• Title/Summary/Keyword: 인 회수

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화재와 연소현상

  • 김상욱
    • Fire Science and Engineering
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    • v.2 no.1
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    • pp.71-80
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    • 1988
  • 본 강좌는 소방공학분야를 기초과정에서부터 전문성에 이르기까지 공부하는 데에 관심을 갖거나, 산발적으로 또는 부분적으로 상당한 지식은 있으나 보다 이해의 체계화를 추구하고자 하는 회원들을 위하여 연재물의 성격으로 마련된 것이다. 따라서 본 강좌는 매우 교과서적 성격으로 편집될 것이다. 본 강좌의 내용은 본 학회의 회원중 사계의 전문인들이 협동하여 적절히 번갈아 집필함으로써 향후 연재회수에 제한 없이 게재될 것이며, 관심 있는 회원들에게 다소라도 도움이 되었으면 한다.

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Development of Vanadium Recovery Process Using Reduction Pre-treatment from Vanadium Titanium-Magnetite (VTM) Ore (VTM광으로부터 환원 전처리를 이용한 바나듐 회수 공정 개발)

  • Go, Byunghun;Jeong, Dohyun;Han, Yosep;Kim, Seongmin;Chu, Yeoni;Kim, Byung-su;Jeon, Ho-Seok
    • Resources Recycling
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    • v.31 no.2
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    • pp.12-19
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    • 2022
  • The study was conducted to develop a vanadium recovery process using reduction pre-treatment in the Vanadium TitanoMagnetite (VTM) The sample for the research was provided by the Gwan-in Mine in Pocheon, Gyeonggi-do. The vanadium content of the sample is 0.54 V2O5% and vanadium is concentrated mainly in magnetite and ilmenite. Magnetic separation of the sample can increase vanadium content up to 1.10 V2O5%. To increase the vanadium content further, reduction pre-treatment was performed, which is a process of concentrating vanadium present in the iron by reducing iron in magnetite using carbon(C). Based on this reduction pre-treatment, the magnetic separation process was developed, which achieved a vanadium grade of 1.31V2O5% and 79.68% recovery. In addition, XRD analysis of the vanadium concentrate before and after reduction and the final vanadium concentrate was performed to confirm the behavior of vanadium by reduction pre-treatment.

A Study on the Phosphorus Resources Recovery using the MAP + PACI (Ca과 응집제를 보완한 MAP법을 이용한 폐수로부터의 인 자원 회수에 관한 연구)

  • Kim, Dong-Ha
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.3
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    • pp.273-278
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    • 2007
  • Modern society has moved from a phosphorus recycling loop, where animal manure and human wastes were spread on farming land to recycle nutrients, to a once-through system, where phosphates are extracted from mined, non-renewable phosphate rock and end up either in landfill(sewage sludge, incinerator ash) or in surface waters. In this research, crystallization of nitrogen and phosphate with natural sources of $Mg^{2+}$ in synthetic water was tested. The operational parameters of pH, mixing time, and the magnesium molar ratio were investigated to find optimal conditions of the MAP precipitation using synthetic wastewater. The removal efficiency of phosphate increased with pH up to 11. By MAP precipitaiton of the synthetic waste water, 94% of the phosphate were eliminated at pH 11. It was found that at least 10 minutes mixing time was required and 20 minutes mixing time was recommended for efficient phosphate removal. High efficiency removal of phosphate was possible when the magnesium molar ratio was 1.0~2.0. The comparative study of different magnesium sources showed that coagulants (PAC) was the more efficient sources than only magnesium. The result showed that 97% of phosphate removal. In conclusion, coagulants (PAC) induced crystallization of struvite and hydroxyapatite was shown to be a technically viable process that could prove cost effective for removing phosphate in wastewater.

Trends of phosphorus recovery technology from sewage sludge ash by wet chemical method (습식 화학적 방법에 의한 하수 슬러지 소각재에서의 인 회수 기술동향)

  • Lee, Min-Su;Kim, Dong-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.2
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    • pp.131-143
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    • 2018
  • Phosphorus (P) is a limited, essential, and irreplaceable nutrient for the biological activity of all the living organisms. Sewage sludge ash (SSA) is one of the most important secondary P resources due to its high P content. The SSA has been intensively investigated to recover P by wet chemicals (acid or alkali). Even though $H_2SO_4$ was mainly used to extract P because of its low cost and accessibility, the formation of $CaSO_4$ (gypsum) hinders its use. Heavy metals in the SSA also cause a significant problem in P recovery since fertilizer needs to meet government standards for human health. Therefore, P recovery process with selective heavy metal removal needs to be developed. In this paper some of the most advanced P recovery processes have been introduced and discussed their technical characteristics. The results showed that further research is needed to identify the chemical mechanisms of P transformation in the recovery process and to increase P recovery efficiency and the yields.

Effects of Phosphorus Starvation on Fatty Acid Production by Microalgae Cultivated from Wastewater Environment (인 결핍에 따른 하수배양 미세조류의 지방산 특성 분석 연구)

  • Woo, Sung-Geun;Park, Joon-Hong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.4B
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    • pp.253-259
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    • 2012
  • Wastewater-adapted microalgae such as Chlorella vulgaris AG10032, Ankistrodesmus gracilis SAG278-2 and Scenedesmus quadricauda AG10308 are useful biological resources for recovering biofuel and other bio-based materials from wastewater because of their efficient removals of nitrogen and phosphorus from wastewater and their high fatty acid contents in biomass. Although the concentrations of phosphorus typically vary in wastewater environment, very little is known about the effect of phosphorus concentration, especially phosphorus starvation, on microalgal fatty acid synthesis. This is partially due to the lack of methodological establishment for algal fatty acid analysis. In this study, we compared the analysis performances of microalgal fatty acids by two different methods; one is a non-polar GC (gas chromatography) column based method, which is generally used for microbial fatty acids, and the other is a polar WAX-type GC column method, which is typically used for plant fatty acids. And then, we explored the effect of phosphorus concentration levels on fatty acid production in microalgae cultivated from wastewater. As results, the polar WAX-type column method has better ability to separate poly unsaturated fatty acids (PUFA) including $C_{18:3}$ (linolenic acid), and was found to be more applicable in analyzing fatty acids from wastewater-cultivated microalgae than the non-polar column method. The fatty acid characterization by the WAX-type column method revealed little effect of phosphorus starvation on the quantity and composition of fatty acids from wastewater-cultivated microalgae.

Determination of 129I in simulated radioactive wastes using distillation technique (증류법을 이용한 모의 방사성폐기물 중 129I 의 정량)

  • Choi, Ke-Chon;Song, Byung-Cheol;Han, Sun-Ho;Park, Yong-Joon;Song, Kyu-Seok
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.9 no.3
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    • pp.141-148
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    • 2011
  • It is clarified in the radioactive waste transfer regulation that the concentration of radioactive waste for the major radio nuclide has to be examined when radioactive waste is guided to the radioactive waste stores. In case of the low level radioactive waste sample, the analytical results of radioactive waste concentration frequently show a value lower than minimum detectable activity (MDA). Since the MDA value basically depends on the amount of a sample, background value, measurement time, counting efficiency, and etc, it would be necessary to increase a sample amount with a intention of minimizing MDA. In order to measure a concentration of $^{129}I$ in low and medium level radioactive waste, $^{129}I$ was collected by using a distillation technique after leaching the simulated radioactive waste sample with a non-volatile acid. The recovery of $^{129}I$ measured was compared with that measured with column elution technique which is a conventional method using an anion-exchange resin. The recovery of inactive iodide by using the distillation method and column elution were found as $86.5{\pm}0.9%$ and $87.3{\pm}2.7%$, respectively. The recovery and MDA value calculated for distillation technique when 100 g of extracted solution of $^{129}I$ was taken, were found to be $84.6{\pm}1.6%$ and $1.2{\times}10^{-4}Bq/g$, respectively. Consequently, the proposed technique with simplified process lowered the MDA value more than 10 times compared to the column elution technique that has a disadvantage of limited sampling amount.

Testing the Potential of Sewage Sludge Gasification Solid Residues as a Circulating Resource by Physical Separation (하수슬러지의 가스화 고형 잔재물의 순환자원으로서 물리적 선별에 의한 잠재성 검토)

  • Donghyun Kim;Sunghyun Bae;Seongmin Kim;Seongsoo Han;Yosep Han;Gi Woon Kwon
    • Resources Recycling
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    • v.33 no.3
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    • pp.48-56
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    • 2024
  • In this study, physical property evaluation and physical separation of the target product were performed to investigate the possibility of using sewage sludge gasification solid residue (GSRs) as a circulating resource. Firstly, the GSRs used in this study was supplied by Sudokwon Landfill Management Corporation, and generally the GSRs was in the form of porous pellets with a particle size of several millimetres. In addition, the partially black areas were confirmed to be unburned and ungasified carbon, and the average carbon content was 5%. In addition, the content of silica, alumina and phosphorus oxide was more than 70% of the total content. It was confirmed that the metallic components of the wet grinding product were separated into individual elements. As a physical separation of metallic and non-metallic components was required, it was finally found that flotation screening was suitable. Accordingly, cationic and anionic surfactants were selected to separate metallic components in which a relatively large amount of non-metallic components were concentrated, and the separation characteristics were confirmed. As a result, it is expected that the concentration of non-metallic components such as silica, alumina and phosphorus will be easier than the separation of metallic components. Therefore, since it is possible to physically treat the gasified sludge residue, it is judged to have potential as a circular resource according to the proposed recycling method for the separated product.

An efficient kanban operation method in just-in-time production system with a single buffer (Just-in-time하의 단일 버퍼를 갖는 생산시스템의 칸반 운영에 관한 연구)

  • 김동민;이종태
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 1996.04a
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    • pp.294-296
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    • 1996
  • JIT(just-in-time) 생산시스템은 제조라인의 재공품 재고량을 최소화하고, 필요한 품목을 적시에 필요한 양만큼만 생산하여 공급하는 것을 목적으로 한다. 이러한 시스템은 사용하는 칸반의 수에 따라 single-card kanban system과 two-card kanban system으로 구별할 수 있다. 또한 각 공정이 입력버퍼(input buffer)와 출력버퍼(output buffer)를 갖는 경우와 공정간에 하나의 버퍼를 갖는 경우로 나누어 볼 수 있다. 본 연구는 기계간의 물류(material handling)가 필요한 시점에 즉시 이루어진다는 가정하에 기계간 버퍼가 하나이고, 그 버퍼의 용량이 1인 경우의 single-card kanban의 효율적인 운용방안을 개발하였다. 본 연구의 목적은 생산지시칸반의 회수시기를 적절히 조절하여 생산라인의 이용효율(utilization)을 극대화하고자 하는 것이다. 칸반회수시기 결정을 위한 상황분석의 범위를 10대의 기계로 제한하여 시뮬레이션에 의해 분석하였다. 기존의 칸반운영방식과 생산라인에서의 재고를 최소화하는 운영 알고리듬, 그리고 생산기계의 효율을 최대화할 수 있는 운영 알고리듬을 개발하여 비교.분석하였다.

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Design of Heat Pump Renewable Energy System Using Wastewater with a Heat Source (폐수열 히트펌프 재생에너지 시스템 설계)

  • Choo, Yeon-Gyu;Kim, Bong-Gi;Kim, Sung-Du
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2011.05a
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    • pp.787-790
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    • 2011
  • 본 연구에서는 페수열 회수 보일러에서 버려지는 페수열을 재생하여 에너지를 재활용하기 위하여 퍼지제어 알고리즘을 사용한 지능제어기를 설계하고자 한다. 폐수유입온도의 변화와 폐수유입량의 변화를 파라미터로 하여 컴프레서의 정속운전 대수와 토출온수온도의 특성곡선을 전문가의 지식으로부터 얻을 수 있다. 폐수열 회수 보일러에 유입되는 폐수부하에 따른 컴프레서의 정속운전 대수를 최소화 하기위해 폐수유입온도와 유입량의 변화를 측정하여 최적의 정속운전 대수 및 인버터 운전량을 실시간으로 결정하는 지능제어기를 설계하여 페수열 부하의 변동을 실시간으로 추정하여 최소의 컴프레서 운전대수 및 조작량을 제어함으로써 에너지 효율과 경제성을 극대화할 수 있다.

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