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http://dx.doi.org/10.5806/AST.2006.19.4.352

Separation properties of 209 PCB congeners on capillary columns and identification of PCBs congeners in aroclor standards for source identification  

Kim, Kyoung-Soo (Department of Environmental Engineering, Cheongju University)
Kim, Kyeo-Keun (Department of Environmental Engineering, Cheongju University)
Kim, Jong-Guk (Center for Chemical Safety Management, Chonbuk National University)
Publication Information
Analytical Science and Technology / v.19, no.4, 2006 , pp. 352-364 More about this Journal
Abstract
This study was performed to search for useful separation properties and elution orders of three GC columns (DB-1, DB-5MS, SPB-Octyl) for 209 PCBs congeners using M-1668A-0.01X-SET of the AccuStandard Inc.. In addition, to confirm the quantitative peak in peak pattern method, the IUPAC Nos. of PCBs congener peaks were identified with 4 Aroclor standards (Aroclor-1242, 1248, 1254 and 1260). The separation property of dioxin-like PCBs congeners by four columns (DB-1, DB-5MS, SP-2331 and SPB-Octyl) was excellent in SP-2331. DB-1 and SPB-Octyl columns are necessary to use with a column of other types.
Keywords
PCBs; GC column; separation property; Aroclor;
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