• Journal of the Korean Applied Science and Technology
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• v.36 no.4
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• pp.1088-1095
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• 2019

The CKD extract is wastewater from which KCl in CKD has been removed to reuse CKD as a cement raw material, and tried to reuse no extracts due to problems such as wastewater treatment facility expansion. As a result of removing KCl by the ion exchange method, the pH of the extract after ion exchange decreased from 12.7 to less than pH 2, and it was confirmed that H⁺ of the cation exchange resin was dissolved in the extract through ion exchange. In addition, the selectivity of the ion exchange was removed in the order of Ca²⁺, K⁺, it was determined that the increase in the contact time to remove the K⁺ ions. The batch system had a contact time of 6 times or more, compared to the continuous system, and showed 4 times of K⁺ removal efficiency and 7 times of Cl^- removal efficiency. It was showed by analyzing the pH of the extract that more H⁺ of the cation exchange resin was extracted than OH^- of anion exchange resin as the pH of the extract was changed.

• Membrane Journal
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• v.16 no.1
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• pp.77-84
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• 2006

Transport mechanisms of nickel ion through a continuous electrodeionization (CEDI) were investigated in terms of electric properties of ion exchange textile (IET). The porous plug model and extended Nernst-Plank (N-P) equation were applied for the description of transport mechanism of nickel ion. The model revealed that the CEDI performance was mainly due to the induced current not accelerated mobility by IET. This study also suggested that optimal operating conditions are attained with minimized electroregeneration region.

• Proceedings of the KAIS Fall Conference
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• 2002.11a
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• pp.306-308
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• 2002

원자로냉각재계통(Reactor Coolant System) 및 사용 후 저장조정화계통(Spent Fuel Pool Purification System)에는 양ㆍ음이온 교환수지가 충진된 혼상 이온교환수지탑을 설치하여 계통수에 존재하는 방사성 핵종을 제거하고 있으며, 정화율을 나타내는 제염계수(Decontamination Factor)가 특정값 이하이면 수지를 교체하고 있다. 그러나 특정 핵종에 대한 제염계수가 수지 사용기간에 관계없이 기준값 이하로 나타나고 있고, 수지탑의 성능을 예측하고 있지 못하는 실정이다. 원자력발전소 1차 계통에 설치되어 불순물을 제거하는 이온교환 수지탑에 대한 연속화학평형모델에 적용한 결과 수지탑에서 이온 용출은 수지에 대한 이온 선택도 순서와 동일하고 냉각재계통에는 붕산이 주성분이므로 음이온수지에서 붕산이 가장 먼저 누출된다. 그리고 붕산으로 포화된 음이온수지의 음이온 불순물 제거능력은 저하되지 않으며, 리튬으로 포화된 양이온수지의 양이온 불순물 제거능력은 저하된다.

• Journal of Radiation Protection and Research
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• v.24 no.2
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• pp.73-86
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• 1999

The ion-exchange method for the purification of primary coolant has been used broadly in PWR(pressurized water reactor)-type nuclear power plants due to its high decontamination efficiency, simple system, and easy operation. However, its non-selective removal of metal and non-radionuclides shortens its life, resulting in the generation of a large amount of waste ion-exchange resin. In this study, the feasibility of electrodeionization (EDI) was investigated for the purification of primary cooling water using synthetic solutions under various experimental conditions as an alternative method for the ion exchange. The results shows that as the feed flow-rate increased, the removal efficiency increased and the power consumption decreased. The removal rate was observed as a 1000 decontamination factor(DF) at a nearly constant level. For the synthetic solution of 3 ppm TDS (Total Dissolved Solid), the power consumption was 40.3 mWh/L at 2.0 L/min of feed flow rate. The higher removal rate of metal species and lower power consumption were obtained with greater resin volume per diluting compartment. However, the flow rate of the EDI process decreased with the elapsed time because of the hydrodynamic resistivity of resin itself and resin fouling by suspended solids. Thus, the ion-exchange resin was replaced by an ion-conducting spacer in order to overcome the drawback. The system equipped with the ion-conducting spacer resolved the problem of the decreasing flow rate but showed a lower efficiency in terms of the power consumption, the removal rate of metal species and current efficiency. In the repeated batch operation, it was found that the removal efficiency of metal species was stably maintained at DF 1000.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.4 no.3
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• pp.296-300
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• 2003

A large equilibrium and kinetic data set for multi-component cation exchanges was obtained and tested with mass action law and surface complexation model. The systematic batch equilibrium and column experiments of cation adsorption were conducted for binary, ternary, quaternary, and quinary cation exchanges involving $ H^{+}, Li^ {+}, Na^{+}, NH$_4$^{+}, Mg^{2+} $ on a strongly acidic cation exchange resin IRN 77. The mass action law and surface complexation model were tested against both data set to investigate the consistency of ion selectivity and their predictability for competitive cation exchanges. Surface complexation model provided more accurate predictions for both equilibrium and kinetic experimental data than mass action model.

• Membrane Journal
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• v.26 no.6
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• pp.432-448
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• 2016

In the last decade, various types of energy harvesting and conversion systems based on ion exchange membranes (IEMs) have been developed for eco-friendly power generation and energy-grid systems. In these membrane-based energy systems, high ion selectivity and conductivity properties of IEMs are critical parameters to improve efficiency of the systems such as proton exchange membrane fuel cells, anion exchange membrane fuel cells, redox flow batteries, water electrodialysis for hydrogen production, and reverse electrodialysis. This article suggests variable approaches to overcome trade-off limitation of polymeric membrane ion transport properties by reviewing various types of composite ion-exchange membranes including novel inorganic-organic nanocomposite membrane, surface modified membranes, cross-linked and pore-filled membranes.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.2
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• pp.51-58
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• 2017

We investigated the efficiency of natural zeolite with different cation exchange capacity (CEC) as capping material for the remediation of marine sediments contaminated with heavy metals. Three different zeolite with high CEC (HCzeo, 163.74 cmolc/kg), medium CEC (MCzeo, 127.20 cmolc/kg), and low CEC (LCzeo, 70.62 cmolc/kg) were used. The surface area of the zeolite was in decreasing order: HCzeo ($59.43m^2/g$) > MCzeo ($52.10m^2/g$) > LCzeo ($10.12m^2/g$). The results of mineralogical composition obtained from X-ray diffraction (XRD) show that LCzeo was mainly composed of quartz and albite. In the XRD result of MCzeo and HCzeo, the peaks of clinoptilolite, heulandite, and mordenite were also observed along with that of quartz and albite. Sorption equilibrium onto the HCzeo, MCzeo, and LCzeo was reached in 6 h at initial concentration of 10 mg/L and 100 mg/L. Higher adsorption of Cd and Zn onto the zeolite with higher CEC were achieved but adsorption of Cu and Ni were not dependent on the CEC of zeolite. It can be concluded that the zeolite with high cation exchange ability is recommended for the contaminated sediments with Cd and Zn but the inexpensive zeolite with low CEC for Cu and Ni.

• Clean Technology
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• v.3 no.2
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• pp.28-30
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• 1997

발효 아미노산을 분리하는 기존의 공정인 이온교환법에서 폐액 및 폐수처리에 따른 문제점을 해결하기 위한 새로운 분리공정으로 탈염 전기투석과 Water-splitting Electrodiaysis를 이용한 발효 아미노산의 분리 가능성 및 다양한 cell configuration과 막에 대한 성능 실험을 실시하였다. 실험결과 전기투석에 의해 경도물질을 제거한 후 양이온교환막과 bipolar 막으로 구성된 2-compartment WSED로 효과적으로 발효액에서 아미노산을 분리 할 수 있었으나 1가 양이온에 선택성을 지닌 양이온교환막으로는 아미노산의 분리가 어려움을 알 수 있었다.

• Applied Chemistry for Engineering
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• v.10 no.6
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• pp.871-875
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• 1999

We calculated the characteristics of a phosphoric cation exchanger and studied on an accurately computable method to determine the ion exchange capacity for type of potentiometric titration curve. The ion exchanger was prepared by phosphorylation of a styrene-divinylbenzene copolymer with 4% crosslinking. The ion exchange capacity is 5.7 meq/g. The experimental pK values versus ${\mathit{x}}$ in phosphoric cation exchanger can be expressed as a linear equation. The ${\Delta}pK$ values were obtained from the slope of linear equation. The ${\Delta}pK$ values are the differences of antilogarithms(pK) values of the apparent equilibrium constant at complete and zeroth neutralization of the ion exchanger. Also the experimental pK values at ${\mathit{x}}=0.5$ were accorded well with theoretical data. And when it is titrated with NaOH and $Ba(OH)_2$ solutions, a good agreement between experimental and theoretical pK values for various ${\mathit{x}}$ was seen in all the potentiometric titration curves. We knew that the inflection point of potentiometric titration curve in the case of divalent ions are changed much large than that for monovalent ions. If the relation between g values and ${\partial}pH/{\partial}g$ was plotted to the Lorentz distribution curve, ion exchange capacity can be accurately evaluated.

• Applied Chemistry for Engineering
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• v.10 no.1
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• pp.51-57
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• 1999

Adsorption characteristics of Ni(II), Co(II) and Ag(I) ions on the Amberite IRN 77 cation exchange resin have been studied to suggest the guide-line for the optimum operation of demineralization process in primary coolant system during the shut-down period of pressurized water reactor(PWR). The adsorption mechanism of each metal ion, Ni(II), Co(II) or Ag(I) ion, on a cation exchange resin was well coincided with Langmuir isotherm. The adsorption and treatment capacities of $H^+$-form resin were higher than those of $Li^+$-form resin. In the continuous ion exchange process for the solution of multi-component system, the selectivity of the resin was in increasing order of Ni(II)${\approx}$Co(II)>Ag(I). In addition, the increase of the flow rate decreased the treatment capacity of the resin as well as the slope of the breakthrough curve.