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Development of Fly Ash/slag Cement Using Alkali-activated Reaction(1) - Compressive strength and acid corrosion resistance -  

Park, Sang-Sook (Division of Civil and Environmental Engineering, Sunchon National University)
Kang, Hwa-Young (Department of Civil and Environmental, Hanyeong College)
Han, Kwan-Su (Division of Civil and Environmental Engineering, Sunchon National University)
Publication Information
Abstract
Fly ash and blast furnace slag are an industrial by-product that can be alkali-activated to yield adhesive and cementitious materials, whose production is less energy-intensive and emits less $CO_2$ than ordinary Portland cement manufacture. A laboratory investigation was carried out to evaluate the effect of alkali-activating conditions on compressive strength of fly ash/slag cement and the acid corrosion resistance of this cement. Two alkali activator solution, NaOH and waterglass + NaOH solutions, were used. Waterglass concentration was the factor that gave the highest compressive strength in all tests. The next significant factor was the NaOH concentration, followed by curing temperature. Acid corrosion resistance of FC(fly ash cement) and FSC(fly ash/slag cement), such as sulfuric$(H_2SO_4)$ and hydrochloric acid(HCl), was for better than Portland cement(PC).
Keywords
Alkali Activated; Fly Ash/Slag Cement; Strength; Acid Corrosion Resistance;
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Times Cited By KSCI : 1  (Citation Analysis)
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1 Cochrane, J. W. and Boyd, T. J., 'Benification of fly ash by carbon burnout,' in Proc. 10th Ash Use Symp., Jan.(1993)
2 Purtas, F., 'Alkaline-activated slag cements: present and future(Spanish),' Mater. Canstrucc., 45(239), 53-64(1995)   DOI
3 Palomo, A., Grutzeck, M. W., Blanco, M. T., 'Alkali-activated fly ashes, A cement for the future,' Cem. Concr. Res., 29, 1323-1329(1999)   DOI   ScienceOn
4 진지영, 문희수, 장영남, 석탄회를 이용한 제올라이트의 열수합성, Econ. Geol., 32(6), 575-584(1999)
5 박상숙, 강화영, 한상호, 임요섭, 김동국, '알칼리-활성 플라이 애쉬 페이스트의 압축강도에 대합 배합조건 및 물유리 모듈의 영향,' 한국폐기물학회지, 23(7), 591-599(2006)
6 Van Jaarsveld, J. G. S. and Van Deventer, J. S. J., 'The potential use of geopolymeric materials to immobilize toxic metals: Part I. Theory and applications,' Miner. Eng., 10, 659-669(1997)   DOI   ScienceOn
7 Puertas, F. and Fernandez-Jimenez. A., 'Mineralogical and Microstructural Characterisation of Alkali-activated Fly Ash/Slag Pastes,' Cement & Concrete Composites, 25, 287-292(2003)   DOI   ScienceOn
8 Hossein. R. and William B., 'Alkali ash material: A novel fly ash-based cement,' Environ. Sci. Technol., 37, 3454-3457(2003)   DOI   ScienceOn
9 Bakharev, T., Sanjayan, J. G., Cheng, Y. B., 'Effect of admixtures on properties of alkali-activated slag concrete,' Cem. Concr. Res., 30(9), 1367-1374(2000)   DOI   ScienceOn
10 Atis, C. D., 'High volume fly ash abrasion resistant concrete,' J. Mater. Civ. Eng., 14(3), ACE, 274-277(2002)   DOI   ScienceOn
11 Gebauer, J., 'Alkali in clinker: influence on cement and concrete properties,' Proceedings of the 5th International Conference on Alkali-Aggregate Reaction in Concrete, Capetown, South Africa, March 30-April 3, 1981, National Building Research Institute, Pretoria, South Africa, pp. 1-9, S252/4(1981)
12 Wang, S. D., Scrivener, K. L., Pratt, P. L., 'Factors affecting the strength of alkali-activated slag,' Cem. Concr. Res., 24(6), 1033-1043(1994)   DOI   ScienceOn
13 Yueming F., Suhong, Y., Zhiyun, W., Jingyu Z., 'Activation of fly ash and its effects on cement properties,' Cem. Concr. Res., 29, 467-472(1999)   DOI   ScienceOn
14 Puertas, F., Martinez-Ramirez, S., Alonso, S., Vazquez, T., 'Alkali-activated fly ash/slag cement strength behaviour and hydration products,' Cem. Concr. Res., 30, 1625-1632(2000)   DOI   ScienceOn
15 Davidovits, J., 'Geopolymer: Inorganic polymeric new materials,' J. Mater. Eng., 16, 91-139(1994)
16 Roy, A., Schilling, P., Eaton, H., 'Alkali Activated Class C Fly Ash Cement,' U. S. Patent 5,435,843, Issued July 25(1995)