• Polymer(Korea)
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• v.31 no.4
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• pp.315-321
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• 2007

Aminated PONF-9-GMA ion exchange fabrics were synthesized by radiation induced graft copolymerization. Hybrid ion exchange fabrics combined with aminated PONF-g-GMA fabrics and anionic ion exchange resin were also fabricated by hot melt adhesion method and then their adsorption properties were investigated. Ion exchange capacity of the hybrid ion exchange fabrics was higher than ion exchange fabric and was lower than bead resin. The maximum value was 4.18 meq/g. Adsorption breakthrough time for vanadium of the hybrid ion exchange fabric was 550 min, which was faster than bead resin but slower than fibrous ion exchanger. The Breakthrough time of the hybrid ion exchange fabrics gets longer with increasing pH. The initial breakthrough time occurred around 400 min with increasing vanadium concentration.

• Applied Chemistry for Engineering
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• v.10 no.2
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• pp.206-211
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• 1999

Mixed-bed ion exchange performance was studied experimentally with variations of cation to anion resin ratio, resin weight and temperature at ultralow sodium chloride solution concentrations of less than $1.0{\times}10^{-4}M$. Analyzing the effluent concentration histories the performance test was examined as a function of tested solution volume for a laboratory-scale continuous flow column until both the cation and anion-exchange resins were exhausted. Initial leakage was observed for both cation and anion breakthrough curves, but serious at cation breakthrough curve because of low selectivity coefficient. The slope of breakthrough curve was affected by selectivity coefficient and temperature. The slope of anion breakthrough curve was steep because of the large selectivity coefficient, and ion exchange rates increased as temperature increased. The temperature effect decreased as the total volume was increased or as the resins were exhausted.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2006.05a
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• pp.278-279
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• 2006

본 연구에서는 수중 silica 제거에 이온교환수지의 성능이 실험되었다. 음이온 단일수지에 비해 양이온/음이온 혼합수지가 silica제거에 효과적이었고, 혼합수지에서 온도가 높을수록 교환반응속도는 빨랐다. 음이온과 양이온교환능은 용액의 pH를 변화를 측정하여 해석할 수 있었다. 용액에 공존하는 양이온인 $Na^+$는 혼합수지에서 pH변화에 영향을 주는 물질이었고, 이러한 pH의 변화는 silica의 제거능에 영향을 주었다. 각 온도에서 도달된 평형농도로부터 각 수지에 대한 silica의 선택도계수가 측정되었다.

• Proceedings of the Korean Nuclear Society Conference
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• 1997.10a
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• pp.375-380
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• 1997

모의 방사성 세탁폐액을 제조하여 오존에 의한 세제 파괴를 확인하고 활성탄 및 이온교환수지를 이용하여 세제 및 Co, Cs 제거율을 조사하였으며 모의 방사성 세탁폐액을 오존으로 부분적으로 산화ㆍ파괴시킨후 활성탄 및 이온교환수지에 의한 흡착 및 이온교환 실험을 수행하여 오존의 세제 파괴가 방사성 물질 제거에 미치는 영향을 조사하였다. 오존에 의해 세제는 75% 정도 제거될 수 있었고 활성탄으로 방사성 모의세탁폐액을 처리할 때 세제농도가 증가하면 방사성 핵종 제거율이 감소하였다. 이온교환수지로 세제를 제거할 때 성취가능 제거율은 Co의 경우 99% 이상이었으며, 세제 존재시 방사성 Co 및 Cs 제거율은 감소하며, 방사성 모의세탁폐액을 오존으로 조사후 활성탄과 이온교환수지로 방사성 핵종을 제거할 때 그 제거율은 거의 변화가 없었다. 이상과 같은 실험 결과로부터 오존으로 부분적으로 산화시켜 활성탄의 세제 제거효율을 최대화하고, 역삼투막에 의한 방사성 핵종을 제거하며 이온교환수지로 잔류 방사성 핵종을 완전히 처리할 수 있는 복합 공정을 도출하였다.

• Korean Journal of Materials Research
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• v.6 no.4
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• pp.364-371
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• 1996

본 연구는 이온교환에 의한 Li2O-AI2O3 계 결정화유리의 강화에 관한 연구이다. 모유리의 이온교환 전후의 강도를 비교하였으며, 결정화유리의 결정화전후에 이온교환에 따르는 강도를 상호 비교하였다. 그 결과 모유리의 Na+이온교환에 따른 최대 강도값은 45$0^{\circ}C$-3hr의 열처리 조건하에서 최고 6배(60Kg/mm2)의 강도값을 나타내었으며, 결정화후 이온교환에 따른 강도증가는 45$0^{\circ}C$-1hr의 열처리 조건하에서 최고 10배의 강도증대효과를 보였다. 한편 과도한 이온교환 열처리조건하에서는 응력이완현상을 나타냄을 알 수 있었다.

• Journal of the Korean Chemical Society
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• v.37 no.9
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• pp.820-825
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• 1993

The ion exchange capacity of HDBPDA ion exchanger, {(4,5) : (13,14)-dibenzo-6,9,12-trioxa-3,15,21-triazabicyclo[15.3.l]heneicosa-(1,17,19)(18,20,21) triene ion exchanger: HDBPDA ion exchanger} was 3.8 meq/g. The distribution coefficients of alkali and alkaline earth metal ions in water and the various concentration of hydrochloric acid were determined. Concentration of hydrochloric acid have almost not influenced on the distribution coefficients of alkali and alkaline earth metal ions, but generally, the distribution coefficient was slightly increased with decrease of concentration of hydrochloric acid. The distribution coefficients of metal ions in water are larger than those of various hydrochloric acid concentrations. Also, alkali and alkaline earth metal ions are separated by column ion exchange chromatography using HDBPDA ion exchange with water as eluent. The distribution coefficents of alkali and alkaline earth metal ions were increased with increase of ionic radii of metal ions.

• Analytical Science and Technology
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• v.6 no.3
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• pp.261-265
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• 1993

The ion exchange capacity of DBPDA ion exchanger, {(4,5):(13,14)-dibenzo-6, 9, 12-trioxa-3, 15, 21-triazabicyclo [15.3.1] heneicosa-1(21), 17, 19-triene-2, 16-dione : DBPDA ion exchanger} was 4.2meq/g. The distribution coefficients of alkali and alkaline earth metal ions in the various concentrations of hydrochloric acid were determined using DBPDA ion exchanger. Also alkali and alkaline earth metal ions were separated using DBPDA ion exchanger. From these results the effect of pH of solution and ionic radii of the metal ions on the distribution coefficients of alkali and alkaline earth metal ions were discussed.

• Proceedings of the Optical Society of Korea Conference
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• 1988.06a
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• pp.117-126
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• 1988

Sode-line 유리에서 Na+ K+ 이온교환시 이온교환 온도에 따른 Porassium 농도와 굴절률 변화량에 대한 관계를 구하였다. 그 결과 같은 potassium 농도에 따라서도 이오교환 온도가 높으면 굴절률 증가량이 작고 TM모드가 TE모드보다 굴절률이 증가량이 크다.

• Resources Recycling
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• v.24 no.3
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• pp.51-58
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• 2015

In order to recover tin from the waste tin plating solution, we used the ion exchange method using three types of ion exchange resins. The ion exchange resin with tertiary functional group(Lewatit TP 272) has not adsorption ratio of tin. The ion exchange resin with iminodiacetic functional group(Lewatit TP 207) has high adsorption ratio of tin, but impurity content in the recovered tin solution was relatively high. Whereas, in case of the ion exchange resin with functional group of ethylhexyl-phosphate(Lewatit VP OC 1026), adsorption ratio of tin was less than that of Lewatit TP 207. However, it was possible to remove impurities in the recovered tin solution by controlling the pH of the solution. High purity tin solution can be recovered by removing the organic materials with water washing process.

• Korean Journal of Food Science and Technology
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• v.27 no.3
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• pp.313-317
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• 1995

Ion exchange process was optimized to purify ultrafiltrated bean cooking water(BCW) for the production of soy-oligosaccharides. The ultrafiltrated BCW with cutoff MW(COMW) 20,000 membrane was treated with various ion exchange resins. Protein and ash were mostly removed by anion and cation exchange resins, respectively. Based upon removing capabilities for ash and protein, a cation exchange resin(SK1B) and an anion exchange resin(WA30) were selected. Protein and ash were more efficiently removed at low extract/resin ratios(ERR), but part of the oligosaccharides were concomitantly lost. When 2-step-ultrafiltrated BCW first with COMW 20,000 membrane and successively with COMW 5,000 membrane was treated with a mixed resin(SK1B : WA30 =1 : 2) at ERR 5.0, most oligosaccharides were recovered in a clear protein- and ash-free liquid.