• Title/Summary/Keyword: 입자경 분포

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이동 벡터 모델을 이용한 표층 퇴적물의 이동 경로 분석

  • 김혜진;추용식;성효현
    • Proceedings of the KGS Conference
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    • 2003.11a
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    • pp.19-23
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    • 2003
  • 해안 퇴적 환경의 가장 기본적인 특징은 퇴적물의 입도 특성을 통해 파악할 수 있다. 퇴적물 특성을 정량적으로 표현하는 대표적인 방법은 입자 크기에 대한 값을 이용하여 평균입도(mean size), 분급도(sorting), 왜도(skewness), 첨도(kurtosis) 등의 퇴적물 입도 조직 변수를 구하여 표현하는 것이다. 퇴적 환경에서 입도 분포는 퇴적물의 이동과 퇴적의 동적 상태를 나타내는 기본적인 정보이다. (중략)

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A Study on the Curing Characteristics and the Synthesis of Polyurethane Acrylate Hybrid Emulsion (폴리우레탄 아크릴레이트 하이브리드 에멀젼의 합성 및 경화특성에 관한 연구)

  • Han, Sang-Hoon;Park, Dong-Won
    • Applied Chemistry for Engineering
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    • v.17 no.2
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    • pp.132-137
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    • 2006
  • Polyurethane acrylate hybrid emulsions were prepared by seeded polymerization techniques. In the synthesis, seeded polyurethane dispersion containing a carboxylic group was used to endow hydrophilicity to the hybrid emulsion and various acrylates such as methyl methacrylate (MMA), 2-hydroxy ethylmethacrylate (2-HEMA), n-butyl acrylate (n-BA) and acrylic acid (AAc) were used to endow hydrophobicity. The particle size and distribution of various emulsion particles such as polyurethane acrylate hybrid emulsion, polyurethane dispersion homopolymer, acrylate emulsion, and physical blending emulsion were measured by a particle size analyzer. The average particle size of hybrid emulsion was greater than physical blending emulsion. And tensile strength, 100% modulus, elongation, and swelling properties of the polyurethane acrylate hybrid emulsion were studied and compared with those of polyurethane homopolymer, acrylate emulsion, and physically blended compositor, respectively. To improve chemical and physical resistance, this paper review a melamine hardener and compares it for effects on the physical properties of cured coating.

A Study on Dispersion Copolymerization of Styrene/n-Butylmethacrylate and Alumina (스티렌/노말 부틸 메타크릴레이트와 알루미나의 분산 공중합에 관한 연구)

  • Bang, Hyun-Su;Cho, Ur-Ryong
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.549-554
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    • 2008
  • In order to synthesize polymer particle containing inorganic material, styrene and n-butylmethacrylate were copolymerized with alumina by dispersion polymerization. The weight ratio of styrene to n-butylmethacrylate was 3 : 1. A poly(N-vinyl pyrrolidon) was added as stabilizer. 2,2'-AzobisCisobutyronitrile) and 3-methacryloxypropyl trimethoxysilane were used as initiator and coupling agent, respectively. The weight ratio of 70 : 30 of isopropanol to distilled water was used as dispersion medium. According to the TEM measurement, we could confirm that alumina was dispersed into the polymer particle. The increase 'of concentration of alumina resulted in enhancement of particle size, but decreased its distribution. By the XRD method, it was found that the increase of alumina concentration showed the increase of intensity in peak and the increased 2$\theta$ value. From the TGA measurement, the increase of alumina concentration caused high heat resistance of the polymer. With respect to the type of initiator, the longer half life of initiator, the smaller particle size. We also found that the increase of particle stabilizer concentration made the decreased of particle size due to the accelerated generation of polymer particle in the early stage of reaction.

Preparation of Monodispersed Crosslinked Polymer Beads (단분산상으로 가교된 고분자 비드의 합성)

  • 심상은;변재만;전종원;차윤종;최순자
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.287-298
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    • 2000
  • In preparing micron-sized monodisperse polystyrene beads by dispersion polymerization, the conversion, and the particle size and its distribution were affected by the reaction temperature, concentration of the monomer, solvent and initiator, molecular weight and concentration of the steric stabilizer, amount of oxygen existing in the reactor, and an appropriate combination of these starting materials. Ethanol as a dispersing agent, styrene as a monomer, PVP as a steric stabilizer, AIBN as an initiator, DVB as a cross-linking agent and toluene as a co-solvent were the basic materials for the synthesis. The reaction rate and the conversion were increased with the reaction temperature and the amount of DVB from 1 to 4%, and the conversion was saturated after 10 hours of the reaction time. The optimum reaction recipe for the preparation of the monodisperse PS beads was 25% styrene monomer, 0.5% DVB, 25% toluene, 10-15% PVP, and 2 and 4% AIBN, thereby, 3.9~4 ${\mu}{\textrm}{m}$ and 3.4~9.3 ${\mu}{\textrm}{m}$ of polystyrene beads, respectively, were successfully synthesized.

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Optical Characteristics of Impact Craters on Mercury

  • Sim, Chae Kyung;Kim, Sungsoo S.
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.2
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    • pp.44.3-44.3
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    • 2018
  • 수성의 대기와 자기장은 매우 희박하여 그 표면이 우주 환경에 거의 그대로 노출되어있다. 표면의 토양은 태양풍입자와 미소유성체 등에 의해 계속해서 밝기가 어두워지고 입자의 크기도 작아진다. 이러한 현상을 종합적으로 '우주풍화'(space weathering)라고 부르는데, 그 정도를 정량화하거나 상대적으로 평가하는 데에는 어려움이 따른다. 왜냐하면 우주풍화의 정도에는 원인이 되는 입자의 입사 플럭스는 물론이고, 표면의 지역 조성비와 토양의 노화도 등이 모두 섞여 영향을 미치기 때문이다. 이를 극복하는 한 가지 방법은 수성 표면을 뒤덮고 있는 수많은 충돌구(impact crater) 내의 광학적 특성 분포를 통계적으로 분석하는 것이다. 충돌구 안쪽의 토양은 충돌 시점에 동시에 형성되었고, 그 성분이 충돌구 밖 임의의 지역에 비교해 상대적으로 균질하며, 지형적으로 충돌구 안팎의 경계가 분명하게 정해져 있다. 또한, 충돌구는 수성 전구(全球)에 걸쳐 어디에서나 발견되므로 각 충돌구의 특성을 경도 위도 연대 등 여러 측면에서 조사할 수 있다. 본 연구에서는, 메신저(MESSENGER) 탐사선의 MDIS 영상기에서 얻은 관측 자료를 활용하여 수성 충돌구의 광학적 특성에 대해 알아본다.

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Experimental Study on the Size Distribution of Fragmentation by Effects of Drilling Pattern and Time Delay Using the Sequential Blasting Machine (천공패턴 및 기폭시차의 변화에 의한 파쇄암의 입도 분포 연구)

  • 이춘우;양형식;송승근
    • Explosives and Blasting
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    • v.18 no.4
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    • pp.43-54
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    • 2000
  • 본 연구에서는 계단식 발파에서 파쇄입도에 영향을 미치는 변수들로부터 대괴를 줄이는 새로운 발파패턴을 제시하고자 하였다. 광주 제2순환도로 대절토 구간에서 천공경, 1회발파공수, 화약의 종류 등의 영향을 파쇄암의 평균입자의 크기와 상위 5개의 대괴 평균치로 나타내었다. 그 결과 대괴의 크기는 평균 파쇄암의 크기와 선형적인 추이를 나타내었으며 평균파쇄도는 저폭속 폭약인ANFO가 NewMITE 보다 좋은 결과를 보였다. 또 천공경 65 mm와 75 mm로 ANFO즉 사용했을 때 파쇄도는 약포의 직경이 작은 경우에 파쇄도가 양호하게 나타났고 총공수와 파쇄도를 살펴본 결과 평균파쇄도와 대괴의 크기는 대제적으로 총공수의 증가에 비례하여 커지는 경향이었으며 평균파쇄도 보다는 대괴의 크기가 증가의 폭이 컸다. 한편 첫째 열을 2단 분리장약했을 때가 일반 발파나 1열 소단벤치발파 때보다 파쇄도가 좋았다.

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Numerical Modeling of Large Triaxial Compression Test with Rockfill Material Considering 3D Grain Size Distribution (3차원 입도분포를 고려한 락필재료의 대형삼축압축시험 수치모델링)

  • Noh, Tae Kil;Jeon, Je Sung;Lee, Song
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.10
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    • pp.55-62
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    • 2012
  • In this research, the algorithm for simulating specific grain size distribution(GSD) with large diameter granular material was developed using the distinct element analysis program $PFC^{3D}$(Particle Flow Code). This modeling approach can generate the initial distinct elements without clump logic or cluster logic and prevent distinct element from escaping through the confining walls during the process. Finally the proposed distinct element model is used to simulate large triaxial compression test of the rockfill material and we compared the simulation output with lab test results. Simulation results of Assembly showed very well agreement with the GSD of the test sample and numerical modeling of granular material would be possible for various stress conditions using this application through the calibration.

A Study on the Transient State of Deep Bed Filtration by the Network Model (Network 모델을 이용한 입상여과공정의 전이상태 해석에 대한 연구)

  • Choo, Changupp
    • Clean Technology
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    • v.12 no.4
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    • pp.224-231
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    • 2006
  • Collection efficiencies and pressure drops for the removal of small particles from dilute liquid suspensions by granular bed filter were calculated using network model. The network model is composed of a number of nodes connected with cylindrical bond and particles are deposited on the bond surface. The collection efficiency of each cylindrical bond was predicted using unit cell model corresponding to the pore volume of cylindrical pore both at the initial and transient states. Deposited particles on the collector surface may act as additional collector and reduce the pore size of the collector. As a result, the collection efficiency was improved and pressure drop increased with deposition. Even though the stochastic nature of network requires a large number of simulation work, the model proposed in this study can be used in investigating collection efficiency and pressure drop.

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Preparation of Silica Microgels Using Membrane Emulsification Method (막유화법을 이용한 실리카 마이크로겔의 제조)

  • Youm, Kyung-Ho;Kwak, No-Shin
    • Membrane Journal
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    • v.19 no.2
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    • pp.122-128
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    • 2009
  • We prepared monodispersed spherical silica microgels by controlling various conditions of emulsification procedure using a lab-scale membrane emulsification system equipped with SPG (Shirasu porous glass) porous membrane having pore size of $1.5{\mu}m$. We determined the effects of process parameters of membrane emulsification (ratio of dispersed phase to continuous phase, sodium silicate concentration, emulsifier concentration, dispersed phase pressure, stirring speed) on the mean size and size distribution of silica microgels. The increase of the ratio of dispersed phase to continuous phase, dispersed phase pressure and sodium silicate concentration led to the increase in the mean size of microgels. On the contrary, the increase in emulsifier concentration and stirring speed of the continuous phase caused the reduction of the mean size of microgels. Through controlling these parameters, monodisperse spherical silica microgels with about $6{\mu}m$ of the mean size were finally prepared.

The Effects of Size Reduction and pH on Dispersion Characteristics of ATO (Antimony-Doped Tin Oxide) (입자 저감 및 pH가 ATO (안티몬도핑 산화주석)의 분산 특성에 미치는 영향)

  • Kim, Jin-Hoon;Jeong, Eui-Gyung;Lee, Sang-Hun;Han, Won-Hee;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.21 no.3
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    • pp.311-316
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    • 2010
  • This study aimed to prepare antimony-doped tin oxide (ATO) dispersion with high stability. The methods to achieve this goal were sought by investigating the changes of ATO particle size, size distribution, dispersion property as wet ball milling treatment time increased. And the changes of wet ball milled ATO dispersion property were also investigated, as pH increased. The changes of ATO particle size and size distribution, according to wet ball milling treatment time were evaluated with laser diffraction particle size analyzer and scanning electron microscope (SEM). The changes of ATO dispersion property, as wet ball milling treatment time and pH increased, were evaluated with zeta potential analysis and Turbiscan. By 60 min wet ball milling treatment time, ATO particle size decreased and size distribution became narrower, as the treatment time increased. After 60 min milling, the ATO particle size decreased to less than 30% of the initial size and the size distribution was narrowed to $0.1{\sim}5{\mu}m$ from $1{\sim}35{\mu}m$. However, more than 60 min milling, ATO particles aggregated and the particle size increased. ATO dispersion stability also increased as the treatment time and pH increased because the reduced particle size increased particle surface energy and repulsion between particles and the increased pH enhanced particle surface ionization. Hence, after proper length of wet ball milling treatment, highly stable ATO dispersion can be prepared, as increasing pH of the dispersion.