• 상하수도학회지
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• 제8권2호
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• pp.25-34
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• 1994

In this research, investigations were made on the effect of type and load of organic substrate on phosphorus release. Reactors of three different sizes were operated, being fed on five kinds of organic substrates. The quantitative analyses were made on phosphorus release and substrate utilization under anaerobic condition. The molar ratios of the uptaken organic substrate to the released phosphorus were 0.5 with acetate, 0.6 with glucose, 0.8 with glucose/acetate, and 1.2 with glucose/acids, respectively. The phosphorus release was inhibited at the higher organic load than the normal at stead state. Both acetate and acids/glucose enhanced phosphorus release- as well as uptake-rate, however, the complete phosphorus removal was achieved after the microbial adaptation to the new environment. In case with acetate, operation was hampered by the poor sludge settleability and phosphorus uptake was not enough although the phosphorus release was active. But with milk/starch, the phosphorus release and uptake was well developed even though phosphorus release was not comparatively high. From this study, it was concluded that organic substrates, such as glucose seemed to be converted fatty acids after fast bio-sorption, followed by concurrent uptake of these acids by excess phosphorus removing bacteria.

• 상하수도학회지
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• 제18권2호
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• pp.137-144
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• 2004

In this study, several series of experiments were conducted to investigate the phosphorus (P) removal process in slag-containing solution using furnace and converter slags. High amount of $OH^-$, $Ca^{2+}$ and alkalinity were discharged from the slags and hydroxyapatites [$Ca_5(PO_4)_3(OH)$] were kept accumulated on the surface of slag. P removal capacity of the slag decreased with the increase of slag dosage. The maximum capacity was found to be 11.25 mg/g at the converter slag. Converter slag adsorbed P more than furnace slag(about four times in average). An experimental study on the effect of pH shows that the percentage removal of P increased upto 30% at the pH range of 56 than that of above pH 8. Langmuir isotherm constants gave a better correlation than Freundlich ones. P removal amount in the presence of $NH^+_4$ was less compared to the one in the absence of $NH^+_4$. Maximum percentage reduction was 23%.

• 한국물환경학회지
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• 제18권2호
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• pp.131-140
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• 2002

Laboratory-scale membrane bioreactor added alum into the anaerobic basin as a flocculant and adsorbent was carried out to find removal efficient of nitrogen and phosphorus components in the mixed liquid and weather or not maintaining the stability for the permeate flux and pressure at various internal recycle conditions. It was found that denitrification efficient of maximum 65% was obtained when the ratio of internal recycle was 3Q. Additionally when the ratio of internal recycle was fixed at 3Q, $BOD_5$ and T-P concentration of permeate was much more reduced compared to not added alum in anaerobic basin but T-N concentration of permeate was relatively increased. In case of added alum as the flocculant and adsorbent in anaerobic basin, the permeate flux was maintained above $10{\ell}/m^2/hr$ but the permeate pressure was relatively higher than alum was not added in anaerobic basin.

• 한국산학기술학회:학술대회논문집
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• 한국산학기술학회 2007년도 추계학술발표논문집
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• pp.305-307
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• 2007

Struvite(MAP) 및 hydroxyapatite(HAP) 결정화로 질소 및 인을 제거하기 위한 최적조건을 평가하기 위한 실험을 실시하였으며, $Mg^{2+}$, $NH_4^+$, $PO_4^{3-}$ 및 $Ca^{2+}$용액을 이용하여 인공폐수를 조제하였으며 각 이온의 몰비 조건을 1:1:1에서 실험을 수행하였다. $Ca^{2+}$ 및 $PO_4^{3-}$를 이용한 HAP 결정화는 알칼리조건의 pH 범위에서는 pH에 큰영향을 받지 않고 HAP가 형성되었으며, MAP 및 HAP 동시 결정화를 위한 실험에서는 pH가 증가하면서 $NH_4^+$, $PO_4^{3-}$ 제거효율은 감소하며 $Ca^{2+}$ 및 $Mg^{2+}$는 모든 pH에서 99% 이상 제거되었다. 폐수중에 $Ca^{2+}$이 포함되어 있다면 pH 9.5에서 $Mg^{2+}:NH_4^+:PO_4^{3-}:Ca^{2+}$는 1.2:1.0:1.2:2.0의 몰비로 존재했을 때 MAP 및 HAP 생성 최적조건인 것으로 나타났다. 그러나 pH가 10이상이 되면 부반응으로 인해 각종 무정형 결정체가 생성되므로 MAP 생성을 위해서는 pH 9.5로 운영을 하는 것이 가장 바람직하다.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2017년도 학술발표회
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• pp.112-112
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• 2017

하천은 크게 하도와 홍수터 그리고 제방으로 나눌 수 있으며, 최근 대하천 및 중 소규모 하천의 홍수터 공간을 활용하여 인공습지, 체육시설 및 공원 등과 같은 다양한 친수시설들을 조성하여 활용하고 있다. 이러한 홍수터는 여름철 태풍이나 집중호우로 인해 침수되다가, 강우 사상이 종료된 이후에는 유사가 퇴적되어 복구비용이 반복적으로 발생하고 있다. 홍수시 홍수터에서의 수리적 안정성을 평가하기 위해서는 홍수터를 포함한 복단면에서의 흐름해석이 선행되어야 하며, 계산된 수리적 인자들을 이용하여 홍수터에서의 수리적 안정성을 평가할 수 있다. 국외에서는 국내와 다르게 하천 홍수터 공간을 거의 활용하지 않기 때문에 홍수터에서의 수리적 안정성 평가에 대한 연구사례는 드문 실정이며, 도시침수로 인한 제내지 홍수위험도 평가에 대한 연구가 주를 이루고 있다. 하지만 기존에 사용되고 있는 제내지 홍수위험도 지수를 국내 홍수터에 도입하여 수리적 안정성을 평가하기에는 침식 및 퇴적을 올바르게 고려할 수 없는 한계점이 있기 때문에 본 연구에서는 홍수시 홍수터 내에서 침식과 퇴적을 고려할 수 있는 홍수터 수리적 안정성 지수를 산정하고 과거 연구된 실내 수리실험 자료와 비교하여 적용성을 분석하고자 한다. 또한 자연하천에서의 실제 태풍 사상에 의한 침식 및 퇴적의 상대적 공간분포를 산정하여 홍수터에서의 수리적 안정성을 평가하고자 하였다.

• 한국수처리학회지
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• 제26권6호
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• pp.117-124
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• 2018

For the effective removal of phosphorus in water, a novel type of composite was prepared by combining Poly Alumiun Chloride, widely used in sewage/wastewater treatment plants, and Humic Acid particles, which are known to have phosphorus removal ability, with CI. The surface of the ferromagnetic CI particles was oxidized and activated, and then PAC and HA were synthesized to finally produce CIPAC and CIHA. CIPAC and CIHA prepared by this study showed similar results to the phosphorus removal efficiencies of PAC and HA coagulants. The novel composite has a larger weight than the conventional coagulant, and the coagulated sludge precipitates rapidly. The sludge could be easily separated in a short time if the external magnetic field was given by the ferromagnetic force of CIPAC and CIHA prepared with CI as support. Therefore, it can be concluded that if phosphorus removal is carried out using CIPAC and CIHA prepared through this study with external magnetic field, the sedimentation rate will be much faster than that of conventional coagulant. Thus it is possible to obtain a high economic benefit in the sludge recovery part.

• 한국환경과학회:학술대회논문집
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• 한국환경과학회 2006년도 추계 학술발표회 발표논문집
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• pp.479-480
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• 2006

폐수의 부하량 감소를 위하여 전처리단계에서 전기응집장치를 이용한 총인 및 총질소, 생물화학적산소요구량과 화학적 산소요구량 등을 측정하고자 실험을 하였다. 실험결과 철 전극에서는 총인제거효율이 가장 높았으며, 총질소 제거 효율은 두 회사 폐수 모두 낮았다. Sus 및 Ti전극에서는 제거효율이 미미하였다. 따라서 부하량 감소를 위한 폐수의 전처리시 철전극사용시 가장효율이 좋으며, 부하량 감소는 90%이상임을 알 수 있었다.

• 상하수도학회지
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• 제18권4호
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• pp.470-479
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• 2004

The experimental conditions and relationships between parameters such as organic matter, aeration volume, aeration time, and precipitation time for the effective treatment of domestic wastewater were investigated. With the batch systems, the adsorption amount of unit microbe was measured with the change of MLSS concentration, precipitation time, and aeration amount. Theoretical adsorption amount of microbes was then numerically formulated by use of a SPSS multiple analysis as follows: $$Y=-0.0106(X_1)+0.07310(X_2)+42.705(X_3)+62.700$$ In this study, the amount of organisms to be removed in the range of MLSS concentration 2,000~4,500 mg/l were examined. In order to investigate the optimal condition of nitrification, the upper water in the biosorption stage was used as the initial experiment water. The results showed that the C/N ratio was 1.5 and the reaction time for the optimal nitrification was 1.5 hr. When the adsorption efficiency for microbe biosorption was 66%, the optimum denitrification efficiency was 83.3%. When the optimum parameters obtained from the batch experiment were applied to the lab-scale operation, the total retention time from the flow-in to flow-out was 10 hours and the removal efficiency was 93.8% for $COD_{cr}$ and 80.9% for TN. For the full-scale operation, the total retention time was 9.0 hours and the removal efficiency was 94.4% for BOD, 89.6% for $COD_{cr}$, 88.0% for TN, and 86.2% for TP.

• 한국물환경학회지
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• 제26권4호
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• pp.664-672
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• 2010

This study was performed to evaluate the feasibility of industrial by-products such as converter slag, olivine, red mud and fly ash as a seed crystal of struvite crystallization for the removal of highly concentrated $NH_4-N$ and $PO_4-P$. In the kinetic experiments, more than 90% of $NH_4-N$ and $PO_4-P$ was eliminated by struvite crystallization within 30 minutes of reaction time. The pH range in meta-stable region of struvite crystallization was found to be pH 7.0~9.0 under the Mg:N:P=1:1:1 equi-molar condition with 100 mg/L of $NH_4-N$. Total removal efficiencies of $NH_4-N$ and $PO_4-P$ by both struvite precipitation and crystallization were increased with the increase of pH. Removal efficiencies of $NH_4-N$ and $PO_4-P$ were significantly enhanced by struvite crystallization using industrial by-products as a seed crystal compared with those by struvite precipitation without seed crystal. Red mud, converter slag, olivine and fly ash enhanced the removal efficiencies of $NH_4-N$ by 40.9%, 37.7%, 28.4% and 16.4%, respectively. Removal efficiencies of $PO_4-P$ for converter slag, red mud, fly ash, olivine were increased by 3.7 times, 2.6 times, 72.4% and 68.0%, respectively. Converter slag and red mud showed higher feasibility as a seed crystal than others for the removal of highly concentrated $NH_4-N$ and $PO_4-P$. In particular, converter slag might have a high capacity of phosphorus removal.

• 한국농공학회논문집
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• 제46권5호
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• pp.155-163
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• 2004

The objectives of this study were to characterize the wastewater flow through the VFS, and relate this to the P removal in the VFS. A total of 68 subsurface wells (20∼40 cm below the soil surface) and 35 surface wells (0~5 cm), and the application of chloride tracer were used to investigate flow paths and soluble reactive P (SRP) removal from the 21 m wide and 33 m long VFS receiving dairy milkhouse waste. The early chloride breakthroughs in wells in the center of the VFS showed that the milkhouse waste flows preferentially down in the center of the hillslope. The locally saturated area created near the discharge pipe in the center of the VFS accelerates surface flow that contributed to rapid transport of P to the down slope area. Although VFS of 33m long eventually reduced SRP to lower than 0.2 mg/L in most cases, SRP is less effectively removed in the areas where soil saturation occurred. It is suggested that the effort to distribute the wastewater uniformly to avoid soil saturation and reduce the flow velocity need to be considered in new designs.