• Title/Summary/Keyword: 이온권

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Functional UF HDPE Hollow Fiber Membrane

  • Ma, Seok-Il;Kwon, Soon-Heung;Sun, Hyang
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.461-464
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    • 1998
  • 막의 면적에 비례되는 막분리 공정의 생산성은 넓은 표면적을 갖는 중공사막의 이용으로 가능해지므로 중공사막에 관한 연구가 활발하게 진행되어 해수의 담수화, 가정용수의 정화 등은 이미 실용화되었다. 해수의 담수화에 이용되는 역삼투(RO)막은 고압 하에서 무기이온의 제거, 가정용수의 정화에 이용되는 UF막은 저압 하에서 분자량이 비교적 큰 이물질의 분리에 사용되는 점이 다르다. 최근에는 해수에서 우라늄을 회수하기 위한 연구를 진행되고 있다. (중략)

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유한요소법을 이용한 단발 방전의 시뮬레이션

  • 김동길;민병권;이상조
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.05a
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    • pp.253-253
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    • 2004
  • 방전가공은 현재의 정밀 금형산업에서는 필수적인 가공방법이나, 공작물과 전극사이에서 방전이 발생할 때 고온고압의 플라즈마 상태에서 재료를 제거하는 메카니즘에 대한 해석은 아직도 많은 연구 대상이다. 방전가공은 기본적으로 3단계의 과정으로 구별할 수 있는데, 첫째 공작물과 전극의 간격과 기하학적 형상, 전압에 의해서 전계가 집중되어 절연체의 절연강도보다 초과하면 절연체가 이온화되어 방전이 시작된다. 둘째, 전극과 공작물이 통전이 되어 플라즈마 채널이 형성되면서 열에너지에 의하여 공작물이 용융 증발이 발생한다.(중략)

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TiN 및 TiAlN이 코팅된 SKD61강의 내산화성 및 Zn 증기반응성 연구

  • Chae, Ok-Ju;Yang, Hyeon-Sam;Ban, Jae-Sam;Mun, Byeong-Gwon
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.170-170
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    • 2015
  • 아크이온플레이팅(AIP)을 이용하여 SKD61강에 TiN 및 TiAlN을 증착함으로써 내산화성 및 아연증기와의 반응을 억제할 수 있었으며, 도금두께 제어를 위한 에어나이프의 수명개선 및 생산성향상에 매우 중요한 요인으로 판단되었다.

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Stereoselective Electron Transfer Reactions between Optically Active${\Delta}-cis-[Co(en)_2(NO_2)_2]^+$and rac-$[CO(Y)^{2-}$(Y=EDTA. PDTA, CyDTA) (광학활성인${\Delta}-cis-[Co(en)_2(NO_2)_2]^+$과 라세미-$[CO(Y)^{2-}$(Y=EDTA. PDTA, CyDTA)간의 입체선택적 전자전달반응)

  • Lee, Bae Wook;Kim, Dong Yeub;Lee, Dong Jin;Oh, Chang Eun;Doh, Myung Ki
    • Journal of the Korean Chemical Society
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    • v.39 no.4
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    • pp.275-280
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    • 1995
  • The electron transfer reactions between cis-[Co(en)2(NO2)2]+ and rac-[Co(Y)]2-(Y=EDTA, PDTA, CyDTA) have been investigated in the presence of hydrogen ion. From the kinetic data, it has been found that electron transfer reactions between cis-[Co(en)2(NO2)2]+ and rac-[Co(Y)]2- proceed via inner-sphere pathway by catalysis of hydogen ion. The stereoselectivity in the electron transfer reactions between optically active △-cis-[Co(en)2(NO2)2]+ and rac-[Co(Y)]2- produced 6.0, 2.9, 3.0% e.e.(e.e.=enantiomeric excess) of △-[Co(EDTA)]-, △-[Co(PDTA)]- and △-[Co(CyDTA)]-, respectively. Based upon this observation, it seems that △-cis-[Co(en)2(NO2)2]+ is associated with rac-[Co(Y)]2- at first, and followed by the electron transfer reaction. Therefore, it was suggested that stereoselective electron transfer reaction between △-cis-[Co(en)2(NO2)2]+ and rac-[Co(Y)]2- proceed through both inner-sphere by the proton catalysis and outer-sphere with ionic association.

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Antioxidant Enzyme Activities and Soil Properties of Healthy and Declining Abies koreana (Wils.) in Mt. Halla (한라산 구상나무 건전개체와 쇠약개체의 항산화효소활성 및 토양특성)

  • Lim, Jong-Hwan;Woo, Su-Young;Kwon, Mi Jeong;Kim, Young Kul
    • Journal of Korean Society of Forest Science
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    • v.96 no.1
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    • pp.14-20
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    • 2007
  • In order to examine the differences in antioxidant enzyme activities which represent defence mechanism to stressful environments, and soil properties between healthy and declining (or unhealthy) trees, we selected three sites, Witseorum, Youngsil and Sungpanak (Jindallebat). Antioxidant enzymes including Ascorbate peroxidase (APX) and Glutathione Reductase (GR), forest soil properties including soil texture, soil pH, organic matter, total nitrogen, available phosphate, cation exchange capacity, exchangeable cation content and nutrient contents in leaves of Abies koreana (Korean fir) trees were analyzed. There were no significant differences between healthy and declining trees in GR activity. However, seasonal difference in antioxidant enzyme activity was observed. GR activity was lower in June and August than that of September. Soil chemical and physical properties of each site showed a tendency that organic content, total nitrogen content, available phosphorus, cation exchange capacity and cation content were lower at the site of declining trees than the site of healthy trees.

Effect of Ruthenium Red and Ryanodine on Calcium Ion Metabolism in Oocyte and Early Embryo of Mouse (생쥐의 난자와 초기배아의 칼슘이온 대사에 미치는 Ruthenium Red와 Ryanodine의 영향)

  • Lee Joon Yeong;Hong Soon Cap;Kim Tae Sik;Min Byeong Yeol;Kim Haekwon;Yoon Yong-Dal
    • Development and Reproduction
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    • v.7 no.2
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    • pp.95-103
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    • 2003
  • Intracellular calcium is an important physiological factor in most cells, and ruthenium red and ryanodine play an important role as calcium modulators. Ruthenium red inhibits calcium-induced calcium release(CICR) from the intracellular calcium store. Ryanodine activates calcium release through ryanodine channel. The present experiment was performed to investigate the effects of two modulators on calcium ion metabolism and to determine their dose-dependency in oocyte and early embryo of mouse. Intracellular calcium ion concentration was measured in realtime by using confocal laser scanning microscope(CLSM) after loading of Fluo-3/AM in mouse oocytes and early embryos. Ruthenium red decreased intracellular calcium ion concentration in oocytes and early embryos at its high concentration(30, 300 $\mu$M). Ryanodine increased intracellular calcium ion concentration in oocytes and early embryos in low concentration(0.01 $\mu$M) but decreased that at higher concentrations(1, 10 $\mu$M). These results indicate that two modulators affected calcium ion metabolism in oocyte and early embryo of mouse, and their dose-dependency was different from somatic cell including myocytes.

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A Study on the Luminescence Properties of Eu3+ Ions Doped Vanadate (Eu3+ 이온이 첨가된 바나듐산염의 형광특성 연구)

  • Kang, Yeonhee;Yoon, Changyong
    • Journal of the Korean Society of Radiology
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    • v.13 no.3
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    • pp.445-451
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    • 2019
  • The fluorescence intensity and fluorescence lifetime of $Ba_2GdV_3O_{11}$, a vanadate compound based on $Ba^{2+}$ ion, were investigated by adding $Eu^{3+}$ as a rare earth ion which is an alkaline earth metal, which is distributed around active ions and has a large influence on fluorescent properties when used as a host in a phosphor. $Ba_2GdV_3O_{11}:Eu^{3+}$ phosphor was synthesized by solid state method and the crystallinity of the phosphor was confirmed by X - ray diffraction analysis. The fluorescence properties of the $Ba_2GdV_3O_{11}:Eu^{3+}$ phosphor were measured using optical and laser. The energy transfer and diffusion of the $Ba_2GdV_3O_{11}:Eu^{3+}$ phosphor are highly dependent on the concentration of $Eu^{3+}$. When the concentration of $Eu^{3+}$ is low, it shows strong fluorescence to the CT band. However, as the concentration of $Eu^{3+}$ increases, the fluorescence due to 4f - 4f transition is strong. The concentration of $Eu^{3+}$ ion increased and the energy between ions was diffused, and the lifetime of fluorescence decreased. Energy transfer occurs between two $Eu^{3+}$ ions at low $Eu^{3+}$ concentration and energy diffusion occurs at high $Eu^{3+}$ concentration.

Luminescence Properties of Europium-doped NaSr(PO3)3 Phosphor (Europium이 첨가된 NaSr(PO3)3형광체의 형광특성)

  • Yoon, Changyong;Park, Cheolwoo
    • Journal of the Korean Society of Radiology
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    • v.13 no.4
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    • pp.645-652
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    • 2019
  • Phosphor with phosphorus doped with rare earth ions was investigated by searching Sr and Eu phosphors suitable for substitution of Eu ions with similar ionic radius to polyphosphate host. The $NaSr(PO_3)_3$ phosphor was synthesized by the solid state method and the $NaSr(PO_3)_3:Eu^{2+}$ phosphor was prepared by the carbon thermal reduction method. Both of the phosphors were identified by X - ray diffraction. The excitation and emission spectra of $NaSr(PO_3)_3:Eu^{3+}$ increased fluorescence intensity and intensity quenching with increasing $Eu^{3+}$ concentration. The higher the $Eu^{3+}$ concentration in the emission spectrum, the higher the local symmetry of $Eu^{3+}$ environment. The mechanism of concentration quenching, in which fluorescence decreases due to the energy transfer between $Eu^{2+}$ ions with the closest critical distance between $Eu^{2+}$ ions with increasing $Eu^{2+}$ ion concentration, was confirmed in the emission spectrum of $NaSr(PO_3)_3:Eu^{2+}$ concentration. It is possible to change the fluorescent region through the post-processing of single rare earth ion added phosphors, and it is possible to change the fluorescence by applying the energy transfer and concentration quenching mechanism according to the local symmetry of $Eu^{3+}$ will be used for high phosphor development.

Trace impurities analysis of the electronic polymer resins by neutron activation analysis (중성자방사화분석법에 의한 전자소재용 고분자수지의 불순물 분석법연구)

  • Yoon, Yoon Yeol;Cho, Soo Young;Lee, Kil Yong;Yang, Myung Kwon;Shim, Sang Kwon;Chung, Yong Sam
    • Analytical Science and Technology
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    • v.17 no.4
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    • pp.308-314
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    • 2004
  • When the polymer was used for the guard raw materials of electronic device, the content of U, Th and their daughter nuclides were known as a factor of soft error. Because emitted alpha ray could be caused of mis-operation. And ionic impurities such as Cl, Fe, Na could shorten the device life-time. For the analysis of trace impurities in the polymer, neutron activation analysis(NAA) and ICP/AES have been studied. To improve the accuracy and sensitivity of the trace and ultratrace metallic impurities in the epoxy and phenol polymer, sample pretreatment method and optimum analytical condition of NAA were developed. Using the above method, U, Th and other 23 trace impurity elements were analyzed.