• The Journal of Engineering Geology
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• v.33 no.1
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• pp.39-49
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• 2023

Soil contaminants measured and managed in Korea include those of geologic origin such as arsenic, cadmium, copper, lead, zinc, nickel, mercury, and fluoride. This study identifies the distribution of these contaminants using GIS modeling to analyze the spatial probability of soil contamination originating from geology. The modeling found that cadmium, copper, lead, nickel, and mercury often exceed the regulated standard by <1%. Concentrations of arsenic and zinc greatly exceeded the standard in the vicinity of mines and industrial complexes: mining and industry seemed to have substantial effects on the concentrations of these metals. Although fluoride was sampled at the lowest number of points, its frequency of exceeding the standard was the highest. No obvious source of artificial contamination has been identified, and fluoride's distribution characteristics showed continuity over a wide area, suggesting a strong correlation between geological characteristics and fluoride concentration. The highest frequencies of fluoride exceeding the standard were in Jurassic granite (40.00%) and Precambrian banded gneiss (34.12%). As these rocks contributed to the formation of soil through their weathering, high fluoride concentrations can be expected in soil in areas where these rocks are distributed.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.1
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• pp.149-157
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• 2000

This paper presents the first results of dissolved arsenic in the Kangnung Namdae stream. The distribution of As concentrations measured in 28 August (high water flow) and in 21 November 1997 (low water flow) differs from those of other metals measured during the same period; The concentrations of Doam-dam are lower than those of Obong-dam and accumulation in the downstream in the period of low water flow is not pronounced. The As concentration in the downstream under the low water flow is lower than under high water flow, reciprocally to other metals. Freshwater concentrations are comparable with those measured in pristine river and lower than the world average and the diffrence of concentrations measured during two period is minute. Therefore, the As concentrations in the Namdae stream are background level and the source of As contamination does not exist. In the mixing zone between the freshwater and Donghae seawater, As behave conservatively, indicating the absence of any significant removal or mobilization processes. A first estimation of total dissolved As input from Namdae stream to Donghae coastal sea shows 65.12 kg/yr.

• Proceedings of the Korea Water Resources Association Conference
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• 2017.05a
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• pp.102-102
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• 2017

갈수시 하천의 수질문제는 다양한 요인에 의해 발생하고 제어된다. 수질 그 자체는 상류나 지류의 점오염원과 비점오염원의 증가 또는 예상치 못한 추가적인 오염원의 유출에 직접 영향을 받으며, 조류 등의 발생도 영향인자인 수온 및 일사량 또는 바람에 의존적이다. 최근 수년간은 특히 빈번한 가뭄조건의 발생으로 인하여 갈수기의 강우 및 유출량이 저조하여 상대적으로 하천의 조류발생이 다수 발견되고 보고된 바 있다. 이와 같은 수질의 이상상태를 일시적으로라도 제어하기 위한 방편으로 유량의 증가, 인위적인 하천 수위의 변동 및 유속 변동 등이 고려될 수 있으며, 이를 위해서는 상류의 댐과 하천의 다기능보 등의 조절을 탄력적으로 수행하여야 한다. 이와 같은 시설물 운영효과는 수질문제의 원인을 근본적으로 해결하는 것은 아니지만, 이의 일시적인 효과를 극대화하기 위해서는 기존의 수리 수질 모델링이 이상 수질 발생시의 방제 및 사후분석 등을 중심으로 이루어진 부분을 넘어서, 사전 설정된 조건에 의한 예측모의와 가이드라인의 연계방식이 효과적일 것이다. 본 연구는 수질 이상이 빈번히 발생되었던 낙동강의 칠곡 하류 하천을 중심으로 2차원 CE-QUAL-W2 모형과 EFDC모형을 병행 모의하여 다기능보 인근의 표층과 저층의 수온(밀도) 성층화 및 이의 해소와 관련된 수리모의 및 수질인자에 대한 영향을 분석하였다. 수리모형 구축의 적정성은 현장의 실측 수온과 모의결과 비교를 통해 확인하였으며, 구축된 수리 수질 모델을 이용하여 추가방류량 3~23백만$m^3$ 규모에서 발생하는 수리적인 수층혼합 현상과 일시적으로 저감가능한 수질개선 효과가 의미있는 수준으로 나타날 수 있음을 예측하였다. 또한, 다기능보의 수문방류 모의시에 개방조건을 0.3~3.5m로 달리하여 방류기간 중 총방류량이 유사하더라도 최대방류량 또는 유속이 충분치 않은 경우에는 혼합효과가 급격히 감소함을 알 수 있었다. 연구에서 밝혀진 조건들을 향후 보다 효과적으로 수치모의하기 위한 방안으로서 EFDC모형의 내부경계조건을 다기능보의 문비조건(RSG, Lift 등)에 맞게 조정하는 방법을 제안하고 그 적용성을 검토한 뒤 모형을 부분 수정하여 제시하였다.

• Analytical Science and Technology
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• v.24 no.4
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• pp.310-318
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• 2011

The collection of atmospheric $PM_{10}$ and $PM_{2.5}$ particle samples was made at Gosan site of Jeju Island, which is one of the most representative background sites in Korea. Their chemical compositions have been analyzed to explore the pollution characteristics and emission sources. The mass concentrations of $PM_{10}$ and $PM_{2.5}$ particles were $37.6{\pm}20.1$ and $22.9{\pm}14.3{\mu}g/m^3$, respectively, with the content of $PM_{2.5}$ to $PM_{10}$ as 61%. The $PM_{2.5}/PM_{10}$ ratios of nss-$SO_4^{2-}$, $NO_3^-$, and $NH_4^+$ were 0.94, 0.56, 1.02, respectively, indicating that these components were distributed mostly in the fine fractions. Based on the factor analysis, it was found that the compositions of fine particles were mainly influenced by anthropogenic sources, followed by soil or marine sources. The results of the backward trajectory analysis indicate that the concentrations of nss-$SO_4^{2-}$, $NO_3^-$, $NH_4^+$, nss-$Ca^{2+}$, and Pb were high when the air parcels moved from the China continent, while relatively low with the air parcels coming from North Pacific Ocean and/or East Sea.

• Korean Journal of Heritage: History & Science
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• v.46 no.1
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• pp.228-237
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• 2013

Paper relics are affected by a number of complex physical, chemical, biological and artificial damaging factors due to the vulnerability of organic materials. Wet cleaning is a conservation treatment method for removing pollutants from paper artefacts. This study was carried out in order to analyse the effect of wet cleaning on Hanji (Traditional Korean paper made from mulberry trees) which is the main material used in Korean paper relics (historical paper documents). For this study, the color change and folding endurance of artificially degraded paper was analysed before and after immersion wet cleaning. The result showed that washing each twice in 30 minutes is the most appropriate method for obtaining cleaning efficiency and material stability.

• The Journal of Engineering Geology
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• v.23 no.4
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• pp.493-502
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• 2013

This study investigates the design parameters for riverbed filtration (RBF) based on the geochemistry of river water and groundwater. The study area consists of alluvium, and the area is readily affected by non-point sources of chemical contaminants in the surface environment; this is expected to affect the design parameters for RBF. River and groundwater samples were collected at three points along the river flow and at nine points along a transect normal to the river, respectively. The geochemical data indicate that the sources of individual chemical contaminants are industrial facilities and agricultural activity near the study area. In addition, The samples are mainly Ca-Na-$HCO_3$, Ca-Cl, and Ca-$HCO_3$-Cl type waters. The design parameters of RBF in the study area should consider K, $HCO_3$, $NO_3$, and Cl. We divided the study area into three regions based on the concentrations of stable nitrogen isotopes: Region A, the origin of the river and denitrification; Region B, denitrification in the flow direction of tributaries; and Region C, the origin of natural soil, sewage, and anthropogenic pollution.

• Analytical Science and Technology
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• v.26 no.5
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• pp.333-339
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• 2013

This study was conducted to build up the inventories of Pb isotopic compositions of major Pb pollution sources in South Korea. Since non-ferrous metal smelters are one of major anthropogenic sources, two smelters for zinc, each one of smelter for lead and copper were selected for the study. The Pb concentrations and isotopic compositions of metal ores, wastewater, sludge, metal rod and produced sulfuric acid were analysed to understand the Pb isotopic patterns in environment. The isotopic ratio, $^{206}Pb/^{207}Pb$, of zinc ores from zinc smelter were in the range of 1.179~1.198 and the ratio of waste, flue gas and products samples were 1.105~1.147. This results implied that the isotopic patterns of output samples showed mixing patterns between two distinct metal ore soerces. In 2011, major importing countries of zinc ore were Australia, Peru and Mexico. Thus Pb isotopic patterns from zinc smelter is originated from the mixing patterns between less radiogenic Australian ores and more radiogenic South America's ores. Lead smelters also showed the same mixing patterns with those of zinc smelters. However copper smelter showed same Pb isotopic patterns with more radiogenic South America's ores.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.215-218
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• 2002

The purposes of this research are to identify the source and the extent of contamination of nitrate in groundwater in a typical agricultural area. The study area has many livestock raising facilities, rice paddies and grape farms. In order to identify the hydrogeological character, we sampled groundwater and surface water in 27 locations and performed chemical analyses. Nitrate-nitrogen is the major contaminant in this area. Approximately 32 ~ 42% of groundwater samples are over the drinking water limit(10 mg/L) and 77% estimated to be entered from artificial sources. The nitrogen isotope analysis indicates animal waste being the major source of nitrate in water samples. Not only presently operating livestock facilities but also abandoned ones influence groundwater quality for a long time.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.10
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• pp.756-766
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• 2011

In order to investigate the degree of apartment parking lot dust contamination, total 72 samples of parking lot dust (36 from ground parking lots and 36 from the underground parking lots) were collected in Daegu city from the end of March to the early June 2010. The dust samples were sieved below $100{\mu}m$, and analysed by ICP for 14 elements after an acid extraction. Results obtained from the source assessment of trace element using enrichment factor showed that Fe, K, Mg, Mn, Na and V were influenced by natural sources, while Cd, Cr, Cu, Ni, Pb and Zn were influenced by anthropogenic sources in both the ground parking lot and the underground parking lot. And results showed that Ca were influenced by natural sources in the ground parking lot, but influenced by anthropogenic sources in the underground parking lot. The measured values were remarkably higher in components from natural sources than in components from anthropogenic sources. Underground parking lot dust was more affected by anthropogenic sources and contaminated compared with the ground parking lot dust. Pollution index of heavy metals revealed that underground parking lot dust was 5.5 times more contaminated with heavy metal components than the ground parking lot dust. The results of correlation analysis among trace elements indicated that components in the ground parking lot were more correlated than those in the underground parking lot, and especially more correlated with natural sources-natural sources. Analysis for correlations between components and influencing factors in the underground parking lot showed that concentrations of heavy metals were higher with smaller number of parking spaces and no ventilation system, and older apartments in last paint and cleaning had relatively higher contents of heavy metals than those of recently painted and cleaned.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.1
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• pp.69-78
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• 2010

In order to investigate the degree of household dust contamination, 48 samples of household dust (24 from urban area and 24 from rural area) in Daegu city were collected in vacuum cleaner during January to February 2009. Samples were sieved below 100 ${\mu}m$, and 14 elements (Al, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, V, Zn) were analyzed using ICP after acid extraction. Results obtained from the source assessment of trace elements using enrichment factor showed that Ca, Fe, K, Mg, Mn, Na, and V were influenced by natural sources such as weathered rock and resuspended soil, while Cd, Cr, Cu, Ni, Pb and Zn were influenced by anthropogenic sources such as fuel combustion and waste incineration. Concentrations were remarkably higher in components from natural sources than in components from urban anthropogenic sources. Household dust in urban area was more affected by anthropogenic sources compared with that of rural area. Pollution index of heavy metals revealed that urban area was 1.8 times more contaminated with heavy metal components than rural area. The correlation analysis among trace elements indicated that components were correlated with natural sources-natural sources (Al-Mg, Al-Mn, Fe-Mn) and natural sources-anthropogenic sources (Al-V, Fe-Cr, V-Mn) in both urban area and rural area. Trace element components of rural area were more correlated than those of urban area. Houses that use oil for heating fuel had relatively higher contents of heavy metals rather than those using gas or electricity for heating fuel. Houses with children also had higher contents of heavy metals. In addition, the age of houses was found to influence the heavy metal levels in household dusts, with older houses (>10years) having higher concentrations than newer houses (<10years) and houses located near the major road (<10 m) were found to have relatively higher heavy metal levels in household dust.