• Title/Summary/Keyword: 임계온도

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Effect of Polymer Concentration and Solvent on the Phase Behavior of Poly(ethylene-co-octene) and Hydrocarbon Binary Mixture (Poly(ethylene-co-octene)과 탄화수소 2성분계 혼합물의 상거동에 대한 고분자 농도 및 용매의 영향)

  • Lee, Sang-Ho;Chung, Sung-Yun;Kim, Hyo-Jun;Park, Kyung-Gyu
    • Elastomers and Composites
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    • v.39 no.4
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    • pp.318-323
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    • 2004
  • Cloud-point and bubble-point curves for poly(ethylene-co-13.8 mol% octene) ($PEO_{13.8}$) and Poly(ethylene-co-15.3 mol% octene) ($PEO_{15.3}$) were determined up to $150^{\circ}C$ and 450 bar in hydrocarbons which have different molecular size and structure. Whereas ($PEO_{15.3}$+ n-pentane) system has cloud-point and bubble-point type transitions, ($PEO_{15.3}$+ n-propane) and ($PEO_{15.3}$+ n-butane) systems do only cloud-point type transition. In cyclo-pentane, -hexane, -heptane, and -octane, $PEO_{15.3}$ has a bubble-point transition. ($PEO_{13.8}$+ n-butane) mixture has a critical mixture concentration at 5 wt% PEO. (PEO + hydrocarbon) mixtures exhibit LCST type behavior. Solubility of PEO increases with hydrocarbon size due to increasing dispersion interaction which is favorable to dissolve PEO.

Comparison of the Thermal-Hydraulic Characteristics of Optimised Fuel Assembly with That of Standard Fuel Assembly (최적 핵연료집합체와 표준 핵연료집합체의 열수력학적 특성비교)

  • Paik, Hyun-Jong;Rim, Chang-Saeng;Park, Goon-Cherl
    • Nuclear Engineering and Technology
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    • v.22 no.1
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    • pp.66-74
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    • 1990
  • The thermal-hydraulic characteristics of the 17$\times$17 OFA (Optimized Fuel Assembly) used in the KNU 7&8 are analyzed and compared with that of the 17$\times$17 SFA (Standard Fuel Assembly) loaded in the KNU 5&6. The thermal-hydraulic characteristics analyzed are minimum DNBR, fuel centerline temperature and exit void fraction at normal operation and design over power transient. Additionally, local linear rod power, which will cause fuel centerline melting, is calculated. The DNBR sensitivity calculations are performed with respect to the reactor operating parameters. COBRA-IV-I code is used for these calculations. The modified W-3 correltion and the drift-flux model are applied for the critical heat flux calculation and the void fraction calculation, respectively. From the calculated results, it has been found that the possibility of DNB occurrence is higher in the OFA than in the SFA. The other hand, the local linear power resulting in fuel centerline moiling of the OFA is nearly equal to that of the SFA.

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Evaluation of Limestone for In-Situ Desulfurization in CFB Boilers (순환유동층 보일러 로내 탈황을 위한 석회석 평가)

  • Lee, See Hoon;Kim, Dong Won;Lee, Jong Min;Bae, Yong Chae
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.853-860
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    • 2019
  • In order to meet more severe environmental regulations, oxy-fuel circulating fluidized bed(CFB) boilers or ultra supercritical CFB boilers, which are a kind of process in that solid particles moves similar to fluid, have been developed in the world. In CFB power generation processes, the method to reduce or remove sulfur dioxide is in-situ desulfurization reaction via limestone directly injected into CFB boilers. However, the desulfurization efficiencies have continuously changed because limestones injected into CFB boilers are affected by various operation conditions (Bed temperature, pressure, solid circulating rate, solid holdup, residence time, and so on). In this study, a prediction method with physical and chemical properties of limestone and operation conditions of CFB boiler for in-situ desulfurization reaction in CFB boilers has developed by integrating desulfurization kinetic equations and hydrodynamics equations for CFB previously published. In particular, the prediction equation for in-situ desulfurization was modified by using experimental results from desulfurization reactions of various domestic limestones.

Solubilization of Para-Halogenated Benzoic Acid Isomers by the Solution of Tetradecyltrimethylammonium Bromide (Tetradecyltrimethylammonium Bromide 용액에서 Para-할로겐화 벤조산 이성질체들의 가용화에 대한 연구)

  • Lee, Nam-Min;Lee, Byung-Hwan
    • Applied Chemistry for Engineering
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    • v.22 no.5
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    • pp.473-478
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    • 2011
  • The interaction of para-halogenated benzoic acid isomers with the micellar system of tetradecyltrimethylammonium bromide was studied by the UV/Vis spectrophotometric method. The solubilization constants ($K_s$) of benzoic acid isomers into the micellar system of TTAB and the critical micelle concentration (CMC) of TTAB have been measured with the change of temperature. Various thermodynamic parameters have been calculated and analyzed from those measurement. The results show that the values of ${\Delta}G^{\circ}{_s}$ for the solubilization of all isomers are negative and the values of ${\Delta}H^{\circ}{_s}$ and ${\Delta}S^{\circ}{_s}$ are all positive within the measured temperature range. The effects of additives (n-butanol and NaCl) on the solubilization of benzoic acid isomers have been also measured. There was a great decrease on the values of $K_s$ and CMC simultaneously with these additives. From these changes we can postulate that the solubilization sites of each isomers in the TTAB micellar system are the surface or the palisade region of the micelle.

Implementation and Performance Evaluation of Environmental Data Monitoring System for the Fish Farm (양식장 환경 데이터 모니터링 시스템의 구현 및 성능 평가)

  • Wahyutama, Aria Bisma;Hwang, Mintae
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.26 no.5
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    • pp.743-754
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    • 2022
  • This paper contains the results of the development and performance evaluation of the environmental data monitoring system for the fish farm. For the hardware development, the analogue sensor is used to collect dissolved oxygen, pH, salinity, and temperature of the fish farm water, and the digital sensor is used for collecting ambient temperature, humidity, and location information via a GPS module to be sent to cloud-based Firebase DB. A set of LoRa transmitters and receivers is used as a communication module to upload the collected data. The data stored in Firebase is retrieved as a graph on a web and mobile application to monitor the environmental data changes in real-time. A notification will be delivered if the collected data is outside the determined optimal value. To evaluate the performance of the developed system, a response time from hardware modules to web and mobile applications is ranging from 6.2 to 6.85 seconds, which indicates satisfactory results.

Development of Evaluation Method for Jointed Concrete Pavement with FWD and Finite Element Analysis (FWD와 유한요소해석을 이용한 줄눈콘크리트포장 평가법 개발)

  • Yun, Kyong-Ku;Lee, Joo-Hyung;Choi, Seong-Yong
    • International Journal of Highway Engineering
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    • v.1 no.1
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    • pp.107-119
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    • 1999
  • The joints in the jointed concrete pavement provide a control against transverse or longitudinal cracking at slab, which may be caused by temperature or moisture variation during or after hydration. Without control of cracking, random cracks cause more serious distresses and result in structural or functional failure of pavement system. However, joints nay cause distresses due to its inherent weakness in structural integrity. Thus, the evaluation at joint is very important. and the joint-related distresses should be evaluated reasonably for economic rehabilitation. The purpose of this paper was to develop an evaluation system at joints of jointed concrete pavement using finite element analysis program, ILLI-SLAB, and nondestructive testing device. FWD. To develop an evaluation system for JCP, a sensitivity analysis was performed using ILLI-SLAB program with a selected variables which might affect fairly to on the performance of transverse joints. The most significant variables were selected from precise analysis. An evaluation charts were made for jointed concrete pavement by adopting the field FWD data. It was concluded that the variables which most significantly affect to pavement deflections are the modulus of subgrade reaction(K) and the modulus of dowel/concrete interaction(G), and limiting criteria on the performance of joints at JCP are 300pci. 500,000 lb/in. respectively. Using these variables and FWD test, a charts of load transfer ratio versus surface deflection at joints were made in order to evaluate the performance of JCP. Practically, Chungbu highway was evaluated by these evaluation charts and FWD field data for jointed concrete pavement. For Chungbu highway, only one joint showed smaller value than limiting criterion of the modulus of dowel/concrete interaction(G). The rest joints showed larger values than limiting criteria of the modulus of subgrade reaction(K) and the modulus of dowel/concrete interaction(G).

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Improvement and Validation of Convective Rainfall Rate Retrieved from Visible and Infrared Image Bands of the COMS Satellite (COMS 위성의 가시 및 적외 영상 채널로부터 복원된 대류운의 강우강도 향상과 검증)

  • Moon, Yun Seob;Lee, Kangyeol
    • Journal of the Korean earth science society
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    • v.37 no.7
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    • pp.420-433
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    • 2016
  • The purpose of this study is to improve the calibration matrixes of 2-D and 3-D convective rainfall rates (CRR) using the brightness temperature of the infrared $10.8{\mu}m$ channel (IR), the difference of brightness temperatures between infrared $10.8{\mu}m$ and vapor $6.7{\mu}m$ channels (IR-WV), and the normalized reflectance of the visible channel (VIS) from the COMS satellite and rainfall rate from the weather radar for the period of 75 rainy days from April 22, 2011 to October 22, 2011 in Korea. Especially, the rainfall rate data of the weather radar are used to validate the new 2-D and 3-DCRR calibration matrixes suitable for the Korean peninsula for the period of 24 rainy days in 2011. The 2D and 3D calibration matrixes provide the basic and maximum CRR values ($mm\;h^{-1}$) by multiplying the rain probability matrix, which is calculated by using the number of rainy and no-rainy pixels with associated 2-D (IR, IR-WV) and 3-D (IR, IR-WV, VIS) matrixes, by the mean and maximum rainfall rate matrixes, respectively, which is calculated by dividing the accumulated rainfall rate by the number of rainy pixels and by the product of the maximum rain rate for the calibration period by the number of rain occurrences. Finally, new 2-D and 3-D CRR calibration matrixes are obtained experimentally from the regression analysis of both basic and maximum rainfall rate matrixes. As a result, an area of rainfall rate more than 10 mm/h is magnified in the new ones as well as CRR is shown in lower class ranges in matrixes between IR brightness temperature and IR-WV brightness temperature difference than the existing ones. Accuracy and categorical statistics are computed for the data of CRR events occurred during the given period. The mean error (ME), mean absolute error (MAE), and root mean squire error (RMSE) in new 2-D and 3-D CRR calibrations led to smaller than in the existing ones, where false alarm ratio had decreased, probability of detection had increased a bit, and critical success index scores had improved. To take into account the strong rainfall rate in the weather events such as thunderstorms and typhoon, a moisture correction factor is corrected. This factor is defined as the product of the total precipitable waterby the relative humidity (PW RH), a mean value between surface and 500 hPa level, obtained from a numerical model or the COMS retrieval data. In this study, when the IR cloud top brightness temperature is lower than 210 K and the relative humidity is greater than 40%, the moisture correction factor is empirically scaled from 1.0 to 2.0 basing on PW RH values. Consequently, in applying to this factor in new 2D and 2D CRR calibrations, the ME, MAE, and RMSE are smaller than the new ones.

Influence of the Levee-burning on the Fauna of Insect Pests and Their Natural Enemies (쥐불놀이 (논둑태우기)가 해충 및 천적상에 미치는 영향)

  • 김홍선;이영인;이해빈
    • Korean journal of applied entomology
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    • v.29 no.3
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    • pp.209-215
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    • 1990
  • Some preliminary studies were conducted to find out whether the levee-burning could justifiable for the suppression of insect pests, particularly the smaller brown planthopper (Laodelphax striatellus F.). Density surveys on pests and their enemies (mostly spiders) were carried out upto the mid May at an experimental paddy field located in Suwon after of it's levee $(72\times1m)$ was burned on Feb. 20, 1987. Results were discussed in relation to density recovering of both pests and their possible enemies (spiders) and summarized as below. Not a single individual of any pest or enemy was found from the levee upto sometime after the levee-burning. Grasses started to grow more vigorously in burned ares than in unburned upto about 60 days after the burning. And densities of both pest and enemies grew higher in burned areas than in unburned from about 75 days after the burning (in Early may). It is suspected that all individuals of pests and enemies fond from the burned areas could have immigrated from the surrounding areas. If levee-burning was carried out in much wider areas, much longer time would be needed to recover the density of both pests and enemies to the center region of the burning. Wingless spiders would require even longer time than winged pest species to re-establish in the center region of the widely burned field. Pirata subpiraticus, the most abundant spider species in Korean paddy fields, starts to move about and searches for food at above $9^{\circ}C$ which is somewhat lower than the critical temperature for the pest species. Thus P. subpiraticus would require more food than other pest species early in the spring, and therefore, it would have lower probability to survive than pest species particularly in burned areas. Experiments for pest suppression with levee-burning would better be carried on in much wider areas, and its justification seems to be discussed after man other disciplines related to both pests and their natural enemies were throughly studied together with their density surveys. However, according to the present point of vie, the opinion that levee-burning is helpful for controlling pests which over winter on levee areas could not be justifiable.

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A Study on the Reactivity Effect due to Expansion of Diagrid and Pad (Diagram와 Pad의 팽창에 의한 반응도 효과에 대한 연구)

  • Young In Kim;Keun Bae Oh;Kun Jong Yoo;Mann Cho
    • Nuclear Engineering and Technology
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    • v.16 no.2
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    • pp.70-79
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    • 1984
  • With the help of the nuclear computational system for a large LMFBR (KAERI-26 group cross section library/1DX/2DB), the reactivity coefficients for the diagrid expansion and the pad expansion at the beginning of cycle of the equilibrium core of SUPER-PHENIX I are calculated and reviewed. the core is described using R-Z geometry model, and a two-dimensional multigroup diffusion theory is used. For reference cases, reactivity calculations for radial and axial uniform expansion are performed, and also calculated are reactivity variations due to changes in material density and core volume. The reactivity coefficient for the diagrid expansion is calculated to be -0.553pcm/mil. The temperature coefficient corresponding to the above value is -1.0766pcm/$^{\circ}C$ and is well in accord with the French datum of -1.09pcm/$^{\circ}C$ within 1.2% difference. With the use of 4he calculational method for the diagrid expansion effect, reactivity calculations for the pad expansion bringing about nonuniform expansion are performed, which show that the calculational method is very useful in the analysis of the pad expansion effect. The reactivity coefficients for the pad expansion are calculated to be -0.2743 pcm/mil and -0.2786pcm1mi1 for the averaged expansion model and for the integrated pancake model, respectively. Under the assumption of the free expanding core the temperature reactivity coefficients for each model are obtained to be -0.5766pcm/$^{\circ}C$ and -0.5858pcm/$^{\circ}C$, both of which agree with the French datum of -0.574pcm/$^{\circ}C$ within 2% difference.

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Design and Evaluation of Small-scale Supercritical Carbon Dioxide System with Solar Heat Source (태양열 적용을 위한 소형 초임계 이산화탄소 실험설비 설계 및 평가)

  • Choi, Hundong;So, Wonho;Lee, Jeongmin;Cho, Kyungchan;Lee, Kwon-yeong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.6
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    • pp.403-410
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    • 2020
  • This paper focuses on the design of a 12-kW small-scale supercritical CO2 test loop. A theoretical study, stabilization, and optimization of carbon dioxide were carried out with the application of a solar heat source based on solar thermal data in Pohang. The thermodynamic cycle of the test facility is a Rankine cycle (transcritical cycle), which contains liquid, gas, and supercritical CO2. The system is designed to achieve 6.98% efficiency at a maximum pressure of 12 MPa and a maximum temperature of 70℃. In addition, the optimum turbine inlet temperature and pressure were calculated to increase the cycle efficiency, and the application of an internal heat exchanger (IHX) was simulated. It was found that the maximum efficiency increases to 18.75%. The simulation confirmed that the efficiency of the cycle is 6.7% in May and 6.26% in June.