• Title/Summary/Keyword: 이종 복합재료

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Surface Modification and Bioactivity Improvement of 3Y-TZP Substrate by Spray Coating of Hydroxyapatite/Fosterite Composite Powder (하이드록시아파타이트/포스터라이트 복합분말의 분사코팅에 의한 3Y-TZP 기판의 표면개질과 생체활성 증진)

  • Yu Hyeon Yun;Jong Kook Lee
    • Korean Journal of Materials Research
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    • v.33 no.8
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    • pp.337-343
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    • 2023
  • 3Y-TZP (3 mol% yttria-stabilized tetragonal zirconia polycrystals) ceramics have excellent mechanical properties including high fracture toughness, good abrasion resistance as well as chemical and biological stability. As a result, they are widely used in mechanical and medical components such as bearings, grinding balls, and hip implants. In addition, they provide excellent light transmittance, biocompatibility, and can match tooth color when used as a dental implant. Recently, given the materials' resemblance to human teeth, these ceramics have emerged as an alternative to titanium implants. Since the introduction of CAD/CAM in the manufacture of ceramic implants, they've been increasingly used for prosthetic restoration where aesthetics and strength are required. In this study, to improve the surface roughness of zirconia implants, we modified the 3Y-TZP surface with a biocomposite of hydroxyapatite and forsterite using room temperature spray coating methods, and investigated the mixed effect of the two powders on the evolution of surface microstructure, i.e., coating thickness and roughness, and biological interaction during the in vitro test in SBF solution. We compared improvement in bioactivity by observing dissolution and re-precipitation on the specimen surface. From the results of in vitro testing in SBF solution, we confirmed improvement in the bioactivity of the 3Y-TZP substrate after surface modification with a biocomposite of hydroxyapatite and forsterite. Surface dissolution of the coating layer and the precipitation of new hydroxyapatite particles was observed on the modified surface, indicating the improvement in bioactivity of the zirconia substrate.

Effect of Acoustic Emission During a Fatigue Test with Defect for Type II Gas Cylinder (피로시험시 발생하는 음향방출신호를 이용한 Type II Gas Cylinder의 손상평가)

  • Jee, Hyun-Sup;Lee, Jong-O;Ju, No-Hoe;So, Cheal-Ho;Lee, Jong-Kyu
    • Journal of the Korean Institute of Gas
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    • v.16 no.2
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    • pp.18-24
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    • 2012
  • This research seeks to evaluate damage on type II gas cylinder by an acoustic emission test when executing 20000 cycles fatigue test and thereafter burst test. Used gas cylinders in the experimental are three types as follows; one is sound cylinder, others are cylinders which contain longitudinal and transverse artificial defect. The size of artificial defect is a depth of 3 mm, width of 3 mm and length of 50 mm. In the case of the cylinder which artificial defect, unlike the expectation that it will burst in low pressure, the burst pressure of the cylinder did not differ much according to whether or not there were defects. However, when there was longitudinal defect, the location of burst was near the location of defect. This leads to the effect in which the thickness of the composite material becomes thinner according to the length of the longitudinal defect and this is judged to have an effect on the location of initiation and growth of crack in the liner. Also, for the acoustic emission signal, when there is longitudinal defect, the ratio of an event occurring at defect position among overall hits is more than 50 %, and the source location also accords very precisely with defect position.

Properties of a Thermosetting Epoxy Composite : Effect of Isothermal Physical Aging (에폭시 열경화 복차재료의 성질 : 등온물리시효의 효과)

  • 이종근;윤성호
    • Polymer(Korea)
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    • v.25 no.3
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    • pp.359-366
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    • 2001
  • Isothermal physical aging of a glass fiber/epoxy composite was examined at different aging temperatures ($T_a$) and degrees of conversion (monitored by the glass transition temperature, $T_g$) by means of the TBA torsion pendulum technique. The range of aging temperature was from 10 to $130^{\circ}C$ : the conversion was systematically changed from $T_g$=$76^{\circ}C$ to $T_g$=$177^{\circ}C$ (fully crosslinked). The effect of isothermal physical aging was manifested as perturbations of the modulus and mechanical loss vs. temperature in the vicinity of $T_a$ for all conversions. The rate of isothermal physical aging determined from the change of modulus with aging time at fixed aging temperature decreased and then increased with increasing conversion below T$_{a}$=9$0^{\circ}C$. There exists a superposition in aging rate vs. ($T_g$ -$T_a$) by shifting horizontally and vertically. This implies that the physical aging process is independent of the change of chemical structure as conversion proceeds. It has been found that water absorbed at the aging temperature below $70^{\circ}C$ during isothermal physical aging lowers the apparent aging rate. It is due to the absorbed water molecules forming strong polar interactions with hydroxyl group on network chain and reducing the segmental mobility during the physical aging.g.

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Dimensional Changes of Ceromer Crown by Water Absorption (치과용 심미수복재료 세로모에서 수분흡수와 체적 변화에 관한 연구)

  • Lee, Jong-Hyuk
    • The Journal of Korean Academy of Prosthodontics
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    • v.47 no.2
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    • pp.119-124
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    • 2009
  • Statement of problem: The increasing demand for esthetic restorations has been required developing new materials for tooth colored restoration. Ceromer(Ceramic Optimized Polymer) has some advantages over porcelain, and has gained increasing popularity in restorative dentistry. However, there is little information on the dimensional changes in a clinical restoration in moist conditions. Purpose: This study examined the dimensional changes in Ceromer restorations with a clinical crown shape that were fabricated in a clinical manner. Material and methods: The crowns for the maxillary central incisor were fabricated with two Ceromers($BelleGlass^{(R)}$ and $Targis^{(R)}$) using a similar clinical restoration manufacturing technique. A total of twenty specimens were prepared and immersed in distilled water at room temperature to allow for water absorption. The weight, height and width were measured at 24, 72 and 168 hours. The accumulated ratios of the changes were calculated and evaluated using a paired t-test and an independent independent t-test. Results: The dimensions and weight increased with increasing soaking time. $Targis^{(R)}$ showed significant differences in height and weight between 24 hours and the other times(P<.05). $BelleGlass^{(R)}$ showed significant differences in width and weight between 24 hours and the other times. The two materials showed different changing patterns of the dimensions but there were no statistically significant differences between them. Conclusion: The dimensions and weight of the Ceromer restorations were changed by water absorption. The clinical crown shaped specimen showed more complicated dimensional changes than the simplified specimens.

Surface and Chemical Properties of Surface-modified PE Powder and Mechanical and Thermal Properties of PMMA Bone Cement Containing PE Powder -VIII. Effect of the Molecular Weight of Polyethylene on Surface Modification (표면개질된 PE분말의 표면·화학적특성 및 이를 함유하는 PMMA 뼈시멘트의 열적·기계적특성 -VIII. PE분말의 분자량에 따른 표면개질효과)

  • Ko, Jong Tae;Yang, Dae Hyeok;Kim, Moon Suk;Khang, Gilson;Kim, Yong Sik;Rhee, John M.;Lee, Hai Bang
    • Journal of Adhesion and Interface
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    • v.7 no.3
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    • pp.1-9
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    • 2006
  • To improve the poor mechanical and thermal properties of conventional PMMA bone cement, we impregnated three types of polyethylenes (PE) (200, 3,800, and 8,000 kg/mol). MMA/xylene solution was used to modify the surfaces of PEs and new composite PMMA bone cements were manufactured by impregnating 3 wt% of the surface-modified PEs into conventional PMMA bone cement. As molecuar weigth of PE increased, tensile strengths of the manufactured composite PMMA bone cements were improved. Also, we confirmed that the curing temperatures of the composite PMMA bone cements decreased from near $100^{\circ}C$ to $40^{\circ}C{\sim}80^{\circ}C$.

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Study on the Rational Construction Method Using Analysis of the Case Study of PHC Pile Foundation in Song-Do Area (송도지역 내 PHC 말뚝기초 적용사례분석을 통한 적정 시공방법 연구)

  • Lee, Byengho;Lee, Jonghwi;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.3
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    • pp.55-61
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    • 2011
  • Song-Do international city is the area developed in large-scale land reclamation. Song-Do area consists of reclamation layer, sedimentary layer(loose silt, soft clay and sand alternating) and residual layer from the ground surface. Therefore, using pile foundation is inevitable to build structures safely. In this area, driven PHC piles have been generally constructed in terms of environmental and economic conditions. As a result of analyzing 4 sites in Song-Do district 5 and 7 recently, the method of driving pile has many problems because of existence of rigid soil in sedimentary layer and installation of more than 30m piles. In this case, when installing piles by drive after pre-boring up to appropriate depth, the results of constructability analysis were very good. And in the economic efficiency, although 4% of construction cost rose, it was a very slight increase in comparison with improvement of workability. In the case of the stability, more than 70% compared to the allowable stress of piles was satisfied through the load test. As a result, when PHC piles is installed in Song-Do district, the proper construction method is that piles are located at bearing layer after boring rigid sand layer.

A Study on Durability and Strength Properties of Compact Tension Specimen by Material through Simulation Analysis (시뮬레이션 해석을 통한 소재 별 소형 인장 시험편의 내구성 및 강도 특성에 관한 연구)

  • Lee, Jung-Ho;Cho, Jae-Ung
    • Asia-pacific Journal of Multimedia Services Convergent with Art, Humanities, and Sociology
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    • v.8 no.3
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    • pp.579-588
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    • 2018
  • There are the plastic resin, fiber and the single metal among materials. There is also the inhomogeneous material whose durability is improved as the composite material with the property of light weight. This study notices the composite material with light weight of CFRP. The strength properties of stainless steel and aluminum which have been used generally are compared and analyzed each other with CFRP. The compact tension specimen of the same standard by each material were designed and the simulation tensile analyses were carried out. As the study result, the maximum deformation, maximum stress and maxium strain energy are shown to be about 0.0148mm, 59.104MPa and 0.00529mJ respectively in case of CFRP specimen model. The maximum deformation, maximum stress and maxium strain energy were shown to be about 0.0106mm, 42.22MPa and 0.002699mJ respectively at stainless steel. It could be checked that the maximum deformation, maximum stress and maxium strain energy of aluminum specimen model were shown to be about 0.023mm, 33.29MPa and 0.00464mJ respectively at stainless steel. Therefore, the results at this study are thought to be applied with the basic data on the strength property of CFRP composite material.

A Study on Manufacture standardization of High Strength Concrete to Use Moderate Heat Portland Cement (벨라이트계 시멘트를 이용한 고강도 콘크리트 제조표준화에 관한 연구)

  • Park, Cheol;Kim, Dong-Suck;Um, Tai-Sun;Lee, Jong-Ryul
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.665-668
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    • 2008
  • Recently the city construction and the concrete structures are more becoming extra weight and the efficient use of the space by the population intensively and follow in industrial intensive commerce and the residence commerce composition building which leads the high story of the building. Consequently the high rise of the building which space applies efficiently in objective which will increase continuously. Also with high rise of buildings durability it will be able to increase the life of the structure is emphasized and the concrete structure is demanding the more high strength.

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Study of Optimal Weaving Shape according to Formability and Mechanical Properties of Polyethylene-based Self-reinforced Composite (폴리에틸렌 기반 자기강화복합재료의 성형성 및 기계적 특성에 따른 최적 제직형상 수치해석적 연구)

  • Yu, Seong-hun;Lee, Pil Gyu;Lee, Jong-hyuk;Kim, neul sae rom;Sim, Jee-hyun
    • Textile Coloration and Finishing
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    • v.34 no.1
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    • pp.58-67
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    • 2022
  • In this study, self-reinforced composite(SRC) was prepared using HDPE(High density polyethylene) fabric(2×2 plain) and LDPE(Low density polyethylene) film. The optimal conditions were derived by manufacturing specimens according to the temperature of 100 ~ 140℃ using a hot stamping at a pressure of 100bar for 10 minutes in order to find the optimal conditions for the SRC. The manufactured SRC was analyzed for tensile properties, compressive strength and shear strength through a universal testing machine(UTM). As a result of the measurement, the P3 specimen prepared by hot stamping at a temperature of 130℃ and a pressure of 100bar for 10 minutes was found to be higher than other specimens with tensile strength and tensile modulus of 210MPa and 19GPa, compressive strength 69MPa and shear strength 13MPa and it was considered to be optimal condition. Finally, the composite material according to the fabric structure was modeled using experimental values and the physical properties of the composite material according to the fabric structure were predicted using GeoDict and Digimat.

Experimental Study on Fatigue Characteristics of the Single Spot Welded Joint (점용접재(点熔接材)의 피로(疲勞) 특성(特性)에 관한 실험적(實驗的) 연구(硏究))

  • Chang-Min Suh;Sung-Soo Kang;Nam-Seong Hwang;Yong-Ich Cho
    • Journal of the Society of Naval Architects of Korea
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    • v.29 no.4
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    • pp.214-226
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    • 1992
  • In this paper, the characteristics of fatigue crack growth in the spot welded joint of the same kinds of specimens($HS{\times}HS,\;GA{\times}GAB$) and different kinds of specimens($HS{\times}GA,\;HS{\times}GAB$) which consist of dual phase high strength steel(HS) and monogalvanized steel(GA) were examined with static tension tests and axial tension fatigue tests. Some of the important results are as follows : 1. The divergence of tensile strengths among the same and different kinds of spot welds under the same conditions is comparatively low regardless of the difference of stiffness. 2. At the low load bevel and long life legion, the fatigue crack is initiated near the nugget. However, in the high load level and short life region, it occurs a tittle far from the nugget. 3. It has shown a linear relation between maximum stress Intensity factor, Kmax and fatigue life, $N_f$ among each of the spot welds and has gathered in a narrow band on the log-log graph paper. $Kmax=H{\cdot}{N_f}^{P}$ where H and P are a material constant.

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