• Title/Summary/Keyword: 이온저장

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The effect of citric acid and enzyme inactivation treatment on C3G stability and antioxidant capacity of mulberry fruit alcoholic drink (구연산 및 효소 불활성화 처리가 오디술의 C3G 안정성과 항산화능에 미치는 영향)

  • Kim, Hyun-Bok;Kim, Jung-Bong;Koo, Hui-Yeon;Seok, Young-Seek;Seo, Sang-Deok;Kim, Sun-Lim;Sung, Gyoo-Byung
    • Journal of Sericultural and Entomological Science
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    • v.51 no.1
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    • pp.36-40
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    • 2013
  • To promote the consumption of mulberry fruit, we manufactured mulberry fruit wine with 'simheung' by different processing methods and analyzed cyanidin-3-glucoside(C3G) stability and antioxidant capacity. In the processing of mulberry fruit alcoholic drink, 3 minutes blanching using microwave inhibited the C3G destruction by maintaining the antioxidant capacity and inactivation of enzymes related to pigment's stability. And freeze-dried mulberry fruit was the highest C3G pigment content and antioxidant capacity. Nevertheless, this is not recommended because the economic burden of the cost of freeze-drying. In conclusion, when processing mulberry fruit wine, the addition of citric acid and the enzyme's inactivation treatment were considered more effective than storage containers (transparent glass, brown glass bottles, aluminum foil, green glass, translucent glass bottles).

사용후연료의 건식처리 발생 hull 폐기물의 처리(II)

  • Kim, Jun-Hyeong;Kim, In-Tae
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2009.11a
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    • pp.177-177
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    • 2009
  • 사용후 핵연료의 건식처리 시 핵연료 다발을 절단하여 voloxidation 즉 휘발산화처리를 하면 고온에 의해 분리가 가능한 핵분열생성물의 분리와 우라늄의 산화에 의한 부피팽창으로 핵연료가 쪼개져서 입도가 작아지고 또한 핵연료가 피복재에서 쉽게 박리되게 된다. 그 결과 폐기물 처리 시에 발열핵종으로 폐기물의 저준위화시에 분리가 요망되는 Cs-137이 분리되는 장점이 있어 습식 재처리에 있어서도 바람직하다. 건식처리에 있어서는 voloxidation 으로 처리된 피복재에는 금속 지르코늄에 불순물로 함유된 우라늄의 의한 방사화 생성물과 피복재 표변에 부착/침투한 방사화 생성물이 방사능을 갖게 된다. 이러한 부착된 TRU 잔류물은 통상 1% 미만으로 알파핵종의 방사능이 원자로에서 배출시에는 고준위 기준치의 약 100배 수준이었다가 30년 냉각후에는 약 1/10 수준으로 저준위화 된다. 지르코늄 금속중에 불순물로 함유된 우라늄의 방사화로 생기는 방사능은 고준위 기준치의 10% 를 넘지 않아서 피복재의 저준위화시에 고려할 필요가 없다. 발생열은 방출시에 고준위 기준치의 약 30 배 수준에서 5년 냉각후에는 기준치 미만이 되며 30년후에는 1/8000 정도로 저준위화 된다. 사용후 핵연료를 습시처리시에 발생하는 고준위 폐기물 중 약 1/4 가 피복재 (hull) 임을 고려하면 피복재의 저준위화는 사용후 연료의 건식처리에 있어서도 필수적인 과정이다. 특히 미국의 고준위 폐기물 처분장 Yucca Mt.의 포기와 우리의 고준위 폐기불 처분장이 공론화되는 싯점에서 저준위화는 매우 필요한 기술이다. 피복재는 방사성 물질의 침투두께가 0.01mm 미만이 대부분으로 저준위화에는 표면제염에 의한 저준위화가 주로 연구되어왔다. 표면제염에 의한 저준화는 이온 빔, laser에 의한 방법, dry ice 분사에 의한 방법이 시도되었다. 염소기체를 이용하여 지르코늄의 산화막을 제거하고자 하였으나 이 산화막이 안정적이어서 표변의 연마, 아크릴 칼의 사용, 표면을 눌러서 처리하는 등 전처리하여서 염소기체 반응에 의한 표면제거 실험이 가장 효과적임이 실험적 결과이었다. 이러한 전처리로 방사능을 1/100 수준으로 낮춘다고 하더라도 지르코늄 금속중에 불순물로 함유된 우라늄의 방사화에 의해 중저준위 폐기물의 범주에서 벗어나지 않으므로 재활용에는 제한이 있다. 또한 전처리(표면제염)하여 분리되는 고준위는 다른 고준위 염폐기물과 함께 처리하여 발열 핵종을 제거하면 중저준위화가 가능하다. 저준위화 된 hull폐기물에는 지르코늄 금속에 불순물로서 함유되어있는 우라늄에 의한 방사능을 갖는데 이들의 제거나 분리는 지르코늄 합금 피복재 원료물질에 불순물로 함유하는 우라늄의 함량을 낮추는 것과 유사한 문제이다. 현재까지 지르코늄합금 피복재에 우라늄이 불순물로 함유된 것을 사용함으로 원자로내에서 방사화되어서 방사능을 갖게 되는 것은 피할 수가 없다. 따라서 저준위화 처리된 피복재는 장기 보관으로 방사능을 감쇠시켜서 재활용하도록 한다. 처리 방법으로는 초고압 압축저장, 시멘트 고화, 합성암석에 의한 고화법 등으로 장기간 보관 후에 금속으로서 재활용한다.

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Properties of Chorismate Mutase from intrasporangium sp. (Intrasporangium속 방선균의 Chorismate Mutase 성질)

  • 조원대;신광순;최용진;양한철
    • Microbiology and Biotechnology Letters
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    • v.16 no.4
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    • pp.310-315
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    • 1988
  • Two isoenzymes of chorismate mutase(E.C.5.4.99.5) designated as chorismate mutase I(CM I) and chorismate mutase II(CM II), were detected and partially purified from a sp. of intrasporangium isolated from soil. CM I and CM II had pH optima of pH 6.5 and 8.0, respectively and showed the same temperature optimum of 45$^{\circ}C$. The activation energy of the enzymatic reaction was estimated to be 14.7kcal/ mole with CM I and 10.8kcal/mole with CM II. The affinity of isoenzyme CM I for substrate(Km= 1.35mM) was almost the same level as that of CM II(Km = 1.22mM). Both isoenzymes were stable at pH values ranged from pH 6.5 to 9.0, but rapidly denaturated at temperatures above 45$^{\circ}C$. CM II was activated about 7$^{\circ}C$ of its activity by $Ba^{++}$ or $Mg^{++}$ while CM I was slightly inhibited by the same metal ions. Thiol compounds were found not to be necessary for stability of the two enzymes but Co$^{++}$ and EDTA had a little stabilizing effect on CM II only. p-Chloromercuribenzoate strongly inactivated the activities of both enzymes but the reducing agents such as dithiothreitol and L-cysteine protected them against the pCMB inhibition.

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Effects of F-treatment on the Degradation of $Mg_2$Ni type Hydrogen Storage Alloy Electrode ($Mg_2$Ni계 수소저장합금전극의 퇴화거동에 미치는 불화 처리 영향)

  • Kim, Jun-Seong;Choe, Jae-Ung;Lee, Chang-Rae;Gang, Seong-Gun
    • Korean Journal of Materials Research
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    • v.11 no.4
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    • pp.294-299
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    • 2001
  • Effects of the surface fluorination on the electrochemical charge-discharge properties of $Mg_2$Ni electrode in Ni-MH batteries fabricated by mechanical alloying were investigated. After 20h ball milling, Mg and Ni powder formed nanocrystalline $Mg_2$Ni. Discharge capacity of this alloy increased greatly at first one cycle, but due to the formation of Mg(OH)$_2$ passive layer, it showed a rapid degradation in alkaline solution within 10cyc1es. In case of 6N KOH +xN KF electrolyte (x = 0.5, 1, 2), a continuous and stable fluorinated layer formed by adding excess F$^{[-10]}$ ion, increased durability of $Mg_2$Ni electrode greatly and high rate discharge capability(90-100mAh/g). 2N KF addition led to the highest durability of all tested here. The reason of the improvement is due to thin MgF$_2$, which can prevent the $Mg_2$Ni electrode from forming Mg(OH)$_2$layer that is the main cause of degradation.

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Modified Atmosphere Packaging of Fresh Strawberries by Antimicrobial Plastic Films (항균성 플라스틱 필름을 이용한 딸기의 환경기체조절포장)

  • Chung, Sun-Kyung;Cho, Sung-Hwan;Lee, Dong-Sun
    • Korean Journal of Food Science and Technology
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    • v.30 no.5
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    • pp.1140-1145
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    • 1998
  • Low density polyethylene (LDPE) films incorporated with 1% antimicrobial agents of Rheum palmatum extract, Coptis chinensis extract, and Ag-substituted inorganic zirconium matrix, were applied to modified atmosphere packaging of 200 g fresh strawberries. Plain LDPE film package, PVC wrap and perforative pinhole package of the film impregnated with 1% Rheum palmatum extract were also constructed for comparative purpose. All the packages were stored for 13 days at $5^{\circ}C$ and measured in package atmosphere, microbial count and quality attributes of the strawberry fruits. The antimicrobial LDPE films retarded the growth in total aerobic bacteria, lactic acid bacteria and yeast on the fruits, and resulted in significantly lower decay. The degrees of reduced microbial growth and fruit decay in the antimicrobial film packages were more pronounced, when applied by hermetical sealing to produce the modified atmospheres of low $O_2$ (<4.0%) and $CO_2$ concentrations with $6.3{\sim}9.0%$. The hermetically sealed packages of antimicrobial LDPE films also showed better retention of fruit firmness and did not give any negative effect on the physical and chemical qualities of strawberries.

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Membrane-based Direct Air Capture Technologies (분리막을 이용한 공기 중 이산화탄소 제거 기술)

  • Yoo, Seung Yeon;Park, Ho Bum
    • Membrane Journal
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    • v.30 no.3
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    • pp.173-180
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    • 2020
  • As the demand for fossil fuels continues to increase worldwide, carbon dioxide (CO2) concentration in the air has increased over the centuries. The way to reduce CO2 emissions to the atmosphere, carbon capture and sequestration (CCS) technology have been developed that can be applied to power plants and factories, which are primary emission sources. According to the climate change mitigation policy, direct air capture (DAC) in air, referred to as "negative emission" technology, has a low CO2 concentration of 0.04%, so it is focused on adsorbent research, unlike conventional CCS technology. In the DAC field, chemical adsorbents using CO2 absorption, solid absorbents, amine-functionalized materials, and ion exchange resins have been studied. Since the absorbent-based technology requires a high-temperature heat treatment process according to the absorbent regeneration, the membrane-based CO2 capture system has a great potential Membrane-based system is also expected for indoor CO2 ventilation systems and immediate CO2 supply to smart farming systems. CO2 capture efficiency should be improved through efficient process design and material performance improvement.

Production of Sedum Extract Adding Jelly and Assessment of Its Physicochemical Properties (돌나물 즙을 첨가한 젤라틴 젤리의 제조 및 품질특성)

  • Mo, Eun-Kyoung;Kim, Hyun-Ho;Kim, Seung-Mi;Jo, Hyun-Ho;Sung, Chang-Keun
    • Korean Journal of Food Science and Technology
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    • v.39 no.6
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    • pp.619-624
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    • 2007
  • Sedum sarmentosum, also blown as stonecrop (dolnamul), is a widely consumed herb, and is used as an ingredient in salads in Korea. Unfortunately, sedum is perishable and vulnerable to tissue damage during preservation. Therefore, this feasibility study was performed in order to increase the availability of sedum and increase its value. Various concentrations of sedum extract (0.5-3%) were added to gelatin jelly, and their physicochemical properties were determined. The ascorbic acid content of the sedum jelly increased in proportion to the sedum extract concentration. Calcium content of the sedum jelly was 4 to 28 times higher than that of the control. Contrary to the control, iron was detected in the sedum jelly (0.023-1.031 mg/100 g dry weight). Furthermore, magnesium and potassium levels were higher in the sedum extract groups. There were significant differences (p < 0.05) in greenness (a value) and yellowness (b value) between the control and the sedum extract groups. However, significant differences between the 2% and 3% sedum extract groups were not detected. As sedum extract concentration increased, the pH level of soft jellies (solid state) decreased. Therefore, hardness and gumminess were decreased significantly. These results are in agreement with the sensory evaluation. According to sensory tests, the values for palatability, appearance, and color in the 2% sedum extract group were higher than those of the 0.5-1% and 3% sedum extract groups.

Factors Affecting Color Loss in Plum Nectar (자두 Nectar의 퇴색(褪色)에 미치는 영향인자(影響因子))

  • Cho, Sung-Hwan;Kim, Myung-Chan;Lee, Man-Woong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.14 no.2
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    • pp.117-122
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    • 1985
  • The effects of various factors on the color stability of plum nectar were studied. The data showed that pH and temperature were the most important factors affecting the rate of color loss. The concentration of ascorbic acid affected the rate of color loss in plum nectar. Although the color loss could be influenced by the presence of sugars and their degradation products such as 5-hydroxymethyl-2-furfural(HMF), HMF did not accumulate in sufficient amounts during the storage in the plum nectar to affect appreciably the degradation rate. The pigment was very unstable in the fermented juice and its. spectrophotometric spectrum was changed differently from that of natural plum color material. Materials present in plum nectar itself apparently have an appreciable effect on the rate of color loss.

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Geochemical Characteristics of Stream Sediments and Waters around the Pungam Landfill in Gwangju City, Korea (광주광역시 풍암매립지 주변 하상퇴적물과 물의 지구화학적 특성)

  • Park, Cheon-Young;Shim, In-Hyun;Bae, Jong-Phill;Ahn, Kun-Sang
    • Journal of the Korean earth science society
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    • v.24 no.4
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    • pp.290-302
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    • 2003
  • This study was carried out to evaluate geochemical properties for stream sediments, surrounding soils, sludge collected in the drainage pipe of leachate and waters (stream water, groundwater, leachate) around the Pungam Landfill in Gwangju city. The stream sediments don't show any systematic trend of contents from upstream to downstream. The most enriched major element in the stream sediments is Fe (up to 7.08wt.% in GJ-23). Though stream sediment GJ-23 and GJ-34 were enriched by some heavy metals (eg. As, Cu, Zn), they do not constitute serious problems for environment consideration. The concentration of Fe (35.lwt.%) and As (38ppm) are significantly high in the GJ-8, which is soil specimen adjacent to leachate reservoir. The sludge (GJ-7) shows very high concentrations of As, Mn, Cr, Pb. In particular, the Cr content is 45.6 ppm, which exceeds the permitted level. The leachate is characterized by high TDS (2210-2470mg/L) and high electric conductivity (468, 530ms/cm), and enriched in both cation (Na, K) and anion (HCO$_3$). The leachate(PK-3) had a relatively high concentration of Cl, and is plotted in Na-Cl type on the Piper's diagram. The NO$_3$-N of the groundwater and stream water exceeded the permitted levels for drinking water.

Soft-template Synthesis of Magnetically Separable Mesoporous Carbon (자성에 의해 분리 가능한 메조포러스 카본의 소프트 주형 합성)

  • Park, Sung Soo;Ha, Chang-Sik
    • Journal of Adhesion and Interface
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    • v.18 no.2
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    • pp.75-81
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    • 2017
  • In this study, we synthesized mesoporous carbon (Carbonized Ni-FDU-15) containing nanoporous structures and magnetic nanoparticles. Carbonized Ni-FDU-15 was synthesized via evaporation-induced self-assembly (EISA) and direct carbonization by using a triblock copolymer (F127) as a structure-directing agent, a resol precursor as a carbon-pore wall forming material, and nickel (II) nitrate as a metal ion source. The mesoporous carbon has a well-ordered two-dimensional hexagonal structure. Meanwhile, nickel (Ni) metal and nickel oxide (NiO) were produced in the magnetic nanoparticles in the pore wall. The size of the nanoparticles was about 37 nm. The surface area, pore size and pore volume of Carbonized Ni-FDU-15 were $558m^2g^{-1}$, $22.5{\AA}$ and $0.5cm^3g^{-1}$, respectively. Carbonized Ni-FDU-15 was found to move in the direction of magnetic force when magnetic force was externally applied. The magnetic nanoparticle-bearing mesoporous carbons are expected to have high applicability in a wide variety of applications such as adsorption/separation, magnetic storage media, ferrofluid, magnetic resonance imaging (MRI) and drug targeting, etc.