• Title/Summary/Keyword: 인화성물질

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Analysis of Ignitable Liquid Residues from Fire Debris Samples with GC/MS (GC/MS를 이용한 화재증거물속의 인화성물질 분석에 관한 연구)

  • Lee, Sung-Ryong;Han, Dong-Hun
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2010.10a
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    • pp.148-151
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    • 2010
  • 화재증거물 속의 인화성물질을 분석하는 기술은 현재 다양한 추출 및 농축법을 활용한다. 본 연구에서는 Tenax TA를 이용하여 화재증거물 속의 인화성물질을 농축한 후 자동열탈착 장비를 사용하여 Tenax TA관 속에 농축되어 있는 인화성물질을 자동열탈착시켜 GC로 보낸 후 MS 분석하는 기술을 소개한다. 이러한 전처리과정을 사용하여, 화재증거물속의 인화성물질(경유, 등유 등)을 분석하였는데, 물로 화재증거물을 물을 이용하여 소화하여도, 시간이 오래지난 화재증거물이라도 열탈착 장비를 이용한 분석은 경유, 등유등을 확인하는데 유용하였다.

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A study on the gelation properties of the flammable liquids (인화성액체의 겔화 특성에 관한 연구)

  • 강영구;정문호
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 1998.05a
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    • pp.185-188
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    • 1998
  • 인화성액체는 공장가동에 필요한 연료, 생산과정에서 사용되는 세척제$\cdot$용제, 원료 등 거의 모든 화학공업에서 광범위하게 사용되고 있다. 인화성 액체는 소방법에서 제4류로, 산업안전보건법에서는 인화성물질로, 선박안전법에서는 선적액체 위험물 중 인화성액체 물질로 각각 구분되어 제조, 저장, 취급, 운반, 이송시 지정수량과 저장, 취급방법의 규제 등으로 엄격히 관리되고 있는 실정이다. (중략)

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A Study on Prevention of Fire Accidents by Splash Filling in the Filtration Process of Pharmaceutical Companies (제약회사 여과 공정중 스플래쉬 필링에 의한 화재사고 예방대책에 관한 연구)

  • Kim, Sang Gil;Lee, Dae Joon;Yang, Seung Bok;Rhim, Jong Guk
    • Journal of the Korean Institute of Gas
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    • v.25 no.6
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    • pp.29-34
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    • 2021
  • Flammable substances are often present in the raw materials of pharmaceutical products manufactured by pharmaceutical companies. In this case, an excessive amount of flammable substances is added to make an intermediate, and flammable substances that do not participate in the reaction are removed through filtration and drying steps. In addition, the flammable liquid separated in the filtration process is accumulated in the form of splash filling in the filtrate container. In this case, vapor and mist of flammable liquid are generated, which lowers the lower limit of explosion and minimum ignition energy, and increases the risk of fire and explosion due to complex charging. In this study, by analyzing fire accidents that occurred during the recent filtration process of pharmaceutical companies, it is proposed to prevent static electricity accumulation by measures of nitrogen supply facilities, capacity improvement, conductive filter fabric and so on.

A Study on How to Evaluate Appropriate Ventilation Rate of Indoor Facility Handling Hazardous Substances by Their Flammable and Explosive Properties (유해화학물질을 취급하는 실내시설에서의 인화폭발성에 따른 적정 환기량 산정에 대한 연구)

  • Mansu Park;Cheong-Min Seo;Hyo-Soub Yoon;Kyoshik Park
    • Journal of the Society of Disaster Information
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    • v.20 no.2
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    • pp.293-301
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    • 2024
  • Purpose: Ministry of Environment statistics reveals more than 132 fire·explosion accidents in South Korea between 2014 and 2023. Among them, fire and/or explosion accidents are very impactive in their scale and consequence. This study aims to suggest a new method of reasonable way to calculate the ventilation rate of indoor facility handling hazardous chemicals based on their inflammability. Method: A new method to calculate the ventilation rate is based on the physicochemical properties of the chemicals handled, which is more reasonable compared with the current regulation based only on the floor area of the facility. Result: Considering the physicochemical properties, 178 chemicals based on their inflammability were studied and 168(94%) met the criteria for the current regulation. Some materials have been shown to require too much or too little ventilation rate. Conclusion: Through this study, a reasonable method of calculating the required ventilation rate was proposed. This should be applied to ensure the safety of workers to deal chemicals.

A Study on Optimal Ventilation Design for Gas Boxes Installed in Semiconductor Manufacturing Equipment Handling Flammable Liquids (인화성 가스를 취급하는 반도체 제조장비에 설치된 가스박스 최적 환기 설계에 대한 연구)

  • Gyu Sun Cho;Sang Ryung Kim;Won Baek Yang
    • Journal of the Korean Institute of Gas
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    • v.27 no.1
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    • pp.63-69
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    • 2023
  • Although Korea is the world's No. 1 semiconductor producing country, most studies are conducted with risk assessment for simple material risks due to the closedness of the site for industrial protection. In terms of industrial safety, a monitoring system such as a gas detector to determine the leakage of hazardous substances has been established, but research on effectively discharging harmful gastritis substances in case of leakage has only recently begun. Semiconductor manufacturing facilities (gas boxes) where a large amount of flammable materials are handled are currently being safety managed by using a gas detector and blocking the air inlet. It is difficult to dilute in a short time in case of leakage of flammable substances. Therefore, in this study, based on various criteria, the size of the duct according to the size of the gas box is determined and the appropriate size of the air inlet is studied to minimize the exhaust performance requirement without exposing hazardous chemicals to the outside in the event of a flammable leak. We want to do an optimal exhaust design.

Preserving Reliability of Evidence Containers for Fire Debris Containing Ignitable Liquids (유류화재증거물 보관용기의 신뢰성에 관한 연구)

  • Han, Dong-Hun;Lee, Sung-Ryong
    • Fire Science and Engineering
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    • v.27 no.2
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    • pp.70-74
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    • 2013
  • It is very important for the collected samples at fire scenes to be properly preserved for laboratory analysis. Preserving abilities of four type containers, metal cans, glass jars, zipper and heat sealed polymer bags, with the five ignitable liquids (toluene, n-octane, o-xylene, n-decane and n-hexadecane) were examined with gas chromatography-mass spectrometry. The glass jars with Teflon (PTFE) liner were the best ability to prevent the evaporation of the ignitable liquids.

A Study on the Assessment of Hazardous Properties of Flammable liquids (인화성액체의 위험성평가에 관한 연구)

  • Lee, Bong-Woo;Park, Chul-Woo;Song, Haak;Kim, Hak-Jin
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2009.04a
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    • pp.276-285
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    • 2009
  • 화학물질의 분류 및 표시의 국제표준화시스템(GHS)을 조기에 구축하고 국내에 사용하는 화학물질을 보다 안전하게 제조, 저장 및 운송하기 위하여 위험물안전관리법과 GHS시험 방법으로 다양한 인화성액체 시험을 실시하여 이들의 결과에 대한 연관성을 도출하고, 국내 실정에 적합한 국제표준화 시험방법을 선택가능방식(Building Block Approach)으로 제시하고자 한다. 위험물의 80%를 차지하는 인화성액체의 분류에 필요한 시험은 인화점이 가장 중요한 요소지만, 도료류와 같은 혼합물은 가연성액체량과 GHS-연소지속성에 따라 위험물/비위험물로 분류될 수 있다. 도료류는 두 시험의 분류결과가 대부분 비슷하게 나타나 GHS-연소지속성시험을 선택가능방식을 통해 우리나라에 적합하게 도입하는 것이 바람직 할 것으로 보인다.

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