another self-consistent theory deviate markedly from the others. As the volume fraction increases, the three theories give different results although they have qualitatively similar trends. The present theoretical results for composites considered in this paper exhibit less dispersion and physically realizable attenuation. An important observation is that the multiple scattering theory predicts vanishingly small attenuation at low frequency with volume fraction is high.

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Interfacial Characteristics of Polymeric Composite Materials (고분자 복합재료의 계면특성)

  • Park Soo-Jin;Seo Min-Kang
    • Polymer(Korea)
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    • v.29 no.3
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    • pp.221-230
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    • 2005
  • Interfacial interactions and interphases played a key role in multicomponent materials irrespectively of the number and type of their components or their actual structure. They were equally important in particulate filled polymer, polymer blends, fibers-reinforced advanced composites, nanocomposites or biomimetic materials. Recognition of the role of the main factors influencing interfacial adhesion and proper surface modification could lead to significant progress in many fields of research and development, as well as in related technologies. Although the role and importance of interfaces and interphases were the same for all multicomponent materials, the surface modification could be always selected according to the objectives targeted, as well as to the characteristics of the particular system. In this wort therefore, several types of surface modification were performed to improve the interfacial interactions between two components in composite system and their results for the composites were investigated.

Fabrication and Mechanical Properties of $SiC_p/Al$ Composites by Pressureless Infiltration Technique (무가압침투법에 의한 $SiC_p/Al$ 복합재료의 제조 및 기계적 특성)

  • Jin, H.G.;Oh, M.S.;Kim, Y.S.
    • Journal of Power System Engineering
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    • v.5 no.4
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    • pp.74-81
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    • 2001
  • The infiltration behavior of molten Al-alloy, microstructures, hardness, and the interfacial reactions of $SiC_p/Al$ composites fabricated by the pressureless infiltration technique were investigated. It was made clear that both the weight fraction of SiC reinforcement and additive Mg content considerably influenced on the infiltration behavior of the molten Al-alloy matrix. Complete infiltration of molten Al-alloy achieved under the conditions that weight fraction of SiC content is more than 30wt%, and additive Mg content is more than 9wt%. Interfacial region of Al-alloy matrix and SiC reinforcement phase, $Mg_2Si$ was formed by the reaction between Mg and SiC. Another reaction product AlN was also formed by the reaction between Al-alloy matrix and gas atmosphere nitrogen.

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Study on Erosion of Carbon Fiber Reinforced Plastic Composite (탄소섬유강화복합재료의 마식에 관한 연구)

  • Kim, Am-Kee;Kim, Il-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.2
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    • pp.291-297
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    • 2008
  • The solid particle erosion behaviour of unidirectional carbon fiber reinforced plastic (CFRP) composites was investigated. The erosive wear of these composites was evaluated at different impingement angles ($30^{\circ}$, $45^{\circ}$, $60^{\circ}$, $90^{\circ}$), different impact velocities (40, 55, 60, 70m/s) and at three different fiber orientations ($0^{\circ}$, $45^{\circ}$, $90^{\circ}$). The erodent was SiC sand with the size $50-100{\mu}m$ of irregula. shapes. The result showed ductile erosion behaviour with maximum erosion rate at $30^{\circ}$ impingement angle. The fiber orientations had a significant influence on erosion. The erosion rate was strongly dependent on impact velocity which followed power law $E{\propto}\;V^n$. Based on impact velocity (V), impact angle (${\alpha}$) and fiber orientation angle (${\beta}$), a method was proposed to predict the erosion rate of unidirectional fiber reinforced composites.

Fabrication of $Al_2O_{3p}/Al$ composites by in-situ Reaction Process of Molten Al (In-situ 반응에 의한 $Al_2O_{3p}/Al$기 복합재료의 제조)

  • 김재동;정해용;고성위
    • Composites Research
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    • v.12 no.3
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    • pp.36-44
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    • 1999
  • The fabrication process of $Al_2O_{3p}/Al$ composite by in-situ process was investigated. The effects of processing variables such as addition type and content of Mg, processing temperature and time on the infiltration behavior of molten Al, microstructure and hardness were investigated. When the pure Al was infiltrated into mixtures of Mg and $Al_2O_3l$ powder, processing temperature required to spontaneous infiltration was decreased, and the content of Mg was the most powerful variable for infiltration of molten Al. But when the Al-Mg alloy was infiltrated into $Al_2O_3l$ particles, infiltration ratio indicated nearly same value regardless of Mg content in alloy and processing temperature, and critical processing temperature required to spontaneous infiltration was $800^{\circ}C$. The $Al_2O_{3p}/Al$ composites which were fabricated by mixtures of Mg and $Al_2O_3l$ powders resulted in high hardness value, but hardness values were scattered due to non uniform dispersion of $Al_2O_3l$ particles by excessive reaction of Mg.

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Plasma Treatment of Carbon Nanotubes and Interfacial Evaluation of CNT-Phenolic Composites by Acoustic Emission and Dual Matrix Techniques (음향 방출과 이중 기지 기술을 이용한 탄소나노튜브의 플라즈마 처리 효과에 따른 탄소나노튜브-페놀 복합재료의 계면특성 평가)

  • Wang, Zuo-Jia;Kwon, Dong-Jun;Gu, Ga-Young;Lee, Woo-Il;Park, Jong-Kyoo;Park, Joung-Man
    • Composites Research
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    • v.25 no.3
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    • pp.76-81
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    • 2012
  • Atmospheric pressure plasma treatment on carbon nanotube (CNT) surfaces was performed to modify reinforcement effect and interfacial adhesion of carbon fiber reinforced CNT-phenolic composites. The surface changes occurring on CNT treated with plasma were analyzed by using Fourier transform infrared spectroscope (FT-IR). The significant improvement of wettability on CNT was confirmed by static contact angle test after plasma treatment. Such plasma treatment resulted in a decrease in the advancing contact angle from $118^{\circ}$ to $60^{\circ}$. The interfacial adhesion between carbon fiber and CNT-phenolic composites increased by plasma treatment based on apparent modulus test results during quasi-static tensile strength. Furthermore, the proposed database offers valuable knowledge for evaluating interfacial shear strength (IFSS).

A Study on the Elastoplastic Behavior and Yield Surface of Polymer Nanocomposites by Molecular Dynamics Simulations (분자동역학 전산모사를 이용한 나노입자 복합재의 탄소성 거동과 항복 예측에 관한 연구)

  • Yang, Seung-Hwa;Yu, Su-Young;Cho, Maeng-Hyo
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2010.04a
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    • pp.558-561
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    • 2010
  • 본 연구에서는 나노복합재의 탄소성 거동과 항복응력을 예측하기 위해 분자동역학 전산모사를 수행하였다. 나일론 기지와 실리카 나노입자가 포함된 단위 셀 구조로부터 나노입자의 체적분율 변화에 따른 응력-변형률 선도를 등변형률을 적용한 등온등압 앙상블 전산모사로부터 도출하였다. 4%의 변형률 범위에서 나노복합재의 탄성계수를 도출하였고, 이를 이용하여 2% 오프셋 방법으로 항복응력을 예측하였다. 나노입자의 유무에 따른 항복평면의 변화와 고분자 재료에서 나타나는 정수압 효과가 항복평면에 미치는 영향을 확인하기 위해 일축 인장/압축 그리고 이축 인장/압축을 수행하였고, 각각의 경우에 나타나는 나노복합재 내부의 자유체적 변화에 대한 분석을 통해 나노입자의 강화효과를 고찰하였다. 또한 고분자 기지로 인해 발생하는 정수압 효과를 반영한 von-Miss 항복평면을 도출하고, 입자의 체적분율 변화에 따른 항복응력의 예측이 가능하도록 정수압효과에 대한 파라메터를 체적분율의 함수로 근사하였다.

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