• Title/Summary/Keyword: 이온 침투

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A Study on the Freezing and Thawing Resistance of Hardened Concrete under Sea Water Environment (해수 환경하 콘크리트 경화체의 동결융해 저항성에 관한 연구)

  • 정용철;김원기;정재동;한기성;최상홀
    • Magazine of the Korea Concrete Institute
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    • v.4 no.3
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    • pp.157-166
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    • 1992
  • 해수환경하의 콘크리트 구조물은 동결융해의 반복에 의한 물리적인 침식과 해수중에 용존하는 각종의 이온들의 침투로 인한 화학적 침식에 의해 현저한 성능저하현상을 나타내는 것으로 알려져있다. 본 연구는 포졸란계 혼합재인 플라이 애쉬, 슬래그, 슬리카 흄과 폴리머계 혼합재인 Ethylene Vinyl Acetate(EVA), Styrene-Butadiene Rubber(SBR)를 사용하여 제조한 콘크리트 경화체의 해수환 경하에서 동결융해 저항성에 미치는 혼합재의 종류 및 첨가량의 영향, W/C의 영향을 비교 검토한 실험적 연구이다. 콘크리트의 동결융해 저항성을 위해서는 공기연행이 필수적이며, 공기연행시킨 경우 W/C가 낮을수록 동결융해 저항성이 우수하였다. 해수중에서의 동결융해 저항성은 슬래그분말을 첨가할 때 우수하였으며, 폴리머계 혼합재에서는 EVA가 우수한 결과를 나타내었다.

Effects of Combined Attacks on Chloride Diffusivity in Concrete (콘크리트내의 염소이온 침투특성에 미치는 복합 열화작용의 영향)

  • 오병환;강의영;정상화;장승엽;인광진;서정문
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.665-670
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    • 2001
  • The studies on chloride diffusion of concrete have been done so far by many researchers. However, there are few studies that present the effects of other attacks on chloride diffusion properties. Therefore, in this study the experiments are carried out to show the effects of combined attacks, such as carbonation, sulfate attacks, on chloride diffusivity in concrete. The specimens are made by varying cement type and replacement ratio of fly ash. The results show that cement type and replacement of fly ash do not affect greatly chloride diffusion properties. And concrete treated by combined attacks show a little higher chloride content than those treated by chloride solution only. Therefore, the effects of these factors should be taken into account in predicting the penetration of chloride ion in concrete.

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Development of Multi-functional Polymer Adsorbent for Purifying the Environmental Pollutants by Photoinduced Graft Polymerization (II) - Adsorption Property of Uranium on the PP-g-AA Nonwoven (광그라프팅법을 이용한 다기능성 환경오염 정화용 고분자 흡착제의 개발 (II) - PP-g-AA 부직포의 우라늄 흡착특성)

  • 박현주;나춘기;김상률
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.344-346
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    • 2002
  • 그라프트중합법은 고분자막이나 직포, 부직포, 합성지 등에 기존 소재의 특성을 손상하지 않고 여러 가지 기능을 가진 관능기를 부여할 수 있다는 점에서 각종 섬유 및 범용성 고분자 소재의 개질 및 특성부여 방법으로 이용되고 있다[1,2,3]. 광조사에 의한 그라프트 중합법은 빛의 침투가 약하고 활성점이 균일하게 형성되지 못한다는 단점이 있으나 그 취급의 용이성 및 안전성, 설비의 경제성 및 실용성이 높을 뿐만 아니라 원재료의 물성을 크게 손상시키지 않으면서 특정 단량체를 그 표면에 도입시킬수 있어 섬유 및 고분자 재료의 표면성질이나 친수성 개선뿐만 아니라 역삼투성 및 이온선택투과성과 같은 기능성의 부여 등에도 적용 가능함이 확인되었다[4]. (중략)

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Development of Chloride Ingress Model in Reinforced Concrete Structures (철근콘크리트 구조물의 염소이온 침투 모델 개발)

  • 구현본;이광명
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.731-736
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    • 2002
  • The degradation of reinforced concrete (RC) structures due to physical and chemical attacks has been a major issue in construction engineering. Deterioration of RC structures due to chloride attack followed by reinforcement corrosion is one of the serious problems. The objective of this study is to develop a form of mathematical model of chloride ingress into concrete. In order to overcome some limits of the previous approaches, a mathematical model of chloride ingress into concrete consisting of chloride solution intrusion through the capillary pore and chloride ion diffusion through the pore water was proposed. Moreover, the variability of diffusivity of chloride ion due to degree of hydration of concrete, relative humidity in pore, exposure condition, and variation of chloride binding was considered in the chloride ingress model.

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A Study on the Permeability and Chloride lon Penetration of Concrete (물-시멘트비에 따른 콘크리트의 투과성 및 염화물 이온의 침투성에 관한 연구)

  • 형원길;소형석;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10c
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    • pp.179-184
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    • 1998
  • The permeability of concrete influences the durability of concrete remarkably. This paper describes a programme of permeability tests carried out to determine the differences between permeability coefficients derived using water, oxygen and chloride ions. Tests have been carried out on three concretes having water/cement ratios of 0.45, 0.55, 0.65 to measure their water, chloride-ion and gas permeability coefficients. The test results indicate that the permeability of concrete increase with the increase water cement ratios. The water and gas permeability coefficients is presented from $1.43$\times$10^{-10} to 19.01$\times$10^{-10}m/s$ and from $0.88$\times$10^{-10}$ to $1.59$\times$10^{-10}$m$^2$for concrete of different water cement ratios. The current intensity passing through the concrete is presented from 4504 to 4920 C.

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An Experimental Study on the Penetration of Chloride Ions to Concrete Subjected to Wetting and Drying Conditions (건습반복을 받는 콘크리트의 염소이온 침투에 관한 실험적 연구)

  • Kim Eun-Kyum;Choi Young-Kyu;Kim Seung-Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.838-841
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    • 2004
  • This paper presents the experimental results on the penetration of chloride. ions to ordinary portland cement concrete which is subjected to 2 different artificial environments; consecutive digestion, wetting at $3\%$ NaCl for 1 day and then drying at $40^{\circ}C$ oven for 4 days. The water-cement ratio was $35\%,\;45\%,\;55\%$. Test results showed that the intrusion depth and concentration of chloride ions penetrated into concrete in repeated wetting-drying environments were respectively deeper and higher than those of consecutive digestion environment. The penetration of chloride ions deeply depend on the effect of water to cement ratio.

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Analysis of Chloride Ion Penetraion for Marine Concrete Structure with Cyclic Humidity Environment (건습이 반복되는 환경하의 해양콘크리트 구조물에 대한 염소이온 침투 해석)

  • Han, Sang-Hun
    • Ocean and Polar Research
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    • v.26 no.1
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    • pp.43-50
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    • 2004
  • The diffusion model, which considers diffusion and sorption, is proposed. The FEM program developed on the basis of the diffusion model provides the estimation of chloride concentration according to cyclic humidity and sorption. After the humidity diffusion analysis is carried out, the chloride ion diffusion and sorption analysis are conducted on the basis of the preestimated humidity data in each element. Each element has different analysis variables at different ages and locations. At early ages, the difference between inner and outer relative humidity causes the chloride ion penetration by sorption. As the humidity diffusion reduces the difference with age, the effect of sorption on the chloride ion penetration decreases. By the way, the cyclic humidity increases the effect of sorption on the chloride ion penetration at early ages, and the quantity of chloride ion around steel at later ages. Therefore, the in situ analysis of chloride ion penetration for marine concrete structures must be performed considering the cyclic humidity condition and the long term sorption.

Prediction Model of Chloride Penetration in Concrete Bridge Deck Considering Environmental Effects (대기 환경조건을 고려한 콘크리트 교량 바닥판의 염소이온 침투 예측 모델)

  • Kim, Eui-Sung
    • Journal of the Korean Society of Safety
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    • v.23 no.4
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    • pp.59-66
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    • 2008
  • Recently, the deterioration of reinforced concrete structures, primarily due to corrosion of steel reinforcement, has become a major concern. Chloride-induced deterioration is the most important deterioration phenomenon in reinforced concrete structures in harsh environments. For the realistic prediction of chloride penetration into concrete, a mathematical model was developed in which the effects of diffusion, chloride binding and convection due to water movement can be taken into account. The aim of this research was to reach a better understanding on the physical mechanisms underlying the deterioration process of reinforced concrete associated with chloride-induced corrosion and to propose a reliable method for estimating these effects. Chloride concentrations coming from de-icing salts are significantly influenced by the exposure conditions such as salt usage, ambient temperature and repeated wet-dry cycles.

Analysis on Penetration of Chloride Ion into Carbonated Concrete in Marine Atmospheric Conditions (해양 대기 환경 하에서 탄산화 콘크리트에 대한 염소이온 침투 해석)

  • Choi, Doo-Man;Jang, Seung-Yup
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.233-236
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    • 2006
  • Chloride attack and carbonation induced corrosion of reinforcement are those of the main factors which cause the deterioration of concrete structures. The objective of this study is to suggest an analytic model for the prediction of chloride penetration into carbonated concrete, in order to make up for the current codes. Carbonation depth model considering the moisture effect is validated by being compared with the test data and the analytic model on chloride penetration into carbonated concrete is developed. Finally, the corrosion-initiation time has been predicted by the present model, being compared with that by the current code equation. The comparison shows that the current code equation can underestimate the chloride penetration into carbonated concrete in marine atmospheric conditions.

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Analytical study of the influence of crack width and depth on the penetration of chloride ion and the carbonation (균열 폭 및 깊이가 염소이온 침투 및 탄산화에 미치는 영향에 대한 해석적 연구)

  • Kim, Chin-Yong;Kim, Jin-Keun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05a
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    • pp.594-597
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    • 2006
  • Chloride ion penetration and carbonation are the most important factors in the durability problems of reinforced concrete structures. Most of the existing studies on those subjects are focused on the no-crack concrete, though the existence of crack may strongly affect the chloride ion penetration and carbonation. To evaluate the influence of crack on the chloride ion penetration and carbonation and to assess the service life of reinforced concrete more accurately, finite volume analyses (FVA) were performed based on the FV mesh containing the ideal crack whose width is uniform along the depth. Analytical results show that the influence of crack width and depth is much more pronounced for the chloride ion penetration than for the carbonation.

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