• Title/Summary/Keyword: 이온확산

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Analysis of Chloride ion Penetration of Marine Concrete Structure - Part II. Application of Analysis Program- (해양 콘크리트 구조물의 염소이온 침투해석 - 개발된 프로그램의 적용 중심으로-)

  • 한상훈
    • Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
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    • 2002.08a
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    • pp.280-286
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    • 2002
  • 염소이온 확산해석을 실제 구조물에 대해서 수행하기 위해서는 여러 변수들에 대한 값들이 필요하다. 이러한 변수들에 대한 값들은 적용 배합에 대한 실험을 통해 직접 측정할 수도 있지만 설계 단계에서 염해에 의한 내구성을 평가를 위해 실험을 수행하기가 실용적인 관점에서 매우 어렵다. (중략)

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SC 제염용액에서 $Ce^{4+}/Ce^{3+}$이온쌍의 산화환원 특성 연구

  • 박상윤;문제권;정종헌;오원진
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05b
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    • pp.313-318
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    • 1997
  • 방사성 금속폐기물을 재활용하기 위한 제염기술로서 SC ( Sulfuric acid - Cerium) 제염의 기본특성을 파악하기 위해 Ce$^{4+}$ Ce$^{3+}$ 이온쌍의 산화환원 특성을 cyclic voltammetry 방법으로 연구하였다. 황산용액 내에서 Ce$^{4+}$ Ce$^{3+}$ 이온쌍의 산화환원 특성 조사를 위해서는 백금전극이 효과적이었다. 이중 실린더형 전해셀의 백금전극에서 Ce$^{4+}$ Ce$^{3+}$ 이온쌍의 산화환원에 대한 전달계수, 확산계수 및 비균일 속도상수 둥을 구하였으며, 각각 0,63 $\pm$ 0.05, (2.09$\pm$0.49) x $10^{-5}$ $\textrm{cm}^2$/sec 및 (2.53 $\pm$ 1.33) * $10^{-4}$ cm/sec 의 값을 나타내었다.

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Evaluation Method of Self-healing Performance of Cement Composites (시멘트 복합체의 자기치유 성능평가 방법)

  • Lee, Kwang-Myong;Kim, Hyung-Suk;Min, Kyung-Sung;Choi, Sung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.134-142
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    • 2020
  • In this study, in order to evaluate the self-healing performance of cement composites the self-healing test method and the analysis method were suggested by applying constant water head permeability test, chloride migration test and repeated bending test. The method of making a cracked specimen and controlling crack width are also proposed. Constant head water permeability test can evaluate the healing performance by using the decreasing rate of water flow passing through the crack zone of a specimen. Furthermore, the equivalent crack width can be used to intuitively investigate the healing effect with healing period. The chloride migration test can evaluate the healing rate by the decreasing rate of the diffusion coefficient obtained by ASTM C 1202. Mechanical healing performance can be evaluated using ISR and IDR estimated from load vs. CMOD relationship graph obtained through the repeated bending test. Finally, the applicability of proposed self-healing evaluation methods was examined by testing mortar specimens with or without self-healing agents.

Evaluation on Long-term Mechanical Performance and Durability of Recycled Coarse Aggregate Concrete Produced by Two-stage Mixing Approach (2단계 배합방법으로 제조된 순환굵은골재 콘크리트의 장기재령 역학적 성능 및 내구성 평가)

  • Seong-Uk, Heo;Jeong Jin, Son;Chul-Woo, Chung;Young Chan, Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.475-481
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    • 2022
  • Recycled aggregates show high water absorption rate compared to natural aggregates due to microcrack developed during production process and adhered cement pastes at the surface of recycled aggregates. This leads to the deterioration of mechanical properties and slow work flow. Currently it is getting hard to satisfy high demand for natural aggregates. Utilizing recycled aggregate more widely may be a substitutable countermeasure for the shortage of natural resources. In this study, two-stage mixing approach(TSMA) suggested by Tam et al. is used to produce recycled aggregate concrete(RAC) with 100 % replacement of coarse natural aggregate and tests for compressive strength, elastic modulus, and chloride ion diffusion coefficient are conducted to find out the effect of TSMA compared to normal mixing method. According to experimental result compressive strength and elastic modulus of RAC with TSMA was superior to those of RAC with normal mixing irrespective of water-cement ratio, and in some cases mechanical properties of RAC with TSMA approached to those of natural aggregate concrete(NAC). However, chloride ion diffusion coefficient of RAC was higher than that of NAC. This illustrates that TSMA is not an appropriate method in reducing chloride ion diffusion coefficient, resulting in inconsequential contribution of TSMA to the durability of RAC.

High Efficiency Diffusion Scrubber for the Collection of Water Soluble Gases in Ambient Air (대기중 수용성 기체 포집을 위한 고성능 확산 스크러버)

  • 장인형;이동수;이동훈;박영훈
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.324-325
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    • 2000
  • 대기 오염 성분에 대한 연구 뿐 만 아니라 반도체 가공 현장의 환경평가를 위한 미량 기체의 효과적인 포집 및 정량 방법이 요구되고 있다(Lue, S. J., 1999). 이들 오염원은 대부분 pub 이하의 농도로 존재하며 순간적으로 변화하므로 분석을 위해서는 연속적으로 여러 원소를 감시할 수 있는 장비가 효과적이다. 이러한 관점에서 스크러버 형태의 확산 포집기와 이온 크로마토그래피를 이용한 대기중 미량 기체의 연속 정량법이 가장 효과적이다. (중략)

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A Study on Hetero Junction using NiCuZn Ferrite System for SoP (NiCuZn 페라이트계를 이용한 SoP의 이종접합에 관한연구)

  • Kim, Nam-Hyeon;Kim, Gyeong-Nam
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.256-256
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    • 2012
  • SoP용 재료에 응용하기 위하여 NiCuZn 페라이트계 이용한 이종접합의 관한연구를 하였다. NiCuZn 페라이트계와 유전체의 이종접합특성은 XRD, Dilatometer, LCR meter, FE-SEM, EDS 이용하여 물리 화학적 특성을 조사하였다. NiCuZn 페라이트계는 일반적인 세라믹 제조공정을 이용하여 분말을 제조하였으며, 이종접합은 모든 시편에서 잘 진행되었으며 일부 유전체의 이온들이 페라이트 쪽으로 확산이 진행되었으며 NCZF700계는 $900^{\circ}C$ 소결 시편에서 확산이 진행되지 않은 현상이 나타났다.

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Characteristic changes of Ti layer on $Ti:LiNbO_3$ from various diffusion temperature and gas during $Ti:LiNbO_3$ optical waveguides fabrication ($Ti:LiNbO_3$ 광도파로 제작 동안 확산온도 및 분위기에 따른 Ti 층의 특성변화)

  • 양우석;이승태;김우경;박우정;윤대호;이한영
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.141-141
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    • 2003
  • 전기-광 효과를 이용한 광변조기, 스위치 등의 소자 구현을 위해 고품질의 Ti:LiNbO$_3$ 광도파로 제작은 필수적이다. LiNbO$_3$ 광도파로는 양자교환(APE) 및 Ti 확산 법으로 제조할 수 있으며 전자의 경우 ne 는 증가, no는 감소되는 경향이 있어 편광도 파로의 제작에 용의하며 후자의 경우 ne 와 no 모두 증가하는 도파로 특성을 갖는다. 이러한, 도파로 소자의 특성 향상을 위해서는 Li out-diffusion 이 억제된 손실이 적은 도파로 제작이 필수적이다. 본 연구에서는 Ti 내부 확산법을 이용한 LiNbO$_3$ 광도파로를 확산분위기를 조건으로 하여 제작하였으며, 온도에 따른 각 이온의 반응 메커니즘에 관하여 관찰하였다.

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Chloride Ingress through Cracks in Concrete: from Experiment to Modeling Strategy (균열을 통한 콘크리트의 염소이온 침투: 실험에서 해석기법까지)

  • Yoon, In-Seok;Sung, Jae-Duck
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.467-468
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    • 2010
  • Over the past few decades, considerable numbers of studies on the durability of concrete have been carried out extensively. The majority of these researches have been performed on sound uncracked concrete, although most of in-situ concrete structures have more or less micro-cracks. It is only recent approach that the attention has shifted towards the influence of cracks and crack width on the penetration of chloride into concrete. The penetration of chlorides into concrete through the cracks can make a significant harmful effect on reinforcement corrosion. Author of this study examined the effect of cracks on chloride penetration by short term experiment. However, it is necessary to accomplish the effect by long term experiment to get reliable goal. In this study, the long term and short term experiments were carried out. This can be useful for establishing new species model of chloride penetration through cracks in concrete.

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Characterization of Glasses by Ion-Exchange(I): Ion Exchange Behavior (이온 교환에 따른 유리의 특성화(I) : 이온 교환 거동)

  • 이동인;이용근;이희수
    • Journal of the Korean Ceramic Society
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    • v.25 no.3
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    • pp.237-242
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    • 1988
  • Ion exchange behavior of glasses was investigated in this study. The used glasses were Soda-limesilica glasses that was produced by float process. In order to analyse effects of ion exchange, some properties were measured; $K^+$ ion penetration depth, compressive stress, compression layer thickness, amount of $K^+$ ion exchange and density, in case of 43$0^{\circ}C$-8h and 45$0^{\circ}C$-6h, and activation energy is 17.0kcal/mole. Further it can be seen that excessive heat treatment brings about stress relaxation.

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Characteristics of Hydrodynamic Dispersion Using a Natural Gradient Tracer Test in a Fractured Rock at the Jwacheon-dong, Busan City (부산시 좌천동 단열암반층에서 자연구배 추적자시험을 이용한 수리분산특성 연구)

  • Chung Sang-Yong;Kang Dong-Hwan;Kim Byung-Woo
    • The Journal of Engineering Geology
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    • v.16 no.3 s.49
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    • pp.245-254
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    • 2006
  • Using a natural gradient tracer test, the characteristics of hydrodynamic dispersion according to each depth of a fractured rock were studied, and the effective porosity and longitudinal dispersivity of the fractured rock were estimated. The difference of vertical hydrodynamic dispersion was identified by concentration breakthrough curves linear regression analyses of bromide concentrations according to depths versus time, and hydraulic fracture characteristics at two intervals of the monitoring well. Higher concentration and faster arrival time at GL- 18 m depth (RQD 13%, average joint spacing 2 cm, TCR 100%) than at GL- 25 m depth (RQD 41%, average joint spacing 7 cm, TCR 100%) resulted from shorter distance and more fractures. Tracer was transported through the 1 st fractures until the arrival of its peak concentration and through the 2nd fractures or matrix diffusion after the arrival of its peak concentration. The increase/decrease slopes of bromide concentration versus time were 3.46/-1.57 at GL-18 m depth and 3.l9/-0.47 at GL- 25 m depth of the monitoring well. So the faster bromide transport was confirmed at GL- 18 m depth with more fractures. The concentration increment of bromide was fitted by a Gaussian function and the concentration decrement of bromide was fitted by an exponential function. Effective porosity and longitudinal dispersivity estimated by CATTI code were 10.50% and 0.85 m, respectively.