• Title/Summary/Keyword: 이온그룹

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Quantitative Determination of ABS from Mixture of Anionic and Nonionic Detergents by NMR (NMR을 이용한 음이온 및 비이온세제의 혼합물로부터 ABS의 정량)

  • Koang-Hoon Choe;Sun-Ja Kwon
    • Journal of the Korean Chemical Society
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    • v.27 no.6
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    • pp.419-423
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    • 1983
  • Amounts of alkylbenzene sulfonate (ABS) in the mixtures of anionic and nonionic detergents were determined by nuclear magnetic resonance (NMR) method. In the NMR spectrum of anionic and nonionic detergents, benzene group showed peaks overlapping at 6.5∼8ppm, but after sampling, benzene group showed two doublet at 7∼8ppm. Calibration curve was obtained by relative ratio of area for benzene group in anionic detergent to that for methyl group in acetic acid(acetic acid was used as the internal standard).

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The Developing Process and Transformation of Gloval Retailers - The Case of AEON Group -

  • Bamba, Kaori
    • Korean Business Review
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    • v.21 no.1
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    • pp.119-131
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    • 2008
  • The purpose of this study is to investigate AEON Group which is the largest retailers in Japan. There are same characteristic between E-mart and Aeon. They adopted hyper method as like as European and American. In addition to this, they applied their own custom. As I reviewed about the stages of development corporate, it is enabled to be expected the strategy of Aeon. The corporate will be a holding company and planning to expand branch to hundred in China.

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Changes in Early Stage Vegetation Succession as Affected by Desalinization Process in Dae-Ho Reclaimed Land (대호 간척지의 제염진해에 따른 초기 식생 변화)

  • Lee, Seung-Heon;An, Yeoul;Yoo, Sun-Ho;Lee, Sang-Mo
    • Korean Journal of Environmental Agriculture
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    • v.19 no.4
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    • pp.364-369
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    • 2000
  • In order to obtain the reference data to be used as an vegetation index for degree of desalinization, vegetation successions were surveyed and soil chemical characteristics were analyzed at the naturally maintained plot in Dae-Ho reclaimed land. Seven Groups $(A\;{\sim}\;G\;group)$ were classified as major vegetation; A group (Suaeda asparagoides MAKINO etc.), B group ( Aster tripolium L. etc.), C group (Stearia viridis L. BEAUV), D group ( Phragmites longivalvis STEUD), E group (Limonium tettagonum THUMB A. A. BULLOCK), F group (Trifolium repens L.), G group (Zoysia sinca HANCE etc.). As desalinization process proceeded, the wild vegetation changed in order of $A\;{\to}\;B\;group$, $D\;{\to}\;C\;group$, $E\;{\to}\;F$, G group. Soil texture of the naturally maintained plot was silt loam and soil fertility was very low compared with agricultural cultivated soil. Soil pH ranged from 7.0 to 8.0. Electrical conductivity (ECe) was below 10 and $20\;dS{\cdot}m^{-1}$ at top and subsoil, respectively, except the plot where A group were growing. Resulting from SAR and ECe, The plot where A group was growing was saline-sodic soil and the others were saline soil. The relation between vegetation sucession and soil desalinization showed that vegation appeared under $10\;dS{\cdot}m^{-1}$ of ECe and 15 of SAR except A group.

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Spectrophotometric analysis of feldspathic porcelain with silver ion (은이온을 첨가한 장석계 도재의 분광 측색학적 평가)

  • Kim, Jihyun;Song, Kyeongwoo;Noh, Sera;Yun, Kyelim;Yun, Kwidug
    • Journal of Dental Rehabilitation and Applied Science
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    • v.31 no.1
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    • pp.20-25
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    • 2015
  • Purpose: This study was evaluated the shade of feldspathic porcelain with various concentration of silver ion. Materials and Methods: The control group was conventional feldspathic porcelain with no silver ion, the experimental groups were the feldpathic porcelain with 5%, 10%, 20%, 30% silver ion. The number of specimens on the each group was 5. Commission Internationale de I'Eclairage (CIE) $L^*a^*b^*$ parameters were recorded twice for each specimen with a spectrophotometer (Model CM-2600d, Minolta, Japan). One-way Anova was used for statistical analysis. Results: L value was similar. a value was increasing and b value was decreasing with silver ion statistically significantly. ${\Delta}E$ was increasing according to silver ion significantly. Conclusion: The shade of feldspahtic porcelain was influenced by silver ion. Ag ion under 10% concentration is acceptable clinically.

이온보조 반응법을 이용한 Polystyrene(PS)의 친수성 변화에 관한 연구

  • Yoo, Dae-Hwan;Choi, Sung-Chang;Ko, Seok-Geun;Shin, Gu
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.215-215
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    • 1999
  • 상용의 PS가 가지는 소수 특성을 아르곤, 수소, 산소 이온을 이온 보조 반응법을 이용하여 PS의 표면에 조사하여 PS의 표면을 친수성을 증대시켰으며 이때의 친수성의 변화는 각 이온의 비율과 전류의 세기 및 전압의 변화에 따라 측정하였다. 이온 소스는 직경 5cm의 cold hollow cathod ion gun을 이용하였으며 이온 조사량은 5$\times$1014 ~ 1$\times$1017까지 변화시키고 산소의 유량은 0~6sccm까지 변화시키고 수소의 유량 또한 0~6sccm 까지 변화시키면서 극성 용매인 물과의 접촉각을 정적 접촉각 측정기를 이용하여 측정하였다. 또한 일정 조건에서 이온의 조사 후 대기와 물속에서 시간에 따른 물의 접촉각의 변화를 측정하였다. 표면에 형성된 극성 그룹을 조사하기 위하여 XPS를 측정하였다. XPS 측정결과 표면에 C-O, C=O, (C=O)-O와 같은 극성 작용기가 형성되었음을 확인하였으나 PS 표면에 생성된 정확한 작용기를 구분하기 어려웠다. 따라서 좀더 세밀한 조사를 위하여 FT-IR을 이용하여 이온 조사 조건에 따른 PS 표면의 분자단의 Peak 변화를 관찰하였다.

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Preparation and Characterization of Proton Conducting Crosslinked P(VDF-co-CTFE)-MAA/SEMA membranes (수소이온 전도성 가교된 P(VDF-co-CTFE)-MAA/SEMA 막 제조 및 분석)

  • Patel, Rajkumar;Lei, Zeng Xiao;Heo, Sung Yeon;Kim, Jong Hak
    • Membrane Journal
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    • v.23 no.4
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    • pp.290-296
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    • 2013
  • Poly(vinylidenefluoride-co-chlorotrifluoroethylene) P(VDF-co-CTFE) polymer was attached to methacrylic acid (MAA) in the presence of 1,8-diazabicyclo[5,4,0]undec-7-ene(DBU) catalyst to prepare P(VDF-co-CTFE)-MAA copolymer. The modified P(VDF-co-CTFE)-MAA was polymerized with 2-sulfoethyl methacrylate (SEMA) monomer in the presence of 4',4'-azobis(4-cyanovaleric acid(ACVA) initiator by free radical polymerization to form the proton conducting membrane. The ratio of the SEMA was increased in the membrane to increase the presence of the acidic group. The maximum IEC value that was observed at 50% SEMA was around 0.82 meq/g, which is consistent with the water uptake value. The highest proton conductivity achieved by P(VDF-co-CTFE)-MAA/SEMA membrane with 50% SEMA was approximately 0.041 S/cm. This indicates that the available ionic group for the proton conduction increases with the increase in the SEMA in the membrane.

Study on Electrochemical Performances of PEO-based Composite Electrolyte by Contents of Oxide Solid Electrolyte (산화물계 고체전해질 함량에 따른 PEO 기반 복합전해질 전기화학 성능 연구)

  • Lee, Myeong Ju;Kim, Ju Young;Oh, Jimin;Kim, Ju Mi;Kim, Kwang Man;Lee, Young-Gi;Shin, Dong Ok
    • Journal of the Korean Electrochemical Society
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    • v.21 no.4
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    • pp.80-87
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    • 2018
  • Safety issues in Li-ion battery system have been prime concerns, as demands for power supply device applicable to wearable device, electrical vehicles and energy storage system have increased. To solve safety problems, promising strategy is to replace organic liquid electrolyte with non-flammable solid electrolyte, leading to the development of all-solid-state battery. However, relative low conductivity and high resistance from rigid solid-solid interface hinder a wide application of solid electrolyte. Composite electrolytes composed of organic and inorganic parts could be alternative solution, which in turn bring about the increase of conductivity and conformal contact at physically rough interfaces. In our study, composite electrolytes were prepared by combining poly(ethylene oxide)(PEO) and $Li_7La_3Zr_2O_{12}$ (LLZO). The crystallinity, morphology and electrochemical performances were investigated with the control of LLZO contents from 0 wt% to 50 wt%. From the results, it is concluded that optimum content and uniform dispersion of LLZO in polymer matrix are significant to improve overall conductivity of composite electrolyte.

Effects of Immobilized Bipolar Interface Formed by Multivalent and Large Molecular Ions on Electrodialytic Water Splitting at Cation-Exchange Membrane Surface (양이온교환막 표면의 전기투석 물분해에서 다가의 큰 이온성분자에 의해 형성된 고정층 바이폴라 계면의 영향)

  • Seung-Hyeon Moon;Moon-Sung Kang;Yong-Jin Choi
    • Membrane Journal
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    • v.13 no.3
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    • pp.143-153
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    • 2003
  • The effects of bipolar interface formed on the surface of cation-exchange membrane on water splitting phenomena were investigated. Results showed that the formation of immobilized bipolar interface resulted in significant water splitting during electrodialysis. In particular, the immobilized bipolar interface was easily created on the cation-exchange membrane surface in the electrodialytic systems where multivalent cations served as an electrolyte. Multivalent cations with low solubility product resulted in violent water splitting because they were easily precipitated on the membrane surface in hydroxide form. Therefore, the bipolar interface consisting of H- and OH-affinity groups were formed on the membrane-solution interface. Apparently, water splitting was largely activated with the help of strong electric fields generated between the metal hydroxide layer and fixed charge groups on the membrane surface. Likewise, the accumulation of large molecular counter ions on the membrane surface led to the formation of a fixed bipolar structure that could cause significant water splitting in the over-limiting current region. Therefore, the prevention of the immobilization of bipolar interface on the membrane surface is very essential in improving the process efficiency in a high-current operation.

Improvement of the Adhesion Properties between Aluminum and a Parylene-C Film by Using the Duoplasmatron Ion Source (Duoplasmatron Ion Source를 이용한 Parylene과 Al의 접착력 향상에 관한 연구)

  • Choi, Sung-Chang
    • Journal of the Korean Vacuum Society
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    • v.21 no.2
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    • pp.78-85
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    • 2012
  • In order to improve the adhesion between poly-monochloro-para-xylylene (Parylene-C) film and Aluminum thin film, the surface of Parylene-C film was irradiated by ${O_2}^+$ and $Ar^+$ ion beam generated by duoplamatron ion source. The ion dose of $Ar^+$ and ${O_2}^+$ was changed from $5{\times}10^{14}$ to $1{\times}10^{17}/cm^2$ and the ion beam energy was 1 kV. Contact angles of water on Parylene-C modified by $Ar^+$ and ${O_2}^+$ ion irradiation decreased from $78^{\circ}$ to around $17^{\circ}$, and $9^{\circ}$, respectively. X-ray photoelectron spectroscopy analysis shows that the hydrophilic groups were formed on the surface of Parylene-C by chemical reaction between the unstable chains induced by the ion irradiation and oxygen ions or residual oxygen gas. The hydrophilic groups were identified as C-O bond, C=O bond and (C=O)-O bond. The cross cut tape test which was applied to characterize the adhesion between Al thin film and Parylene-C film modified by ${O_2}^+$ ions irradiation shows that the adhesion strength was improved as increasing ion dose.

포천지역 하천과 지하수의 환경동위원소 및 수리지구화학 연구: 질소계 오염물질의 기원과 거동에 관한 예비 해석 결과

  • Chae Su-Ho;Yun Seong-Taek;Kim Gyeong-Ho;Jeon Jong-Uk;Gwon Hae-U
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.336-339
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    • 2005
  • 포천지역의 포천천과 그 주변의 8개 소유역을 대상으로 2003년 8월부터 2004년 8월까지 하천 8개 지점과 기존 지하수 관정 66개소를 선정하여 수리지구화학 및 환경동위원소 연구를 실시하였다. 복합적인 토지이용과 관련하여 연구지역 수계에서는 오염물질 유입이 광역적으로 인지되었으며, 일부 지역에서는 지하수계로의 오염물질 유입이 강하게 나타나 인근 하천까지 영향을 줌이 확인되었다. 오염기원으로 해석되는 대표적인 무기이온종인 $NO_3,\;Cl,\;SO_4$의 존재비를 이용하여 연구 지역의 지표수와 충적 지하수를 크게 3개 수질 그룹으로 분류하였다. 이들 그룹들은 각각 특징적인 충진 특성과 용존 이온의 분포/거동 양상을 나타내는 것으로 해석된다. 본 논문에서는 세 유형의 지표수/충적 지하수 외에 암반 지하수를 포함하여 연구지역 자연수의 수리지구화학 진화 경로와 오염물질의 유입 및 거동 양상에 대하여 토의한다.

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