• Journal of the Korean Institute of Gas
• /
• v.15 no.2
• /
• pp.82-87
• /
• 2011

Heat transfer oils are used in applications such as heating systems of chemical plant, refinery heat exchange systems, gas plant process, injection molding systems, and pulp and paper processing. These oils are extremely stable and resistance to thermal and oxidative degradation. In the event of a spill or accidental release of heat transfer oils, it can be ignite easily when there is an ignition source. This paper discusses the flammability and thermal stabilities of new and used oils. The flammability of the oils are assessed by measuring changes in flash point and auto ignition temperature. The thermal stability of oils are evaluated by the thermal screening unit ($TS^u$) and the differential scanning calorimeter (DSC). From the experimental results, it is suggested to give fire hazard characteristics to safe precautions for the proper use and treatment of heat transfer oils.

• Journal of the Korean Institute of Gas
• /
• v.17 no.4
• /
• pp.9-17
• /
• 2013

Butanethiol is known as a typical odorant with hydrogen sulfide, methyl mercaptan, methyl sulfide, but on the physical and chemical properties and biological hazard assessment, including inhalation toxicity data are very scarce. Butanethiol as a colorless transparent liquid, and has physic-chemical characteristics with flash point as $-23^{\circ}C$ and strong fire risk, boiling point $84-85^{\circ}C$, vapor pressure 80.71 mmHg ($25^{\circ}C$), freezing point $-140.14^{\circ}C$. From whole body exposure with SD rats, the $LC_{50}$ is above 2,500 ppm (9.22mg/L), and then it is classified as the acute toxic chemical (inhalation) category 4 according to the governmental notification No. 2012-14.

• Journal of the Korean Institute of Gas
• /
• v.12 no.2
• /
• pp.1-6
• /
• 2008

For the safety design and operation of many gas process, it is necessary to know certain explosion limit, flash point, autoignition temperature (AIT) and minimum oxygen concentration of handling substances. Also it is necessary to know explosion limit at high temperature and pressure. In this study for the safe handling of hydrogen, explosion limit and AIT of combustion properties for hydrogen were investigated. By using the literatures data, the lower and upper explosion limits of hydrogen recommended 4.0 vol% and 77.0 vol%. Also the AIT of hydrogen with ignition sources recommended $400^{\circ}C$ at the electrically heated crucible furnace (the whole surface heating) and recommended $640^{\circ}C$ at the local hot surface. The new equations for predicting the temperature and the pressure dependence of the explosion limits of hydrogen are proposed. The values calculated by the proposed equations were a good agreement with the literature data.

• Fire Science and Engineering
• /
• v.27 no.1
• /
• pp.39-45
• /
• 2013

This study analyzes the explosion hazard of dry cleaning solvent recovery machine in laundry shop in two aspects, i.e. combustible and ignition source, and determines the explosive conditions of this machine by conducting mockup explosion tests repeatedly, varying conditions and using real dry cleaning solvent recovery machines. As to combustibles, two kinds of combustibles used widely in Korea have been selected and tested. The flash points, LEL's, and saturation vapor pressures of those combustibles have been measured, and their explosion specific curves have been drawn, based on the results of the measurements, so that the explosion risks of those materials may be determined, depending on the temperatures. Potential voltages generated from materials for laundry and foreign materials of metals have been assumed to be the ignition sources in this application, and their potential voltages have been measured, depending on temperature, humidity, and antistatic agent, by using real materials for laundry and a potential voltage measuring device. Tests have been conducted, varying the quantities, concentrations, and operating temperatures of materials for laundry. As a result, explosions have not been generated with potential voltages of materials for laundry, but explosions have been observed when applying artificial spark energy of 2.0 mJ.

• Journal of Energy Engineering
• /
• v.14 no.2 s.42
• /
• pp.159-166
• /
• 2005

In Korea, although the generation of waste plastic has been increasing, the rate of recycling is considerably low and moreover, there is no suitable method for the treatment of waste plastics. However, pyrolysis, which is appropriate for the treatment of highly polymerized compounds, such as plastics, has recently gained much interest. In this study, a property of the products from the pyrolysis of mixed waste plastics, with a possible practical use for the recycling oil produced, were assessed. First of all, in order to investigate the pyrolysis characteristic of waste plastics, TGA (Thermogravimetric analysis) and DCS (Differential Scanning Calorimetry) were performed on a number of different plastics, including PP, LDPE, HDPE, PET and PS, as well as others. According to the result, it appeared that PP was the most efficiently pyrolyzed by changing the temperature, followed by LDPE, HDPE, PET, PS and the other plastics, in that order. From the results, the optimum conditions f3r pyrolysis were set up, and the different waste plastics pyrolyzed. The recycling oil produced from the flammable gases generated during the pyrolysis was com-pared with fuel oil by an analysis using the petroleum quality inspection method on KS(Korea industrial Standard). The results of the analysis showed the recycling oil was of a similar standard to fuel oil, with the exception of the ignition point, with a quality somewhere between that of paraffin oil and diesel fuel. With respect to these results, the quality of the recycling oil produced by the pyrolysis of waste plastics was suf-ficient for use as fuel oil.

• Journal of Energy Engineering
• /
• v.22 no.2
• /
• pp.237-244
• /
• 2013

The engine oil is used for lubrication of various internal combustion engines. Recently, the vehicle and engine oil manufacture usually guarantee for oil change over 15000~20000 km mileage, but the most of driver usually change engine oil every 5000 km driving in korea. It can cause to raise environmental contamination by used engine oil and increase the cost of driving by frequently oil change. In this study, we investigate the various physical properties such as flash point, pour point, kinematic viscosity, cold cranking simulator characteristics, total acid number, four-ball test and concentration of metal component for fresh engine oil and used engine oil after real vehicle driving (5000 km, 10000 km). The result showed that the total acid number, wear scar diameter by four-ball test, Fe and Cu had increased than fresh engine oil, but 2 kind of used oil (5000 km and 10000km) had similar physical values and concentration of metal component.

• International Journal of Highway Engineering
• /
• v.9 no.2 s.32
• /
• pp.51-62
• /
• 2007

Recently, the pavement distresses in the bridge deck have seriously affected the durability of bridge deck and driver's safety. The existing asphalt materials have the limitations in reducing the pavement distresses of brides deck. To protect the bridge deck and withstand the high deflection, it is necessary to develop the asphalt materials with good fatigue resistance for bridge deck pavement. The asphalt binder combined with SBS and two other admixtures has been developed for improving the resistance to fatigue cracking, productivity, and workability for bridge deck pavement. Based on the various binder test results, the developed binder is found to be PG 70-34 indicating very higher resistance against fatigue cracking. Fatigue testing, wheel tracking testing, and moisture susceptibility testing have been conducted to evaluate the performance of asphalt mixtures developed in this study. Laboratory test results show that the developed asphalt material has three times higher fatigue lives than the typical modified asphalt mixture. Full scale accelerated testing was also performed on the typical asphalt mixture and newly developed asphalt mixture to evaluate the full scale performance of asphalt mixtures. Test results indicate that the length of cracking on the new materials is only 38% of the typical material at the 250,000 load repetitions.

• Journal of Advanced Marine Engineering and Technology
• /
• v.40 no.4
• /
• pp.362-368
• /
• 2016

In the recent International Maritime Organization's (IMOs) Maritime Safety Committee's 93rd session, the International Chamber of Shipping and International Parcel Tankers Association addressed marine fuel oil quality problems: increasing diluents in marine fuel oil, ignition in engine rooms due to the low flash point of fuel oil, and marine fuel oils that can damage marine engines. To deal with these marine fuel oil quality problems, the International Maritime Organization secretariat appointed the worlds marine fuel oil monitoring institute and constituted a correspondence group to determine the fuel oil quality required by MARPOL Annex VI regulation 14.8 (sulfur content less than 0.5%). In this study, basic research that can help with responding to marine fuel quality issues and the IMO's work is conducted. In order to perform this basic research, the off-spec ratio related to the fuel oil quality standard (ISO 8217:2012), density distribution tendency, gross specific energy, and correlation between components in the fuel oil are analyzed through actual marine fuel oil (residual marine fuel) data from the Port of Singapore.

• Applied Chemistry for Engineering
• /
• v.24 no.3
• /
• pp.274-278
• /
• 2013

Automatic transmission fluid (ATF) is used as an automatic transmission in the vehicle or as a characterized fluid for automatic transmission. Recently, vehicle manufacturers usually guarantee for changing fluids over 80000~100000 km mileage or no exchange. However, most drivers usually change ATF below every 50000 km driving distance when driving in Republic of Korea according to a survey from the Korea Institute of Petroleum Management which can cause both a serious environmental contamination by the used ATF and an increase in the cost of driving. In this study, various physical properties such as flash point, pour point, kinematic viscosity, dynamic viscosity at low temperature, total acid number and four-ball test were investigated for both fresh ATF and used ATF after the actual vehicle driving distance of 50000 km and 100000 km. It was shown that most physical properties were suitable for the specification of ATF, but the foam characteristics of the used oil after running 100000 km was unsuitable for the specification of fresh ATF. Therefore, the exchange cycle of ATF every 80000~100000 km driving distance is recommended considering great positive contributions to preventing environmental pollution and reducing driving cost.

• Journal of the Korean Applied Science and Technology
• /
• v.30 no.1
• /
• pp.35-48
• /
• 2013

Biodiesel is an alternative diesel fuel which can be obtained from the transesterification of vegetable oils, animal fats and waste cooking oil. The objective of this study is to evaluate the properties of biodiesel obtained from different feedstocks (soybean, waste cooking, rapeseed, cottonseed and palm oils). The biodiesel derived from different feedstocks was analyzed for FAME (fatty acid methyl esther) content, kinematic viscosity, flash point, CFPP (cold filter plugging point) and glycerin content. The quality of biodiesel was tested according to the Korean and European standard (EN14214, requirements and test method for biodiesel fuel). The biodiesels derived from soybean, waste cooking, rapeseed and cottonseed oils contain high amount of unsaturated fatty acid, while palm biodiesel is dominated by saturated fatty acid. The fuel properties of biodiesel, such as low temperature performance, kinematic viscosity and oxidation stability are correlated with the FAME composition components in biodiesel.