• Title/Summary/Keyword: 이중결합

Search Result 796, Processing Time 0.025 seconds

Modification of Rubbers through Chemical Reactions including Controlled/"living" Radical Polymerization Techniques (리빙라디칼 중합법을 포함한 화학적 방법에 의한 고무의 개질)

  • Joo, Sang-Il;Cho, Hyun-Chul;Lee, Seong-Hoon;Hong, Sung-Chul
    • Elastomers and Composites
    • /
    • v.44 no.2
    • /
    • pp.122-133
    • /
    • 2009
  • Rubbers, such as natural rubber, polybutadiene, styrene-butadiene rubber, nitrile-butadiene rubber, chlorinated rubber and EPDM, have been continuously improved in response to a heavy demand and a new property requirement from industry. One of the best ways to realize the improvement is the modification of rubbers through chemical reactions, which produce materials with novel properties. In this review, chemical modification reactions of rubbers that contain carbon-carbon double bond units either in their main backbone or as a side group were briefly summarized. The chemical reactions introduce functional groups or functional polymer chains to polymer backbone, which transform a classical rubber to a highly functional material. Especially, we focused on a controlled/"living" radical polymerization techniques, with which a revolutionary broadening of the spectrum of the materials with well defined molecular weight, molecular weight distribution, chain end-functionality and architectures become possible.

Criticizing the Market Concentration Regulation in Open Media Environment (개방형 콘텐츠 유통환경에서 시장집중 규제에 대한 비판적 고찰)

  • Lee, Chi Hyung;Lee, Jungmann;Lee, Jongwon
    • The Journal of the Korea Contents Association
    • /
    • v.12 no.11
    • /
    • pp.368-376
    • /
    • 2012
  • Government has strictly regulated the concentration of the media market because the number of broadcasters was traditionally limited and they had significant influence on public. However as the media market converges with Internet's open architecture, scarcity and pervasiveness are losing their roles in justifying media regulation. This article examines market convergence and its impact on market concentration, and criticizes the current concentration regulation. The study indicates that market performance are much governed by firm's competitive actions than market structure, and that vertical integration contributes to service innovations, and that horizontal concentration makes it difficult to measure due to its even-changing market definition. Therefore, the regulation for market concentration should shift its focus from firm's market share to broadcaster's unfair acts driving market inefficiency and hurting content diversity.

Oxidative Characteristics of Triglyceride Molecular Species in the Presence of Prooxidants (산화촉진제 공존하에서의 트리글리세리드 분자종의 산화특성)

  • Yoon, Hyeung-Sik;Kim, Seon-Bong;Park, Yeung-Ho
    • Korean Journal of Food Science and Technology
    • /
    • v.22 no.1
    • /
    • pp.7-12
    • /
    • 1990
  • The effect of $Fe^{2+}$ and myoglobin on the oxidative stability of triglyceride molecular species was investigated at $25^{\circ}C$. The molecular species of soybean oil triglycerides were analyzed by capillary column gas chromatography and electron impact ionization mass spectrometry utilizing selected ion monitoring. When $Fe^{2+}$ and myoglobin were added to soybean oil triglycerides, the oxidative stability of each molecular species of triglycerides appeared to decrease in proportion to the increase in the number of double bonds present in the acyl residues, and it was affected by degree of unsaturation of fatty acid when the total degree of unsaturation of triglyceride was the same. But the length of the saturated acyl chain had no influence on the stabilization of unsaturated fatty acid present in the same glyceride when prooxidants were added.

  • PDF

An Open Source Mobile Cloud Service: Geo-spatial Image Filtering Tools Using R (오픈소스 모바일 클라우드 서비스: R 기반 공간영상정보 필터링 사례)

  • Kang, Sanggoo;Lee, Kiwon
    • Spatial Information Research
    • /
    • v.22 no.5
    • /
    • pp.1-8
    • /
    • 2014
  • Globally, mobile, cloud computing or big data are the recent marketable key terms. These trend technologies or paradigm in the ICT (Information Communication Technology) fields exert large influence on the most application fields including geo-spatial applications. Among them, cloud computing, though the early stage in Korea now, plays a important role as a platform for other trend technologies uses. Especially, mobile cloud, an integrated platform with mobile device and cloud computing can be considered as a good solution to overcome well known limitations of mobile applications and to provide more information processing functionalities to mobile users. This work is a case study to design and implement the mobile application system for geo-spatial image filtering processing operated on mobile cloud platform built using OpenStack and various open sources. Filtering processing is carried out using R environment, recently being recognized as one of big data analysis technologies. This approach is expected to be an element linking geo-spatial information for new service model development and the geo-spatial analysis service development using R.

Reduction of Cell Membrane Toxicity of Amphotericin B Using Liposome System (리포좀계를 이용한 Amphotericin B의 세포막 독성 저하)

  • 박인철;양지원김종득최태부
    • KSBB Journal
    • /
    • v.9 no.3
    • /
    • pp.266-271
    • /
    • 1994
  • Lipsome system composed of egg phosphatidylcholine was employed to reduce the membrane toxicity of Amphotericin B(Amp. B). Liposomal Amp. B, which showed a free drug equivalent antibiotic effect on fungi, displayed a remarkable reduction of toxicity of the drug against the membrane of red blood cell than that of fungizone which has been used in clinical treatment, and it shows conspicuously lowered toxicity on red blood cells. However liposomal Amp. B which contains cholesterol as a component of liposome lowered the antibiotic effect and toxicity than that phosphatidylcholine liposome. This due to the affinity between Amp. B and cholesterol. In addition to this, ${\beta}$-glucuronidase from snail juice crude enzyme reveals synergistic effect on liposomal Amp. B and free Amp. B. We also obtained positively raised antibiotic effect, when enzyme which is coupled with palmitic acid using NHSP inserted into liposome bilayer From these results, we suppose that the use of liposomal system in the case of Amp. B shows increasing antibiotic effect and dramatically lowered toxicity, thus, we think that we can solve the problem of Amp. B toxicity, which cause hesitate of clinical use.

  • PDF

Ab initio Calculation for Photochemistry of Psoralens (소랄렌의 광화학 반응에 대한 Ab initio 계산)

  • Kim, Ja-Hong;Kwon, O-Hyung
    • Journal of the Korean Chemical Society
    • /
    • v.53 no.3
    • /
    • pp.244-256
    • /
    • 2009
  • The psoralen-pyrimidine base complexes resulting from interstrand cross-linking through $C_4$-cycloaddition is studied by ab initio and DFT methods. The results indicate that in the case of the molecular complex formation between psoralens and pyrimidine base, the most probable photocycloadditions are 8-MOP< >Thy, Ps< >Cyt and Ps< >Thy. The geometries of photoadducts were optimized at the HF levels and ${\Delta}{G^{\circ}}$ were calculated. The photocycloadduct was inferred to be a C4-cycloaddition product with the stereochemistry of trans-syn 8-MOP< >Thy, trans-anti Ps(3, 4)< >Cyt, trans-anti Ps(12, 13)< >Cyt, trans-syn Ps(3, 4)< >Thy, trans-syn Ps(12, 13)< >Thy, trans-anti Ps(12, 13)< >Ps(12, 13), cis syn, cis anti Thy< >(3, 4)Ps(12, 13)< >Thy.

Power study for 2 × 2 factorial design in 4 × 4 latin square design (4 × 4 라틴방격모형 내 2 × 2 요인모형의 검정력 연구)

  • Choi, Young Hun
    • Journal of the Korean Data and Information Science Society
    • /
    • v.25 no.6
    • /
    • pp.1195-1205
    • /
    • 2014
  • Compared with single design, powers of rank transformed statistic for testing main and interaction effects for $2{\times}2$ factorial in $4{\times}4$ latin square design are rapidly increased as effect size and replication size are increased. In general powers of rank transformed statistic are superior without regard to the diversified effect composition and the type of error distributions as nontesting factors are few and effect size are small. Powers of rank transformed statistic show much higher level than those of parametric statistic in exponential and double exponential distributions. Further powers of rank transformed statistic are very similar with those of parametric statistic in normal and uniform distributions.

Development of Tracking Equipment for Real­Time Multiple Face Detection (실시간 복합 얼굴 검출을 위한 추적 장치 개발)

  • 나상동;송선희;나하선;김천석;배철수
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.7 no.8
    • /
    • pp.1823-1830
    • /
    • 2003
  • This paper presents a multiple face detector based on a robust pupil detection technique. The pupil detector uses active illumination that exploits the retro­reflectivity property of eyes to facilitate detection. The detection range of this method is appropriate for interactive desktop and kiosk applications. Once the location of the pupil candidates are computed, the candidates are filtered and grouped into pairs that correspond to faces using heuristic rules. To demonstrate the robustness of the face detection technique, a dual mode face tracker was developed, which is initialized with the most salient detected face. Recursive estimators are used to guarantee the stability of the process and combine the measurements from the multi­face detector and a feature correlation tracker. The estimated position of the face is used to control a pan­tilt servo mechanism in real­time, that moves the camera to keep the tracked face always centered in the image.

Optimum Subband Quantization Filter Design for Image Compression (영상압축을 위한 최적의 서브밴드 양자화 필터 설계)

  • Park, Kyu-Sik;Park, Jae-Hyun
    • The KIPS Transactions:PartB
    • /
    • v.12B no.4 s.100
    • /
    • pp.379-386
    • /
    • 2005
  • This paper provides a rigorous theory for analysis of quantization effects and optimum filter bank design in quantized multidimensional subband filter banks. Even though subband filter design has been a hot topic for last decades, a few results have been reported on the subband filter with a quantizer. Each pdf-optimized quantizer is modeled by a nonlinear gain-plus-additive uncorrelated noise and embedded into the subband structure. Using polyphase decomposition of the analysis/synthesis filter banks, we derive the exact expression for the output mean square quantization error. Based on the minimization of the output mean square error, the technique for optimal filter design methodology is developed. Numerical design examples for optimum nonseparable paraunitary and biorthogonal filter banks are presented with a quincunx subsampling lattice. Through the simulation, $10\~20\;\%$ decreases in MSE have been observed compared with subband filter with no quantizers especially for low bit rate cases.

High gain and broad bandwidth antenna design using cylindrical magneto material (원통형 자성체를 이용한 고이득 및 광대역 안테나 설계)

  • Lee, Ji-Chul;Min, Kyeong-Sik
    • Journal of Navigation and Port Research
    • /
    • v.34 no.1
    • /
    • pp.21-26
    • /
    • 2010
  • This paper describes patch antenna design method of antenna high gain and broad bandwidth using cylindrical magneto material around feeding line. Strong current induction method applied combination to generate magnetic fields around feeding line for antenna high gain characteristic and principle of PIFA designed application for design of antenna broadband. In case of single CMM, gain increased 3.96 dB compare with the reference antenna gain however bandwidth characteristic not increased compare with the reference antenna. In case of dual CMM, gain improved about 10 dB compare with the reference antenna and -10 below bandwidth is 700 MHz(50 MHz~750 MHz) with this paper designed high gain characteristic.