• Title/Summary/Keyword: 입자물질부착

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Inverse Gas Chromatography(IGC)를 이용한 소수성 MCC의 열역학적 표면 특성 분석

  • Lee, Hak-Rae;Lee, Jin-Hui;Park, Il;Lee, Yong-Min;Han, Sin-Ho;Jo, Jung-Yeon
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2001.11a
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    • pp.21-21
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    • 2001
  • 자원재활용과 원가절감를 위해 고지재활용율이 크게 상승하고 있으며, 이와 아울러 고 지원료로부터 고품질의 제품을 생산할 수 있는 기술에 대한 관심이 증대되고 있는 실 정이다. 저급 고지로부터 고품질의 탈묵펄프를 얻기 위해서는 고지재활용공정의 핵심 공정인 부유부상 공정의 효율화가 가장 중요하다고 믿어진다. 이를 위해서는 부유부상 공정에 가장 큰 영향을 미치는 고형입자의 표면 화학적 특성에 따른 공정의 분리효율 평가와 이에 근거한 공정해석과 개선이 요청된다. 이러한 부유부상 공정을 표면화학적 측면에서 구명하기 위해 마이크로 크리스탈린 셀룰로오스(Microcrystalline cellulose: M MCC)를 모댈 물질로 사용하여 표면화학적 특성은 다르나 입자의 크기와 형태는 동일 한 시료를 준비하였다. 친수성의 표면 특성을 나타내는 MCC의 표면 특성을 바꾸기 위 하여 AKD(alkyl ketene dimer)로 처리비율을 달리하여 솔벤트 사이징 처리를 실시하 였다. 이렇게 준비된 MCC의 표면화학적 특성을 IGC를 이용하여 평가하였다 .. IGC는 G GC를 응용한 표면분석 기술로 고체의 물리화학적 특성과 흡착성을 분석하기 위해서 사용되며 이로부터 흡착제의 표면특성을 평가할 수 있다. 본 실험에서는 AKD로 소수화 정도가 다르도록 소수화시킨 MCC 시료를 이용하여 I IGC 칼럼을 준비하고 n-알칸과 몇가지 극성 용매률 이용하여 이들의 칼럼 내 체류시 간을 측정함으로써 흡착특성을 평가하고 이로부터 흡착현상을 열역학적으로 분석하였다. IGC 분석 시에는 칼럼의 온도를 $30^{\circ}C$, $35^{\circ}C$, $40^{\circ}C$의 3수준으로 변화시켰다. 측정결 과로부터 MCC 표면의 흡착자유에너지와 엔탈피, 엔트로피의 변화량을 평가하였으며, 또한 MCC 표면의 극성에너지와 산염기적 성질을 평가하였다. 실험결과 MCC의 소수화도에 따른 열역학적 흡착현상의 차이가 명백하였다. 이는 소 수화 수준에 따라 소수성 및 친수성 물질의 흡착성이 변화된다는 것을 보여준다. 따라서 탈묵 시 진행되는 기포에의 부착현상을 평가할 수 있는 기초자료로 활용될 수 있다 고 사료되었다.

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Analysis on Vehicle Fires Caused by Damage of Diesel Particulate Filter (DPF) (매연저감장치 손상에 기인한 차량화재 사고사례 분석)

  • Song, Jae-Yong;Sa, Seung-Hun;Nam, Jung-Woo;Cho, Young-Jin;Kim, Jin-Pyo;Park, Nam-Kyu
    • Fire Science and Engineering
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    • v.26 no.4
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    • pp.70-76
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    • 2012
  • This paper deal with vehicle fire caused by damage of diesel particulate filter (DPF) on diesel passenger vehicles. In order to reduce particulate matters included exhaust gases, a DPF in the exhaust system were installed diesel vehicles. A DPF was broken by excessively trapped particulate matters, regeneration error with a malfunction of ECU and defect of suction system such as swirl valve. If the DPF was broken, hot exhaust gases was released to the bottom of vehicle and released hot exhaust gases lead to occur the fire through combustible materials around the exhaust system. When a fire happened in the diesel vehicle caused by damage of DPF, silicate inorganic compounds were attached to the exhaust ventilation pipe and muffler. The silicate inorganic compounds were created by DPF combustion consisting of raw material ceramics. If the silicate inorganic compounds attached to the tail pipe in the diesel passenger vehicles, its fire cause will be assumed damage of DPF.

Analysis of the particulate matters in the vertical-flow woodchip wetland treating stormwater from paved road (포장도로 강우유출수 처리목적의 수직흐름형 우드칩 충진 습지에서 입자상 물질분석)

  • Yuan, Qingke;Kim, Youngchul
    • Journal of Wetlands Research
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    • v.20 no.2
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    • pp.145-154
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    • 2018
  • In this study, three pilot-scale wetland systems were built for treating stormwater runoff from asphalt road. Each of the system consists of a settling tank and a vertical flow wetland packed with 25%, 50%, and 75% woodchip as treatment media. According to the analysis of the distributions of particle size, it was found that solids ranging in size $0.52-30{\mu}m$ were predominant in the stormwater runoff. After 24-hours settling, those coarser than $20{\mu}m$ were significantly detained. Further retention, especially for the finer-sized fraction, occurred in the wetland through internal recirculation during the dry day periods. As a primary media of the wetland, woodchip showed a high filtration and attachment capacity for the particulates in pre-settled stormwater, whereas overall amount of solids in the wetland effluent increased due to the detachment of woody elements from the media. This was observed mainly during the initial 75 days of operation, and the size and detachment rate were found to be strongly related with the woodchip packing ratio. The mechanism involving woody particle detachment was modeled as a first-order form. In addition, water quality factors and operational parameters affecting the detachment were analyzed and discussed.

A Study on the Detergency Performance of Zeolite A in the Detergent Solution (세제용액 중에서 Zeolite A의 세정성능에 관한 연구)

  • Kang, Yun-Seog;Kim, Hyun-Chang;Nam, Ki-Dae
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.624-630
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    • 1997
  • Zeolite A helps an increase of detergency performance according to showing the ion exchange effect for polyvalant ions and it's detergency performance could be calculated quantitatively by using the disperse stabilization theory because it is water-insoluble material and is as colloid particles in aqueous solution. In this study, zeta potential of carbon black, cellulose, and Zeolite A were measured in each inorganic salt solutions and applied to the theory of Heterocoagulation in order to evaluate the detergency performance of Zeolite A about the particulate soil at the view point of interaction potential energy. Zeolite A was shown help an increase of detergency performance according to the increasing of the steric repulsion between Zeolite A and cellulose in $Na2CO_3$ solution and the decrease of re-deposition of carbon black on the fabric by rapid coagulation with carbon black in $Na_2SO_4$ solution.

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Ultrastructural Studies of Oocyte Differentiation and Vitellogenesis in female Phacosoma japonicus (Bivalvia: Veneridae) in Western Korea (한국 서해산 암컷 떡조개, Phacosoma japonicus (Bivalvia: Veneridae) 의 난모세포 발달과 난황형성과정의 미세구조적 연구)

  • Jun, Je-Cheon;Kim, Sung-Han
    • The Korean Journal of Malacology
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    • v.32 no.1
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    • pp.17-23
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    • 2016
  • Ultrastructural studies of oocyte development and vitellogenesis associated with the follicle cells in female Phacosoma japonicus were investigated by electron microscope observations. Vitelloogenesis in the oocytes occured by way of endogenous autosynthesis and exogenous heterosynthesis: vitellogenesis occurred through a process of endogenous autosynthesis, which involves a combined activity of the Golgi complex, rough endoplasmic reticulum, and mitochondria. However, the process of exogenous heterosynthesis involved endocytotic incorporation of extraovarian precursors into the basal region of the early vitellogenic oocytes. In this study, follicle cells, which attached to the previtellogenic and vitellogenic oocytes, were easily found. In particular, the follicle cells were involved in the development of previtellogenic oocytes by the supply of nutrients, and vitellogenesis in the early and late vitellogenic oocytes by endocytosis of yolk precursors. The functions of follicle cells, which attached to mature oocytes, accumulate reserves of lipid granules and glycogen particles for vitellogesis in the cytoplasm of the follicle cells.

A Study on Formation of Slurry Ice by using the Reversing Flow in a Bundle of Tube (역전 유동층을 이용한 관군 내에서의 슬러리아이스 생성에 관한 연구)

  • Oh, Cheol;Choi, Young-Gyu
    • Journal of Navigation and Port Research
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    • v.35 no.5
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    • pp.365-370
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    • 2011
  • The ice-thermal energy storage cooling system has been applied to relief a significant portion of the peak demand of electricity during the daytime in summer. Slurry ice type system is one kind of ice-thermal storage cooling system utilizing cheaper off-peak electricity. This study is experimented to observe an influence of experimental conditions on production characteristics of slurry ice by using reversing flow, which is putting reversing material into test section to disturb ice adhesion. At this experiment, poly propylene ball of dimeter 10 mm was used as reversing material, and ethylene glycol-water solution of 20wt% concentration was used as flow material. The experimental apparatus was constructed of the slurry ice making and storage tank(test section), the brine tank, pumps for ethylene glycol-water solution and brine circulating, a mass flow-meter, data logger for fluid temperature measuring. The experiments were carried out under various conditions, with volumetric flow rate, ball filling rate and air filling rate.

Immunoelectron Microscopic Observation on the Stratified Squamous Epithelial Cello of Pemphigus vulgaris (Pemphigus vulgaris의 중층 편평상피세포에 대한 면역전자현미경적 관찰)

  • Lee, Cha-Soo;Picut, Catherine-A.;Wilkinson, J.-Erby;Lewis, Robert-M.
    • Applied Microscopy
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    • v.17 no.2
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    • pp.1-22
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    • 1987
  • Pemphigus vulgar교의 본태(本態)를 알아보기 위한 일환으로 본질병(本疾病)의 병변조직(病變組織)을 전자현미경적(電子顯微鏡的)으로 관찰(觀察)하고 본질병(本疾病)에 관여(關與)하는 세포(細胞)들에 대(對)해 면역전자현미경적(免疫電子顯微鏡的)으로 추구(追究)하였던 바, 그 결과(結果)를 보고(報告)하는 바이다. 견(犬)의 pemphigus vulgaris의 구강(口腔) 및 식도(食道)의 점막층(粘膜層)을 전자현미경적(電子顯微鏡的)으로 관찰(觀察)하였던 바 acantholysis를 일으켜도 desmosome과 기저막(基底膜)은 큰 변화(變化)가 없었으며 세포간(細胞間)은 세포간물질(細胞間物質)의 집적(集積)에 의(依)해 확장(擴張)되고 이들 세포간강물질(細胞間腔物質)은 집괴(集塊) 또는 무구조(無構造)한 물질(物質)로 나타났다. 그리고 기저세포(基底細胞)는 기저막(基底膜)에 단단히 부착(附着)되어 있었고 dendritic cell이 기저세포층(基底細胞層)위로 분포(分布)되어 있었으며, 이들 dendritic cell 중(中)에서는 가끔 여러 형태(形態)의 퇴행성변화(退行性變化)를 볼 수 있었다. Mouse 피부유리상피세포(皮膚遊離上皮細胞)에 있어서 immunogold-labeling 방법(方法)에 의해 dendritic cell을 동정(同定)하는 데에는 post-fixation, pre-embedding immunogold-labeling technique가 좋았으며 15nm와 40nm 크기의 colloid-fold 입자(粒子)로 Langerhans cell과 Thy-1양성(陽性) dendritic cell이 표식(標識)될 수 있었다. 이들 세포(細胞)들은 세포막항원(細胞膜抗元)에 따라 monoclonal antibody의 반응(反應)에 이어 치밀한 colloid-gold 입자(粒子)가 세포막표면(細胞膜表面)을 따라 일정(一定)하게 표식(標識)되었다. 또한 이들 상피세포(上皮細胞)들을 투과전자현미경적(透過電子顯微鏡的)으로 관찰(觀察)하였을 때 초미세구조(超微細構造)가 잘 보존(保存)되었으나 Langer-hans cell내(內)의 Birbeck granule은 유리전(遊離前) 피부상피조직내(皮膚上皮組織內)의 Langerhans cell내(內)의 Birbeck granule에 비(比)해 수적(數的)으로 현저히 감소(減少)되어 있었다. 그러나 Thy-1 양성(陽性) dendritic cell에서 볼 수 있는 dense-core 과립(顆粒)은 별변화(別變化)없이 쉽게 관찰(觀察)될 수 있었다. 조직배양(組織培養)을 한 견(犬)의 keratinocyte에 대(對)해 사람 pemphigus vulgaris의 항체(抗體)로 반응(反應)시킨 후 protein-A gold(15 nm)로 표식(標識)시킨 바 제일 바깥 상층(上層)의 keratinocyte에 있어서 세포막표면(細胞膜表面)을 따라 표식(標識)되어 세포막항원(細胞膜抗元)을 나타내었으며, 이와 같은 소견(所見)으로 미루어 정상피부(正常皮膚) 중층편평상피세포(重層扁平上皮細胞)에서도 동일(同一)한 소견(所見)을 관찰(觀察)할 수 있다고 본다.

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Transport and management of diffuse pollutants using low impact development technologies applied to highly urbanized land uses (고도화 도시지역에 적용된 LID 기법의 비점오염물질 관리 및 이동)

  • Geronimo, F.K.F.;Choi, H.S.;Kim, L.H.
    • Journal of Wetlands Research
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    • v.21 no.2
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    • pp.173-180
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    • 2019
  • This study was conducted to understand factors affecting TSS and heavy metals transport on the road, parking lot and roof. During storm events, heavy metals, which were mostly attached to TSS, were also transported when TSS was washed off in the road, parking lot and roof. This finding may be supported by the significant correlations between TSS load and total and soluble heavy metals load including Cr, Fe, Cu, and Pb (Pearson r value: 0.52 to 0.73; probability p value<0.01). Generation and transport of TSS and heavy metals were greater in the road and parking lot compared to the roof due to vehicular activities, slope and greater catchment areas of these sites. It was found that TSS transport during peak flows of storm events ranges from 65% to 75% implying that by controlling peak flows, TSS transportation to nearby water bodies may be decreased. Depending on the target TSS and heavy metal reduction, sizing of low impact development (LID) technologies and green infrastructures (GI) such as infiltration trench, tree box filter, and rain garden may be calculated. Future researchers were recommended to assess the limitations of the systems and determine the design considerations for these types of facilities.

Estimating Social Benefits According to Exhaust Gas Reduction Devices (DPF) (배출가스 저감장치(DPF) 부착에 따른 사회적 편익 추정)

  • Choi, Soungkyu;Kim, Yongdal;Kim, Hogyeong;Bae, Jinmin
    • Journal of Auto-vehicle Safety Association
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    • v.10 no.3
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    • pp.27-31
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    • 2018
  • The People have a bad perception about diesel vehicle because of serious air pollution, increase fine dust and global vehicle company's diesel gate. Starting the project in 2005, Ministry of Environment has been supporting that is exhaust gas reduction devices (DPF) on diesel vehicles in the metropolitan area. During the period of 2017.01.01 to 2017.12.31, 10,030 diesel vehicles installed exhaust gas reduction devices (DPF). Among them, 9,921 diesel vehicles that they have sufficient data for analysis were analyzed amount of particulate matter reduction before and after exhaust gas reduction devices (DPF) was installed. Opacity smoke meter measures the concentration of particulate matter. So concentration of particulate matter was converted into a mass unit, and then calculated the total amount of reduced particulate matter. It was estimated that social benefits is costs required to remove it from the total amount of particulate matter.

The assessment of self cleaning velocity and optimal flushing velocity in water distribution system (상수관망의 자가세척 유속과 적정 플러싱 유속 평가)

  • Bae, Cheol-Ho;Choi, Doo Yong;Kim, Ju-Hwan;Kim, Do-Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.4
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    • pp.441-451
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    • 2014
  • The flushing is important to maintain good water quality in water main. It is a technique of using water velocity to remove sediments in water distribution system. The variety of water quality problems can occur in a distribution system, so too can a variety of benefits be gained by system flushing. In order to effectively perform the flushing, the contaminants to be removed to set up and it can be solved, it is necessary to ensure the proper flow rate. In this study, the removal of contaminants present in the inner water pipe attached loose deposits such as fine particles of granular activated carbon, sand and iron corrosion product sought to derive flow rates. Thus, the constant observation of using pilot plant scale water distribution plant for the movement of floating characteristics of particles were assessed.