• Korean Chemical Engineering Research
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• v.46 no.4
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• pp.692-696
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• 2008

There is not much method of using C4 Raffinate III, despite having high olefin contents. The majority of the C4 Raffinate III have been converted into n-butane through hydrogenation, and sold as LPG. The C4 Raffinate III is rich 2-butenes with very low isobutene and isobutene contents. The 2-butenes are converted into 1-butene in the vicinity of thermodynamic equilibrium yield through positional isomerization with n-almumina catalyst calcinated at $400{\sim}600^{\circ}C$. The overall process is composed of isomerization-reactor, de-1-buteneizer to prepare the reactants and to enrich reactive products, and 1-butene column to product a high purity 1-butene. The production of 1-butene increases by 40~60 wt% with the selective positional isomerization from the existing separation method.

• Journal of the Korean Chemical Society
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• v.37 no.3
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• pp.317-326
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• 1993

The acid catalytic reactions of toluene with n-propylalcohol were investigated and the adsorption experiments of dialkylbenzene isomers were carried out at 100$^{\circ}C$ over modified HZSM-5 zeolites. ZSM-5 zeolite was synthesized by the hydrothermal reaction using 4-propylammonium ion, sodium aluminate and colloidal silica etc., and several zeolite catalysts, including H-, K-, Sr-, P-Mg-HZSM-5, H-Y and H-mordenite, were prepared by conventional methods. The main reaction products of toluene with n-propylalcohol over HZSM-5 catalyst include not only xylenes, propyltoluenes, but also ethyltoluenes and high para-selectivity among dialkylbenzene isomers was observed on P-Mg-HZSM-5 zeolite. The diffusion coefficients of various p-dialkylbenzenes are nearly the same, about 1 ${times}$ 10$^{-10}$ cm$^2$/sec and that of m-xylene was about one tenth of o-xylene. These reaction and adsorption characteristics were interpreted in the light of the shape-selectivity related to related to the zeolite pore structure and the zeolitic acidity.

• Applied Chemistry for Engineering
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• v.19 no.3
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• pp.287-294
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• 2008

Molecularly imprinted polymer (MIPs) membranes were prepared by UV polymerization to separate racemates with opposite physiological activity, and then its separation selectivity of racemates was carried out. Likewise, their properties were examined. Polycarbonate (PC) membrane was polymerized as small spot form in pore inner wall, but anodisc (AD) membrane was polymerized as film form with thickness 500~700 nm onto the membrane surface. Also the study on the separation selectivity of prepared MIPs membranes was carried out in L-Tryptophane (Trp) racemate solution. The results showed that AD MIPs membrane polymerized as a film form, which was achieved by solution polymerizaion consisting of over 90% cross-linking agent (ethylene glycol dimethacrylate; EGDMA) and under 30% dispersing agent (methanol; MeOH), had predominant 3.5 selectivity.

• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.473-478
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• 2011

The interaction of para-halogenated benzoic acid isomers with the micellar system of tetradecyltrimethylammonium bromide was studied by the UV/Vis spectrophotometric method. The solubilization constants ($K_s$) of benzoic acid isomers into the micellar system of TTAB and the critical micelle concentration (CMC) of TTAB have been measured with the change of temperature. Various thermodynamic parameters have been calculated and analyzed from those measurement. The results show that the values of ${\Delta}G^{\circ}{_s}$ for the solubilization of all isomers are negative and the values of ${\Delta}H^{\circ}{_s}$ and ${\Delta}S^{\circ}{_s}$ are all positive within the measured temperature range. The effects of additives (n-butanol and NaCl) on the solubilization of benzoic acid isomers have been also measured. There was a great decrease on the values of $K_s$ and CMC simultaneously with these additives. From these changes we can postulate that the solubilization sites of each isomers in the TTAB micellar system are the surface or the palisade region of the micelle.

• Analytical Science and Technology
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• v.19 no.4
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• pp.352-364
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• 2006

This study was performed to search for useful separation properties and elution orders of three GC columns (DB-1, DB-5MS, SPB-Octyl) for 209 PCBs congeners using M-1668A-0.01X-SET of the AccuStandard Inc.. In addition, to confirm the quantitative peak in peak pattern method, the IUPAC Nos. of PCBs congener peaks were identified with 4 Aroclor standards (Aroclor-1242, 1248, 1254 and 1260). The separation property of dioxin-like PCBs congeners by four columns (DB-1, DB-5MS, SP-2331 and SPB-Octyl) was excellent in SP-2331. DB-1 and SPB-Octyl columns are necessary to use with a column of other types.

• Journal of the Korean Society for Precision Engineering
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• v.18 no.7
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• pp.72-84
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• 2001

This paper proposes a design methodology for customer, assembly and disassembly considering recycling. The disign process starts with the identification of customer needs, which are in turn converted into functional requirements. The concepts of Design for Customer(DFC), Design for Assembly(DFA), Design for Variety(DFV) and Design for Disassembly(DFD) are considered in the product design phases in order to decreas production variety and mass customization. And, a new module generation approach is developed for rearranging and clustering parts and subassemblies for disassembly and recycling. Based on the result of the module generation, a new configuration methodology is suggested to minimize the disassembly time or number of disassembly operations for recycling.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.12
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• pp.5759-5763
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• 2012

I conducted structural model analysis which is considered the influence of "government policy and micro-enterprise manager's characteristics" on management performance through effective analysis on governmental policy for micro-enterprise funding, training and consulting support. This study results showed characteristics of micro-enterprise manager and government policy significant to management performance. In the structural model, significant independent variables are customer's accessibility, promotion availability, goods mobility, customer attractive ability, effectiveness of funding, size of supported training, and effectiveness of training and satisfaction of supported consulting size.

• The Journal of the Korea Contents Association
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• v.6 no.10
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• pp.80-88
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• 2006

This paper suggests frame of analysis about MMORPG and analyzes three representative games. That frame has seven categories and more divisional analysing items. The 7 categories are community orientation, PK orientation, convenient usability of item, variety of character, balance, convenience of interface, aesthetics of graphic and sound. As a result, We found that Lineage and WOW have many different characters and Ragnarok has the characters in-between Lineage and WOW.

• Journal of the Korean Chemical Society
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• v.25 no.3
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• pp.166-171
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• 1981

The reactions of trimethylbenzenes were investigated over dealuminated, cation-exchanged mordenite catalysts. Higher reaction temperature favored the formation of disproportionation products. In the reaction of 1,2,4-trimethylbenzene, the formation of 1,3,5-trimethylbenzene and the disproportionation products decreased sharply with reaction time. The product distribution, especially the distribution of trimethylbenzenes, suggests that the effective pore diameter of Ba-exchanged dealuminated mordenite catalysts lies somewhere between 8.1 and 8.6${\AA}$.

• LOGISTICS
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• s.16
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• pp.37-39
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• 2006

지난 3월 25일 제5회 한국로지스틱스 대상 수상식에서 건설교통부 물류혁신본부는 국가 물류혁신에 기여한 공을 인정 받아 대상을 수상했다. 건설교통부 물류혁신본부(본부장 이성권)는 지난해 9월 발족 이후 건교부가 주로 담당해온 물류인프라의 확충 등 하드웨어적인 시책뿐 아니라, 물류산업 육성, 물류인력 양성 등 소프트웨어적인 시책을 집중적으로 추진, 국제 · 국내 물류, 민 · 관 · 학 분야를 포괄하는 물류 경쟁력 향상을 위한 종합적 지원업무를 수행하고 있다. 특히 물류혁신본부는 물류기업 경쟁력 향상과 제3자 물류 활성화 대책의 일환으로 종합물류기업인증제를 도입, 본격적인 시행에 들어갔으며 현재 부처별로 분산되어 있는 물류정책을 통합조정하기 위하여 물류정책기본법, 물류시설법 제정을 추진 중에 있다. 물류혁신본부의 수장인 이성권 물류혁신본부장은 지난 4월 7일 대한상공회의소가 주최한 조찬간담회에 연사로 참석하여 '물류 경쟁력 강화를 위한 정부 정책방향'이라는 주제로 발표하였다. 이에 그 내용을 요약 게재한다.