• Journal of Forest and Environmental Science
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• v.22 no.1
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• pp.27-31
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• 2006

Sedimentation characteristics such as SS, COD removal efficiency of wastewater in the toilet paper mill using recycled paper were examined by zeta potential. Optimum dosage of coagulant were determined by turbidity, SS, COD and then equation for treatment efficiency was suggested. Mechanical strength of floc was determined by turbidity.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.7
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• pp.483-491
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• 2014

In this study, we developed an M-COS (molit coagulant-dosing optimization system), which enables to apply the optimum coagulant dose determined in real time, in order to satisfy the total phosphorus (TP) regulation (0.5 mg/L), and then tested its field applicability. Field tests were conducted at three different periods in 2014 in a pilot plant where the M-COS was installed. Coagulant reduction rate by the M-COS was 10.4%, 15.3%, and 9.0% for each period (average 11.6%), when comparing with a control where coagulants were applied at a constant rate. Total cost for the M-COS or control was estimated by summing up the coagulant cost and sludge treatment cost, and then the resulting cost increase was predicted. Cost reduction rate by the M-COS was 13.8%, 20.0%, and 11.4% for each period (average 15.0%). This study indicates that the M-COS can be an alternative to a conventional system for TP treatment, with a better cost efficiency.

• Journal of the Korea Organic Resources Recycling Association
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• v.12 no.2
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• pp.101-109
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• 2004

In this study, the solid-liquid separation characteristics of swine wastewater were investigated for the coagulation and dissolved air flotation (DAF). Coagulation characteristics were studied using jar-tester with the different coagulants and dosage amounts. DAF characteristics were also investigated in terms of the different flotation conditions with the raw swine wastewater, pH adjustment only, and adding coagulants. When the raw swine wastewater was coagulated with the only inorganic coagulants, the proper inorganic coagulants were founded as $FeCl_3$ > PAC > Alum orderly, and the optimal coagulant dosages were founded as $1,000mg/{\ell}$, $1,500mg/{\ell}$, $1,500mg/{\ell}$, respectively. As the raw swine wastewater was treated with the polymer coagulants, the only cationic polymer coagulant showed an effective coagulation and the optimal dosage of cationic coagulant was founded as $200mg/{\ell}$. When the different dosages of cationic polymer was added to each $500mg/{\ell}$ of the inorganic coagulants, the proper inorganic coagulants were founded as $FeCl_3$ > Alum > PAC orderly, and optimal cationic polymer dosages was founded as $25mg/{\ell}$, $25mg/{\ell}$, and $100mg/{\ell}$, respectively. Resulting from the raw swine wastewater experiments using DAF without coagulation, the proper operation conditions of DAF were set to 400% of recycling ratio, 4 atm in air dissolving tank, and under pH 3. But the raw swine wastewater was difficult to successfully operate DAF without pre-coagulation. While the DAF separation after pre-coagulation using inorganic coagulants was not accomplished due to the low intensity of the floc, DAF after pre-coagulation using both the inorganic and cationic polymer coagulants was accomplished very well. Optimal dosage of cationic polymer coagulant in case of $500mg/{\ell}$ Alum dosage was founded as $500mg/{\ell}$.

• Membrane Journal
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• v.16 no.3
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• pp.182-187
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• 2006

The purpose of this study was to investigate effect of coagulation on filtration performance of membrane in submerged MBR system and influence of continuous aeration to reduce fouling of membrane surface on coagulated floc. For this purpose, aeration tank sludge of MBR system was compared with jar-test sludge. The experimental results were analysed in terms of floc size and SRF (Specific resistance of Filtration). The more alum was added, the more content of floc below $10{\mu}m$ reduced and SRF decreased. But compared with jar-test results, it was found that effect of coagulation on MBR floc was reduced. Operation time of membrane in alum added MBR was longer than that in control MBR. But operation time was not proportional to alum dose. It was thought that the result was reason that floc below $10{\mu}m$ was not reduced sufficiently by shear force of continuous aeration. Moreover it was founded that if alum is added more than proper dose, it brings filtration resistance to increase.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.12
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• pp.883-888
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• 2013

Coagulation and sedimentation tests were conducted with clay and three different coagulants of soil origin (AC-A, AC-B, AC-C) to determine optimal coagulant types and doses to remove algae in stagnant water bodies such as reservoirs. Raw water had an algal density of 2,950 cells/mL and was dominated by Cyanobacteria. Removal rates of algal density by clay (50 mg/L) were 49% and 85% after 10 and 30 minutes sedimentation, respectively. Other natural coagulants achieved 80-90% removal in 10 minutes and 89-94% removal in 30 minutes of sedimentation after adding 20 mg/L each. AC-A was the optimal coagulant from this study considering algal removal rates and other water quality parameters such as turbidity and pH. For the same removal rates of algae, raw waters with higher algal densities required higher coagulant doses although no strong corelation was observed. The coagulants of soil origin did not impact orgnic contents and pH of raw water, but remove phosphate up to 70%.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.8
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• pp.428-434
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• 2016

This study evaluated the efficacy of Ti-based coagulants on phosphorus (P) removal from municipal wastewater and compared them with Al-based coagulants. Jar test experiments were performed at various chemical doses and OH/Ti molar ratio (B value). The higher the intial phosphate ($PO_4-P$) concentration, the lower the [Ti]/[P] to reach a residual concentration below 0.2 mg P/L. Removal efficiencies of total phosphorus increased with an increased coagulant dose but decreased after the efficiencies reached their maximum value regardless of coagulant or B value. On the other hand, $PO_4-P$ removal showed an increasing trend with an increased coagulant dose, reaching the plateau value under large coagulant dose conditions for both Ti- and Al-based coagulants regardless of B value. The chemical dose of Ti-based coagulants was approximately twice higher than that of Al-based coagulants with the same P-removal efficiency. The coagulation efficiency was influenced by different B values.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.8
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• pp.775-780
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• 2008

Sludge conditioning is widely used to improve aggregation and dewaterability of waste sludge in sludge treatment processes. The study aims to examine quantitative correlations between coagulant dosage and sludge cake dewaterability using three kinds of coagulants, such as an aluminum sulfate, a ferric chloride, and a poly aluminum chloride(PAC). When an aluminum sulfate, a ferric chloride, and a PAC were injected with 0.79$\sim$1.19 mmol/g, 0.61$\sim$1.25 mmol/g TSS, and 0.21$\sim$0.39 mmol/g TSS, respectively, specific resistances to filtration of the sludge were decreased at 95.0% or more. This study shows that the correlation between coagulant dosage per g sludge(D) and normalized specific resistance to filtration(R) could be expressed by the exponential functions.

• Membrane Journal
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• v.22 no.2
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• pp.135-141
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• 2012

This study was carried out to find the optimum coagulation conditions for ceramic microfiltration process of Y water treatment plant. When pH of raw water from Y Dam was adjusted to 7, the efficiency of coagulation was the best and the optimun dosage of coagulant was 3 mg/L(as $Al_2O_3$) for turbidity of raw water less then 10 NTU in Jar test. In mini module test, the decay rate of specific flux was the lowest when PAC (poly Aluminum Chloride) was used among coagulants and pH was adjusted to 7. The decay rate of specific flux for raw water turbidity of 10~30 NTU was greatly decreased with increase of dosage of coagulant (PAC) while the rate was not significantly decreased for turbidity more than 50 NTU. In conclusion, the optimum dosage of PAC (11% as $Al_2O_3$) was 30 and 50 mg/L for raw water turbidity of less than 10 NTU and more than 50 NTU, respectively. The dosage of PAC should be increased linearly 30 to 50 mg/L depending on raw water turbidity of 10 to 50 NTU.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.11
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• pp.1139-1145
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• 2008

The objectives of this research are to investigate the mechanism of coagulation affecting UF and find out the optimum conditions of the combined of coagulation with UF membrane filtration for NOM removal. During the mixing period, substantial changes in particle size distribution occurred under rapid and slow mixing condition due to the simultaneous formation of microflocs and NOM precipitates. Therefore, combined pretreatment using coagulation (both rapid mixing and slow mixing) improved dissolved removal efficiency. Also, for combined coagulation to membrane process, flux reduction rate showed lower than only UF process. The rate of flux decline for the hydrophobic membrane was considerably greater than for the hydrophilic membrane. Applying coagulation process before membrane filtration showed not only reducing membrane fouling, but also improving the removal of dissolved organic materials that might otherwise not be removed by the membrane.

• Journal of the Korean Wood Science and Technology
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• v.48 no.3
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• pp.271-282
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• 2020

Sewage treatment plants are social infrastructure of cities. The sewage distribution rate in Korea is reaching 94% based on the sewage statistics based in the year of 2017. In Korean sewage treatment plants, use of PAC (Poly Aluminum Chloride) accounts for 58%. It contains a large amount of impurities (heavy metal) according to the quality standards, however, there have been insufficient efforts to reinforce the standards or technically improve the quality, which resulted in secondary pollution problems from injecting excessive coagulant. Also, the increase in the use of chemicals is leading to the increases in the annual amount of sewage sludge generated in 2017 and the need to reuse sludge. As such, this study aims to verify the possibility of reusing sludge by evaluating the stability of heavy metals based on the injection of coagulant mixture during water treatment which uses the torrefield wood powder and natural materials, and evaluating the sedimentation and heating value of sewage sludge. As a result of analyzing heavy metals (Cr, Fe, Zn, Cu, Cd, As, Pb, and Ni) from the coagulant mixture and PAC (10%), Cr, Cd, Pb, Ni, and Hg were not detected. As for Zn, while its concentration notified in the quality standards for drinking water is 3 mg/L, only a small amount of 0.007 mg/L was detected in the coagulant mixture. Maximum amounts of over double amounts of Fe, Cu, and As were found with PAC (10%) compared to the coagulant mixture. Also, an analysis of sludge sedimentation found that the coagulant mixture showed a better performance of up to double the speed of the conventional coagulant, PAC (10%). The dry-basis lower heating value of sewage sludge produced by injecting the coagulant mixture was 3,378 kcal/kg, while that of sewage sludge generated due to PAC (10%) was 3,171 kcal/kg; although both coagulants met the requirements to be used as auxiliary fuel at thermal power plants, the coagulant mixture developed in this study could secure heating values 200 kal/kg higher than the counterpart. Therefore, utilization of the coagulant mixture for water treatment rather than PAC (10%) is expected to be more environmentally stable and effective, as it helps generating sludge with better stability against heavy metals, having a faster sludge sedimentation, and higher heating value.