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Determination of alkylphenol ethoxylate in water by high performance liquid chromatography/electrospray ionization/mass spectrometry (HPLC/ESI/MS를 이용한 물 중의 알킬페놀에톡실레이트 분석)

  • Lee, Jeongae;Park, Song-Ja;Chung, Bong Chul
    • Analytical Science and Technology
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    • v.17 no.3
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    • pp.263-270
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    • 2004
  • A method is described for the analysis of short-chain alkylphenol ethoxylates (APEOs), 4-octylphenol-di-ethoxylate (OP2EO) and 4-nonylphenol-di-ethoxylate (NP2EO), in drinking water or wastewater using reversed phase high-performance liquid chromatography with electrospray ionization mass spectrometry. The solvent system was water and methanol containing $10{\mu}M$ trifluoroacetic acid as an ionization solvent. We acidified 1 L of water samples to less than pH 2 with concentrated $H_2SO_4$ and loaded onto Sep-Pak $C_{18}$, and eluted with acetone. The calibration of OP2EO and NP2EO was performed for the concentration range from 20 to 500 ng/L and the correlation coefficients were 0.999 and 0.990, respectively. The limits of detection were 20 ng/L (OP2EO) and 50 ng/L (NP2EO) at a signal-to-noise ratio of 3. Accuracy and precision of this analytical method were 85.8 ~ 122.1% and 8.2 ~ 18.8%, respectively. The proposed method allowed a sensitive and rapid detection of OP2EO and NP2EO and it could be applied for monitoring of APEOs from environmental samples.

The Effects of Fluoride Administered Systemically during Rat Development on Forming Bone (발생중인 흰쥐에 전신적으로 투여된 불소가 골형성에 미치는 영향)

  • Lim, Do-Seon;Ahn, Yong-Soon;Kim, Eun-Sook;Bae, Hyung-Joon;Chang, Byung-Soo
    • Applied Microscopy
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    • v.32 no.3
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    • pp.265-273
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    • 2002
  • The purpose of this study was to observe the influences of the water fluoride concentration on the growth changes, the histologic characteristics of osteoblast in the tibia of growing newborn rats by using electron microscopy and on the composition changes of bone matrix in those by using energy dispersive x-ray system (EDX). The water fluoride concentration was respectively 0 ppm (contrast group), 100 ppm (100 ppm group), 200 ppm (200 ppm group) and 300 ppm (300 ppm group). The results of the investigation by using electron microscopy were as followed. In contrast group, the traditional cuboidal osteoblasts were observed. In 100 ppm group, several reversal line, the newly formed osteoid by the strongly activated osteoblast and the well developed rough endoplasmic reticulum, mitochondria in cytoplasm of osteoblast were observed. Also, many secretory vesicle around cell membrane were observed and some fused with cell membrane released secretory granule out of cell. In 200 ppm group, the depressed osteoblasts were observed, mitochondria in cytoplasm were expanded and cristae shape in mitochondria were destroyed. Also, the ribosome at the surface of rough endoplasmic reticulum were not observed. In 300 ppm group, the adjacent osteoblasts with endosteum were irregularly arranged, the cell membrane were destroyed and organelles were flowed out of cell. On the other hand, the results of the investigation by using energy dispersive x-ray system were as followed. P and Ca concentrations in 100 ppm group were increased more than those in contrast group. But, in 200 and 300 ppm group were not increased more than those in 100 ppm group. Therefore, the activities of the osteoblasts were increased, the bone matrix were actively synthesized by the supplied water fluoride. But, the osteoblasts were destroyed, inhibited by the higher water fluoride concentration.

Assessing the Pollution Trend in Water and Sediments of Tancheon Down the Stream (탄천 상.하류의 하천수 및 퇴적물 오염도 연구)

  • Baek, Yong-Wook;Lee, Yong-Han;Kim, Hack-Kyu;Jung, Da-Un;An, Youn-Joo
    • Korean Journal of Ecology and Environment
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    • v.43 no.1
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    • pp.11-18
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    • 2010
  • The contamination of a suite of heavy metals were evaluated in water and sediments of urban stream, Tancheon down the stream. Tancheon is a urban stream which goes all the way across the urban area where various pollution sources are present. The sixteen study sites from seven different areas were designated down the stream. The heavy metal levels of the streams were detected in the order of Zn>Cu>Ni>Pb>Cd>Cr>Sb. There was a difference in the relative order of the concentration ranking in lake sediments. There is a trend that the heavy metal levels are higher at the sites where the construction causes inflow of soil particles to stream. Toxicity tests using pore-water in sediments were conducted for samples collected in some study sites, and pore-water in one site was proven to be toxic to Japanes medaka (Oryzias latipes). The reason may be the fecal pollution rather than heavy metal effect. Strong odor was detected in the sediment whose pore-water samples showed ecotoxicity. We did not observed the increasing concentration of heavy metals down to stream since the soil texture varied in the stream area of our study. Further study is needed to find quantitative relations between the level of contamination and its eco-effect.

Components Analysis of Korean Pollens and Pollen Extracts (국내산 화분 및 화분 추출물의 성분 분석)

  • Lee, Boo-Yong;Choi, Hee-Don;Hwang, Jin-Bong
    • Korean Journal of Food Science and Technology
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    • v.29 no.5
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    • pp.869-875
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    • 1997
  • The chemical components of Korean pollens and pollen extracts were analysed to provide fundamental data for pollen processing and products development. The contents of crude protein, crude lipid, crude ash, crude fiber and carbohydrate of pollens were $14.0{\sim}22.3%,\;3.0{\sim}8.8%,\;2.2{\sim}3.3%,\;0{\sim}37.5%,\;and\;31.9{\sim}64.4%$ respectively, showing the specially high crude fiber content (37.5%) in Pine pollen. Almost all the carbohydrate, lipid, protein and ash components except fiber were extracted by water and n-hexane. Free sugars identified in water extracts $(10\;^{\circ}Bx)$ of pollens were fructose and glucose as major component and maltose as minor component. The proportions of three free sugars to total soluble solid content of Mixed, Acorn, and Pine water extracts were 73.6%, 85.4% and 47.7% respectively. Potassium and phosphorus content in pollens and pollen water extracts were high, but Ca, Na, Mg, Fe and Zn were not major mineral components. The essential amino acids such as leucine, phenylalanine, methionine, lysine, valine, isoleucine and threonine were contained richly in pollens and those were almost completely extracted by water. Vitamin $B_1$ and C were not detected, but only small amount of vitamin $B_2$ was detected in the pollens and pollen extracts tested. The essential fatty acids such as linoleic acid and linolenic acid were contained richly in pollens. The proportion of unsaturated fatty acids to total fatty acid content in Mixed, Acorn and Darae pollen except Pine was higher than 50%.

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Nutritional Components of Cow Feet Jokpyun and Jokpyun Added Chicken and Codfish (소족편 및 소족에 닭과 건대구를 첨가한 족편의 영양성분 - 연구노트 -)

  • 곽은정;안효진;이경희;이영순
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.2
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    • pp.307-310
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    • 2003
  • This study investigated the nutritional components of jokpyun. Jokpyuns made with cow feet and two kinds of jokpyun were added 30% of chicken and dry codfish to 70% of cow feet, respectively. There was no difference in moisture contents among three jokpyuns. Crude protein content was higher in jokpyun made with cow feet than in those added chicken and dry codfish. Contents of lipid and ash in jokpyuns added chicken and dry codfish were higher than those of jokpyun made with cow feet. The ratio of unsaturated fatty acid in jokpyun added dry codfish was the highest, but, that of linoleic acid was the highest in jokpyun added chicken than the others. Amino acid contents were higher in the order of glycine, proline, alanine, glutamic acid and composition of essential amino acid was similar to soupstock made with beef shank and leg bone. The contents of glycine and alanine in jokpyun added codfish and that of glutamic acid in jokpyun made with cow feet were the highest. Especially, among essential amino acids lysine was the highest in all jokpyuns. Methionine and valine were higher jokpyun added chicken and jokpyun made with cow feet than the others. Calcium and phosphorous were higher in jokpyun added chicken than in others. From these results, jokpyun, especially added chicken, was seemed to be more nutritious than other jokpyuns.

Determination Method of Hydrocarbon Compounds in DME-LPG Blending Fuels by Gas Chromatography with Deans Switching (Deans Switching을 이용한 가스크로마토그래피에서 DME-LPG 혼합연료의 탄화수소 화합물 분석방법)

  • Youn, Ju Min;Park, Cheon Kyu;Yim, Eui Soon;Jung, Choong Sub
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.353-357
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    • 2012
  • The new qualitative and quantitative analytical method for hydrocarbon compounds in DME-LPG blending fuel, mixing dimethyl ether (DME) with liquefied petroleum gas (LPG), by using gas chromatography (GC) was investigated. It is difficult to analyze all components of DME-LPG blending fuel by using single column in GC due to consisting of the non-polar LPG and the polar DME which is oxygen-containing compound. Therefore, it has been introduced the Deans switching system, which are useful for analyzing mixtures of a very different nature and/or target analytes in very complex matrix. This technique is to control the pressure between two columns and to selectively change the path of effluent flows to either one of two columns. As a result, we found that DME and LPG can be completely separated at the different columns and the determination of all hydrocarbon compounds in DME-LPG blending fuel can be achieved to this method qualitatively and quantitatively during the operation of one injection. In addition, this method can be applied to the determination of trace components of by-product, such as methanol, methyl formate and ethyl methyl ether, which will be derived from DME synthesis process.

Design and Implementation of a Distribution Internet Fax System (분산 인터넷 팩스 시스템의 설계 및 구현)

  • 김건우;윤재관;한기준
    • Proceedings of the Korean Information Science Society Conference
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    • 2001.04a
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    • pp.193-195
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    • 2001
  • 현대 사회는 인터넷을 통하여 수많은 정보들을 신속히 얻을 수 있고 공유할 수 있지만, 아직까지 PSTN(Public Switched Telephone Network: 공중전화망)을 이용하는 팩스가 광범위하게 사용되고 있다. 그것은 팩스가 컴퓨터 환경이 주어지지 않는 상황에서도 정보의 교환이 가능하며, 현재 팩스의 기능을 대체할 수 있는 전자메일 못지 않게 상세한 정보를 24시간 주고 받아볼 수 있기 때문이다. 그러나, 공중전화망을 이용한 팩스 전송은 LAN 환경에서의 정보 전송보다 높은 전송 비용 및 느린 전송 속도록 인하여 LAN과 PSTN을 혼용하는 인터넷 팩스 시스템이 개발되었고, 현재 상용 서비스되고 있다. 그런데, 상용 서비스를 하고 있는 인터넷 팩스 업체들은 고가의 장비와 유지/보수비용에 따른 전송 비용을 책정함으로써 공중 전화망을 이용한 전송 비용의 부담을 완전히 해소해 주지는 못하고 있다. 본 논문에서는 상용 업체들의 팩스 시스템과 서비스 형태를 분석하고, 그에 따라 전송 비용을 좀 더 절감할 수 있게 하기 위한 분산 인터넷 팩스 시스템을 설계 및 구현하였다. 즉, 상용 업체에서 제공하는 인터넷 팩스 시스템의 전송 서비스 기능의 대부분을 포함하면서, 팩스 모뎀과 LAN 환경에 연결된 PC를 사용하여 인터넷 팩스 시스템을 구축하게 함으로써 하드웨어의 구입비 및 유지/보수비용을 최소화하였을 뿐만 아니라 지역마다 팩스 서버를 분산 배치하여 별도로 운영하게 함으로써 상용 인터넷 팩스 서비스 업체들이 단독 혹은 일부 분사-지사 형태로 전송 처리해 오던 방법을 완전히 지역별로 작업을 분배 처리할 수 있게 하였다.위를 점하였다.전송과 복원이 이루어질 것이다.하지 않은 경우 단어 인식률이 43.21%인 반면 표제어간 음운변화 현상을 반영한 1-Best 사전의 경우 48.99%, Multi 사전의 경우 50.19%로 인식률이 5~6%정도 향상되었음을 볼 수 있었고, 수작업에 의한 표준발음사전의 단어 인식률 45.90% 보다도 약 3~4% 좋은 성능을 보였다.으로서 hemicellulose구조가 polyuronic acid의 형태인 것으로 사료된다. 추출획분의 구성단당은 여러 곡물연구의 보고와 유사하게 glucose, arabinose, xylose 함량이 대체로 높게 나타났다. 점미가 수가용성분에서 goucose대비 용출함량이 고르게 나타나는 경향을 보였고 흑미는 알칼리가용분에서 glucose가 상당량(0.68%) 포함되고 있음을 보여주었고 arabinose(0.68%), xylose(0.05%)도 다른 종류에 비해서 다량 함유한 것으로 나타났다. 흑미는 총식이섬유 함량이 높고 pectic substances, hemicellulose, uronic acid 함량이 높아서 콜레스테롤 저하 등의 효과가 기대되며 고섬유식품으로서 조리 특성 연구가 필요한 것으로 사료된다.리하였다. 얻어진 소견(所見)은 다음과 같았다. 1. 모년령(母年齡), 임신회수(姙娠回數), 임신기간(姙娠其間), 출산시체중등(出産時體重等)의 제요인(諸要因)은 주산기사망(周産基死亡)에 대(對)하여 통계적(統計的)으로 유의(有意)한 영향을 미치고 있어 $25{\sim}29$세(歲)의 연령군에서, 2번째 임신과 2번째의 출산에서 그리고 만삭의 임신 기간에, 출산시

Round Robin(RR) ONE-IP: Efficient Connection Scheduling Technique for Hosting Internet Services on a Cluster of Servers (서버 클러스터에서의 인터넷 서비스를 위한 효율적인 연결 스케줄링 기법)

  • 최재웅;김성천
    • Proceedings of the Korean Information Science Society Conference
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    • 2001.04a
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    • pp.736-738
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    • 2001
  • 웹을 사용하는 사용자들의 급속도로 증가하는 서비스 요청을 신속하고 저렴한 비용으로 처리하기 위한 대응책으로, LAN 환경의 웹 서버 클러스터 구조가 각광을 받고 있다. 높은 가용성 및 확장성을 보장하는 웹 서비스를 제공하기 위해 많은 부하의 서비스 요구를 여러 서버에게 효과적으로 나누어 처리할 수 있어야 하며, 따라서 서비스 요청 패킷을 고르게 분배할 수 있는 합리적인 스케줄링 기법을 필요로 한다. ONE-IP 스케줄링 기법은 이더넷의 브로드케스트 메시지에 의해 스케줄링이 분산되도록 하는 전략을 사용함으로써, 클러스터에 유입되는 패킷의 집중화로 인해 발생할 수 있는 병목 현상(bottleneck)과 치명적인 오류(Single-point of Failure) 문제를 효과적으로 해결하였다. 그러나, 서비스를 요청하는 패킷의 발신지 주소만을 이용하는 단순한 패킷 스케줄링을 사용하기 때문에 클러스터를 구성하는 서버들 간의 부하 불균형을 가중시키며, 결과적으로 클러스터의 효율성을 저하시키는 문제점을 가지고 있다. 본 논문에서는 이러한 문제점을 해결하기 위하여 RR ONE-IP 기법을 제안하였다. 제안한 기법은 서버에 할당되는 부하간에 불균형이 발생하는 문제점을 해결하기 위해 TCP 연결 단위의 스케줄링 전략을 사용하였으며, 서버의 부하 정보를 이용하지 않는 RR 스케줄링 기법을 도입함으로써, ONE-IP 기법의 장점을 그대로 유지하면서 보다 나은 부하의 균등한 분배로 시스템의 처리 능력을 향상시키도록 하였다. 또한, 실험을 수행한 결과 제안한 기법이 기존의 기법에 비해 평균 3.84%의 시스템의 성능 향상을 보였으며, 과부하 발생율에서는 평균 23.5%의 감소를 가져왔음을 보였다.우 단어 인식률이 43.21%인 반면 표제어간 음운변화 현상을 반영한 1-Best 사전의 경우 48.99%, Multi 사전의 경우 50.19%로 인식률이 5~6%정도 향상되었음을 볼 수 있었고, 수작업에 의한 표준발음사전의 단어 인식률 45.90% 보다도 약 3~4% 좋은 성능을 보였다.으로서 hemicellulose구조가 polyuronic acid의 형태인 것으로 사료된다. 추출획분의 구성단당은 여러 곡물연구의 보고와 유사하게 glucose, arabinose, xylose 함량이 대체로 높게 나타났다. 점미가 수가용성분에서 goucose대비 용출함량이 고르게 나타나는 경향을 보였고 흑미는 알칼리가용분에서 glucose가 상당량(0.68%) 포함되고 있음을 보여주었고 arabinose(0.68%), xylose(0.05%)도 다른 종류에 비해서 다량 함유한 것으로 나타났다. 흑미는 총식이섬유 함량이 높고 pectic substances, hemicellulose, uronic acid 함량이 높아서 콜레스테롤 저하 등의 효과가 기대되며 고섬유식품으로서 조리 특성 연구가 필요한 것으로 사료된다.리하였다. 얻어진 소견(所見)은 다음과 같았다. 1. 모년령(母年齡), 임신회수(姙娠回數), 임신기간(姙娠其間), 출산시체중등(出産時體重等)의 제요인(諸要因)은 주산기사망(周産基死亡)에 대(對)하여 통계적(統計的)으로 유의(有意)한 영향을 미치고 있어 $25{\sim}29$세(歲)의 연령군에서, 2번째 임신과 2번째의 출산에서 그리고 만삭의 임신 기간에, 출산시체중(出産時體重) $3.50{\sim}3.99kg$사이의 아이에서 그 주산기사망률(周産基死亡率)

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Sea Water Intrusion in the Coastal Area of Cheju Volcanic Island, Korea (제주도(濟州島) 임해지역(臨海地域)에서의 해수침입(海水侵入))

  • Choi, Soon Hak;Kim, Young Ki;Lee, Dong Young
    • Economic and Environmental Geology
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    • v.24 no.3
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    • pp.319-327
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    • 1991
  • Cheju is the biggest island in Korean peninsula, consisted entirely of volcanic rocks and pyroclastic sediments. The topography is characterized by wide basalt plain in the low altitude but at the center of island, basalt volcano rises 1,950m above sea-level. Surface drainage is very poor, therefore water supply has been dependent on ground water and natural springs. There are about 1,650 production wells and most of them yield $1,000{\sim}2,000mm^3/day$. According to increase of ground water use, saline water is intruded in the low altitude of coastal area. Specially in the eastern coastal area, the topography is extensively flat and the level of ground water is very close to sea-level, at which overuse of ground water has brought saline intrusion up to maximum 6km far from the coast. Hydrochemical monitoring on this salt water intrusion is now undertaken on long term base.

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Effects of Application of Latex Coated Urea on Yield and N-Use Efficiency of the Direct Seeding Rice on Dry Paddy Field in the Year of High Temperature (Latex 피복요소시용(被覆尿素施用)과 고온(高溫)이 건답직파(乾畓直播) 벼의 질소이용효율(窒素利用效率)과 수량(收量)에 미치는 영향)

  • Yoo, Chul-Hyun;Shin, Bog-Woo;Jeong, Ji-Ho;Kang, Seung-Weon;Han, Sang-Soo;Kim, Seong-Jo
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.4
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    • pp.324-329
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    • 1998
  • To investigate the changes of $NH_4-N$ in soil, nitrogen uptake by rice plant, nitrogen use efficiency and rice yield by the application of Latex Coated Urea(LCU) on direct seeding rice, rice was planted on paddy field, Jeonbuk series at the Honam area, from 1996 to 1997. Nitrogen in LCU applied as basal dressing in whole layer was dissolved almost untill non-productive stage. Thus, nitrogen deficiency symptom appeared and N in shoot was 1.75% showing 28.1 of SPAD value at heading stage. However percentage recovery of fertilizer N was higher in LCU than with urea application. Top dressing of urea at panicle initiation stage in addition to basal dressing of LCU, increased rice yield by 9%. Conventional split application of urea on the surface decreased the percentage recovery of fertilizer N to 56.9% of whole layer application plot.

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