• Title/Summary/Keyword: 이산화탄소 활성화

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Development of Fly Ash/slag Cement Using Alkali-activated Reaction(1) - Compressive strength and acid corrosion resistance - (알칼리 활성반응을 이용한 플라이 애쉬/슬래그 시멘트 개발(1) - 압축강도 및 산 저항성 -)

  • Park, Sang-Sook;Kang, Hwa-Young;Han, Kwan-Su
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.7
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    • pp.801-809
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    • 2007
  • Fly ash and blast furnace slag are an industrial by-product that can be alkali-activated to yield adhesive and cementitious materials, whose production is less energy-intensive and emits less $CO_2$ than ordinary Portland cement manufacture. A laboratory investigation was carried out to evaluate the effect of alkali-activating conditions on compressive strength of fly ash/slag cement and the acid corrosion resistance of this cement. Two alkali activator solution, NaOH and waterglass + NaOH solutions, were used. Waterglass concentration was the factor that gave the highest compressive strength in all tests. The next significant factor was the NaOH concentration, followed by curing temperature. Acid corrosion resistance of FC(fly ash cement) and FSC(fly ash/slag cement), such as sulfuric$(H_2SO_4)$ and hydrochloric acid(HCl), was for better than Portland cement(PC).

Algorithm for Simulation Program to Revitalization Site-Recycling (건설폐기물 재활용 활성화를 위한 시뮬레이션 프로그램 알고리즘 개발)

  • An, Yang-Jin;Lee, Jae-Sung;Lee, Kyoung-Hee;Bae, Kee-Sun;Jung, Jong-Suk
    • Proceedings of the Korean Institute Of Construction Engineering and Management
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    • 2008.11a
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    • pp.712-715
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    • 2008
  • The construction wastes rapidly increase because of redevelopment, the development of new urbanization of large-scale land development, the expansion of social infrastructure. As one of the ways to recycle construction waste to be recycled directly. This case, recycling of materials uses up most of recycled aggregate can be secured reliably. As a result, a decrease in the amount of materials brought in or taken out of the site, the cost of transportation, carbon dioxide emission, and traffic can be reduced. Economic, social and environmental effects can be expected. Therefore, this study of the construction waste "Site-Recycling" to enable the construction waste from the occurrence of "site-recycling" that can be processed in batches to apply the "Site-Recycling Simulation Program" is to develop the algorithms.

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Opportunities and Challanges of New and Ranewable Energy on Climate Change (기후변화협약에서 신.재생에너지의 기회와 도전)

  • Oh, Dae-Gyun;Kim, Kyung-Hee
    • New & Renewable Energy
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    • v.1 no.3 s.3
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    • pp.7-13
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    • 2005
  • 기후변화협약이 지난 2월16일 교토의정서의 발효로 새로운 국면을 맞이하게 되었다. 선진국들의 감축활동의 본격시작, EU의 배출권거래의 시작, CDM/JI사업을 통한 크레딧 확보를 인한 탄소기금의 형성 등 이제는 기후변화협약의 협상에 대한 논의에서 온실가스 감축을 위한 실질적인 이행이 시작되고 있다. 이산화탄소가 거래수단이 되는 새로운 경제체제가 만들어지고 있는데, 온실가스 감축실적이 양(+) 또는 음(-)의 추가적인 경제가치를 가지게 된다. 신재생에너지는 높은 초기투자비용에 의한 어려움을 가지고 있는데, 기후변화협약과 이에 의한 CDM사업의 활성화로 새로운 기회를 맞이하게 되었다. 신재생에너지 부문은 고유가와 온실가스 크레딧의 수요 증대로 시장의 수요와 기회가 증대되고 있지만, 이에 대하여 국내 입장에서 검토하여보고 이러한 기회가 어떤 의미를 가지게 되는지를 되짚어 보고자 한다.

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The Decomposition of Carbon-dioxide and Methanation with Activated Magnetite (활성화 magnetite를 이용한 이산화탄소 분해와 메탄화에 관한 연구)

  • 임병오;김승호;박영구
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.2
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    • pp.183-190
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    • 1999
  • Magnetite was synthesized with $FeSO_4$, and NaOH for the decomposition of carbon dioxide and for the study of the methane formation. The chemical equivalent ratio was changed from 0.5 to 1.50 for the magnetite synthesis. The chemical equivalent ratio was fixed in 1.00, and Nickel chloride and Rhodium chloride equally added and synthesized with the ratio was of 0.10~10.00 mole%. The crystal strucure of the synthesized magnetite was measured XRD. Putting synthesized magnetite in the reactor and using hydrogen gas oxygen-deficient magnetite was made. Injecting carbon dioxide in the reactor, the decomposition reaction was experimented. The formation of methane was confirmed injecting hydrogen gas in the reactor after carbon dioxide was decomposed.

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A Study for Fuel Characteristic by the Recycling of Waste Oil (폐유를 재활용한 연료특성 연구)

  • Lee, Jong Eun;Kang, Hyung Kyu;Lee, Jung Min;Jung, Choong Sub
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.139.2-139.2
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    • 2011
  • 산업혁명 이후 계속된 산업화로 이산화탄소, 메탄, 이산화질소와 같은 온실가스의 대기 중 농도가 지속적으로 증가하고 있다. 세계 각국은 화석연료 고갈 및 기후변화에 대처하기 위해 대체연료에 대한 연구가 활성화되고 있는데 특히, 폐유 재생과 폐기물의 발생 및 처리 문제를 극복하기 위해 많은 노력을 기울이고 있다. 본 시험은 폐유를 정제한 정제연료유와 유화정제연료유의 물성을 석유제품인 중유와 비교 분석하였다. 유화정제연료유는 폐유 중 중금속, 회분 및 슬러지 등을 제거한 후 유화제 등을 넣어 생산된 제품으로 연구를 수행하였다. 본 논문은 이에 대한 전반적인 내용을 언급하였다.

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그린카 보급정책 동향 및 호남광역경제권 전기자동차 산업 육성전략

  • Lee, Jun-Hang
    • KIPE Magazine
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    • v.16 no.2
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    • pp.25-31
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    • 2011
  • 최근 10년동안 지구환경 문제는 인류가 하는 모든 활동에 있어 기본전제가 되고 있다. 지구온난화 문제로 인해 자동차의 $CO_2$ 배출량을 줄이는 문제가 최근 수송기계 분야의 초미 관심사가 되고 있으며 온실가스 문제와 석유자원 고갈에 따른 대체에너지 문제에 따라 자동차 산업은 큰 전환기를 맞고 있다. 세계 각국에서 이산화탄소 배출규제가 법제화되면서 내연기관 중심의 자동차 기술은 그린카(친환경자동차) 기술로의 패러다임의 변화를 보이고 있다. 그린카는 전기자동차, 클린 디젤차, 연료전지차 정도로 대분류되며 전기자동 전기자동차(EV), 하이브리드 전기자동차(HEV), 플러그인 하이브리드 전기자동차(PHEV) 등으로 분류된다. 이미 그린카의 양산이 수년전부터 활발하게 진행되어 왔으며, 최근 2~3년내로 각국의 major급 자동차 메이커에서 이에 대한 양산 계획을 속속 발표하고 있다. 이러한 전 세계의 그린카 정책동향과 국내 그린카 활성화 정책 및 현정부의 광역경제권 선도산업으로 추진중인 호남광역경제권 전기자동차 산업 육성 정책에 대해 소개하고자 한다.

Effects of Persuader and Persuasion Message of Bicycle Exploration Journey (자전거 탐방여행의 설득원과 설득메시지의 효과)

  • Park, Joung-Koo
    • Journal of the Korean Institute of Landscape Architecture
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    • v.37 no.5
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    • pp.13-23
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    • 2009
  • This study investigated the effects of thae persuader and the persuasion message in order to reduce carbon dioxide emissions and activate the exploration journey using bicycles, a form of green transportation, in this green society age. Furthermore, the effects that predictive variables related to the implementation of an infrastructure for bicycles have on the intentions toward an exploration journey using bicycles were examined. The questionnaire survey was administered to 257 respondents for 9 days from March 14 to March 22, 2009. Since Gyeongju has a number of cultural relics that people can look at in one day, Gyeongju is ideal for examining a variety of tourist opinions about exploring cultural relics using bicycles. In conclusion, it was found that the 'persuader' and 'persuasion message' enhanced the desire for bicycle exploration journeys from 'will use a bicycle if possible' to 'want to use a bicycle'. In accordance with two-way ANOVA results on the desire for bicycle exploration journeys by persuader and persuasion message, the persuasion approach emphasizing health effects and geared toward bicycle enthusiasts was significantly effective. Furthermore, the most effective approach was the persuasion strategy emphasizing the 'citizens' and 'health', and 'citizens' and 'eco-friendly' among the effects created by connection of persuader and persuasion message.

Preparation and Characterization of Nanocrystalline Spinel Ferrites by Chemical Co-precipitation (화학적 공침법을 이용한 침상형 페라이트 합성)

  • Shen, Jiao-Wen;Lim, Yun-Hui;Jo, Young-Min
    • Applied Chemistry for Engineering
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    • v.22 no.2
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    • pp.185-189
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    • 2011
  • In this work, nano-sized M-ferrites (M=Co, Ni, Cu, Zn) for the decomposition of carbon dioxide were synthesized by the chemical co-precipitation. From the thermogravimetric analysis, it was clear that the maximum weight loss of each sample took place below $350^{\circ}C$. High temperature calcination resulted in more systematic crystallines, smaller specific surface area and larger particle size. An analysis by FTIR in the range of $375{\sim}406cm^{-1}$ revealed the presence of chelates at the octahedral site, which implies the formation of spinel structure in the ferrites. The current work showed that a $500^{\circ}C$ is the optimum heat treatment temperature of metal ferrites for $CO_2$ decomposition reaction.

Improved Preservation and Shelf-life Extension of Fish Cake by Modified Atmosphere Packaging (변형기체포장에 의한 어묵의 저장성 향상 및 유통기한 연장)

  • Park, Su Yeon;An, Duck Soon;Kang, Jun Soo;Lee, Dong Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.23 no.2
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    • pp.75-81
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    • 2017
  • Modified atmosphere packaging (MAP) of vacuum, 60% $N_2/40%$ $CO_2$, 100% $N_2$ and 100% $CO_2$ were examined to preserve fried fish cakes and extend their shelf life. When product packages in air were stored at 5, 10, and $15^{\circ}C$ with measurement in quality attributes, aerobic bacterial growth was found to be primary quality factor to determine the shelf life of the product. Huang's model was adopted to obtain the parameters for use in shelf life determination for a variety of packaging and storage conditions. Temperature dependence expressed in Arrhenius equation showed activation energies of 139.4 and 41.8 kJ/mol for inverse of lag time and growth rate of the microbial spoilage, respectively. MAP of 100% $CO_2$ could double the product shelf life at $10^{\circ}C$ compared to air package. High $CO_2$ concentration MAP at low temperature was found to be effective to prolong the shelf life.

Production and CO2 Adsorption Characteristics of Activated Carbon from Bamboo by CO2 Activation Method (CO2 활성화법에 의한 대나무 활성탄 제조와 CO2 흡착 특성)

  • Bak, Young-Cheol;Cho, Kwang-Ju;Choi, Joo-Hong
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.146-152
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    • 2005
  • The activated carbon was produced from Sancheong bamboo by carbon dioxide gas activation methods. The carbonization of raw material was conducted at $900^{\circ}C$, and $CO_2$ activation reactions were conducted under various conditions: activation temperatures of $750-900^{\circ}C$, flow rates of carbon dioxide $5-30cm^3/g-char{\cdot}min$, and activation time of 2-5 h. The yield, adsorption capacity of iodine and methylene blue, specific surface area and pore size distribution of the prepared activated carbons were measured. The adsorption capacity of iodine (680.8-1450.1 mg/g) and methylene blue (23.5-220 mg/g) increased with increasing activation temperature and activation time. The adsorption capacity of iodine and methylene blue increased with the $CO_2$ gas quantity in the range of $5-18.9cm^3/g-char{\cdot}min$. But those decreased over those range due to the pore shrinkage. The specific volume of the mesopore and macropore of bamboo activated carbon were $0.65-0.91cm^3/g$. Because of this large specific volume, it can be used to the biological activated carbon process. Bamboo activated carbon phisically adsorbed the $CO_2$ of maximum 106 mg/g-A.C in the condition of 90% $CO_2$ and adsorption temperature of $20^{\circ}C$. The $CO_2$ adsorption ability of bamboo activated carbon was not changed in the 5 cyclic test of desorption and adsorption.