• Title/Summary/Keyword: 응집성분석

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X-선 회절분석을 이용한 일라이트-스멕타이트 기본입자의 적층성에 관한 연구

  • 강일모;문희수
    • Proceedings of the Mineralogical Society of Korea Conference
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    • 2003.05a
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    • pp.10-10
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    • 2003
  • 일라이트-스멕타이트 혼합층광물(I-S)은 열역학적으로 상호 대립적인 두 가지 모델로 이해되고 있다. 첫째, MacEwan 결정자 모델은 I-S를 5-20개의 스멕타이트와 일라이트 층으로 구성된 결정자로 해석한다. 이러한 모델은 분산과 재응집 과정을 기초로 하는 X-선 회절분석(XRD)에서 기인한 것으로 Reynolds의 XRD 모델과 동일하다. 둘째, 기본입자 모델은 I-S를 물리적으로 분리될 수 있는 최소 입자인 기본입자가 $c^{*-}$축 방향으로 응집된 응집체로 해석한다. 이러한 모델은 분산 과정을 기초로 하는 주사전자현미경(TEM) 관찰에서 기인한 모델이다. 강일모 등(2002)은 이 두 가지 모델을 비교함으로써 1< $N_{F}$<100/% $S_{XRD}$ ( $N_{F}$=평균 기본입자 층개수, %$S_{XRD}$=XRD 분석을 통하여 측정된 팽창성)을 도출하였다. 이 식은 기본입자모델과 Eberl & Srodon(1988)이 제시한 최대 팽창성(%$S_{MAX}$)을 동시에 해석할 수 있게 해준다. %$S_{MAX}$는 XRD 모델에서는 고려하지 않는 I-S 결정자 상$\cdot$하부에 존재하는 두 개의 0.5nm 규산염층을 하나의 스멕타이트 층으로 간주하여 얻어진 팽창성이다. Srodon et al.(1992)은 %$S_{MAX}$=100/ $N_{F}$을 제시하였으며, 강일모 등(2002)은 %$S_{MAX}$는 기하학적으로 기본입자가 무한적층을 하였을 때 관찰되는 %$S_{XRD}$와 동일함을 밝힌 바 있다. 만약, XRD 분석을 위한 시료 준비과정에서 I-S 결정자가 분산되었다가 재응집을 한다면, XRD에서 관찰되는 결과는 일차적으로 기본입자의 적층성에 영향을 받게 된다. 따라서, 기본 입자의 적층성은 XRD 분석을 이용하여 I-S 구조를 해석하는데 매우 중요한 요인이다. 본 연구는 기본입자의 적층성을 정량화하기 위해 %$S_{XRD}$=A/ $N_{F}$ (0$S_{MAX}$=100/ $N_{F}$로부터 얼마나 벗어나 있는가는 지시해 준다 금성산화산암복합체에서 산출되는 11개 I-S 시료와 14개의 Drits et al.(1998) 자료로부터 1nA=-0.14 $N_{F}$+4.7의 실험식을 도출할 수 있었으며, 기본입자의 적층성은 일차적으로 기본입자의 두께에 의해 영향을 받는 것으로 관찰되었다. Nadeau(1985)는 기본입자두께분포로부터 I-S 결정자의 팽창성을 측정하기 위하여 Ps=$\Sigma$p(N)/N을 제시하였다(Ps=스멕타이트 층 비율, N=기본 입자 층개수, p(N)=N의 확율). 그러나 위식은 실질적으로 %$S_{MAX}$를 제공해주기 때문에 %$S_{XRD}$를 유추하는데는 부적합하다. 본 연구는 이를 변형하여 Ps=$\Sigma$p(N)A(N)/N을 제시하였다(A(N)=N에 대한 A값). 위의 실험식을 사용하여 헝가리산 Zempleni 시료(15%$S_{XRD}$)의 기본입자분포로부터 %$S_{XRD}$를 계산한 결과, 16%$S_{XRD}$의 결과값을 얻을 수 있었다. 따라서, 본 연구에서 도출한 관계식들이 유효함을 확인할 수 있었다.계식들이 유효함을 확인할 수 있었다.

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Studies on the Factors Affecting Quality and Textural Characteristics of Artificial Gluten Meat Part II: Effects of amount of ingredients on properties of AGM (Walnut, Oils, Salt, Onion) (글루텐 인조육의 품질특성에 영향을 주는 요인과 물성에 관한 연구 2보 : 각 요인이 품질 특성에 미치는 영향 (호두, 식용유, 소금, 양파))

  • 박춘란;김기숙;장주익
    • Korean journal of food and cookery science
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    • v.4 no.2
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    • pp.11-19
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    • 1988
  • These experiments were carried out to study the factors affecting quality and textural characteristics in the preparation of artificial gluten meat (AGM). These results were compared with the raw beef on its properties. Effects of amounts of ingredients on properties of AGM were summarized as follows: 1. On effects of amounts of ingredients, walnut was one of the most factors on the color in AGM The more increased the amounts of walnut, the more decreased hardness, cohesiveness, chewiness, and the more increased springiness and water holding capacity. Therefore, the 30% of walnut added sample became similar to raw beef. 2. The kinds and amounts of oil and mixing methods did not affect on color, shear force, and chewiness, but did on cohesiveness significantly 3. The more increased the salt levels, the better were the hardness and chewiness, but shear force and water holding capacity were not affected. 2% of salt added sample approached to raw beef in hardness, springiness, cohesiveness and chewiness. 4. The more onion levels increased, the more hardness and chewiness decreased.

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A Study on the Decontamination Performance of Cesium by Soil Washing Process With Flocculating Agent (응집제를 적용한 토양세척 공정에서의 세슘 제염 성능 평가 연구)

  • Song, Jong Soon;Kim, Sun Il
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.1
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    • pp.41-47
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    • 2018
  • Radioactive substances, especially $^{137}Cs$ discharged in the course of Nuclear Power Plant Accident or maintenance of power plants, cause contamination of the soil. For habitation of residents and reuse of industrial land, it is inevitably necessary to decontaminate the soil. This study examines a soil washing process that has actually been used for washing of radioactive-contaminated soil. The soil washing process uses a washing agent to weaken surface tension of the soil and cesium, separating cesium from the soil. In this study, in order to raise the efficiency of the process, a flocculating agent was added to the washing water to remove fine soil and cesium. The cesium concentrations before and after applying the flocculating agent to cesium solution were measured through ICP-OES. When using 0.1 g of J-AF flocculating agent in the experiment, the maximum Cs removal performance was approximately 88%; the minimum value was 67%. Species combinations between cesium and soil were predicted using Visual MINTEQ Code; the ability to reuse the washing water or not, and the removal rate of the fine soil, determined via measurement of the turbidity after applying the flocculating agent, were determined.

Characteristic and Economic evaluation of low cost TiO2 photocatalyst made by TiCl4 (TiCl4로 제조된 저비용 이산화티타늄 광촉매의 특성 및 경제성 평가)

  • Kim, Jong Kyu
    • Proceedings of the Korea Water Resources Association Conference
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    • 2019.05a
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    • pp.197-197
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    • 2019
  • 총인처리시설에서는 응집제를 주입하여 인이나 오염물질을 침전시켜 처리하고 있으며 PAC(poly aluminum chloride)나 $FeCl_3$, $Al_2(SO_4)_3$, 등 다양한 종류의 응집제가 사용되어지고 있다. 하지만 기존에 사용되어 지고 있는 알루미늄계열의 응집제는 처리수에 잔류이온이 존재하게 되어 인체에 축적돼 알츠하이머 병 등 신체질환을 유발할 수 있는 단점이 있다. 따라서 이러한 단점을 사전에 예방하기 위해 $TiCl_4$와 같은 티타늄계열 응집제에 대한 연구가 진행되고 있다. $TiCl_4$ 응집제는 인 제거에 효과적으로 적용할 수 있으며 수중에 잔류이온을 유발하지 않으며 Ti이온은 치과임플란트나 의료장비로 사용될 만큼 인체에 무해하다고 알려져 있다. 응집제 사용에 따라 생성된 응집슬러지의 처리방안에 있어서 기존 응집제의 경우 생성된 슬러지의 대부분은 하수슬러지 위탁처리업체를 통해 소각 및 매립, 재활용 되고 있으나, $TiCl_4$를 응집제로 사용할 경우 생성된 슬러지를 인발하여 건조 및 소성을 통해 이산화티타늄으로 재활용할 수 있어 슬러지를 친환경적으로 처리가 가능해 기존 슬러지 처리방안의 경제적, 환경적 부담을 줄일 수 있는 장점이 있다. 따라서 본 연구에서는 $TiCl_4$를 하수처리장 방류수에 주입하여 수중의 총인(T-P)을 처리한 후 생성된 슬러지를 인발하여 건조와 소성과정을 거쳐 이산화티타늄을 제조하였다. 방류수를 취수해 2.5mg/L의 초기 총인 농도를 가진 원수를 제조하였으며 제조된 원수에 $TiCl_4$를 0.6mL 주입하였을 때 99.93%의 총인제거효율을 얻을 수 있었다. 응집 실험 후 생성된 슬러지를 인발하여 건조 후 $300{\sim}1000^{\circ}C$의 각각 다른 온도조건에서 소성하여 이산화티타늄을 제조하였으며, SEM과 XRD를 통해 제조된 이산화티타늄의 표면특성과 결정성 분석을 실시하였다. 제조된 이산화티타늄은 $500{\sim}800^{\circ}C$에서는 아나타제, $900{\sim}1000^{\circ}C$에서는 루타일 결정구조가 나타났다. 또한, $TiCl_4$ 주입량에 따른 이산화티타늄의 최종 생산량과 제조 시 사용되는 건조로 및 소성로의 경제적 비용 등을 고려하여 이산화티타늄 1Ton을 제조하기 위해 필요한 단가를 산출하였다. 본 연구에서 제조된 이산화티타늄 1kg의 생산단가는 약 5,400원으로 나타났으며, 가장 많이 사용되는 P-25 광촉매 보다 저렴한 가격으로 제조 및 판매를 기대할 수 있다. 따라서 하수처리장에 적용 시 기존 응집제 보다 비싼 $TiCl_4$ 비용을 보완하고 친환경적인 슬러지 처리로 제조된 이산화티타늄의 유통 및 현장적용을 통해 경제적, 환경적으로 우수하다고 판단된다.

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The Effect of Group Success on Organizational Commitment: Collective Efficacy and Group Cohesiveness of Naval Officials (집단의 성공 경험이 조직몰입에 미치는 영향: 해군 간부들의 집단효능감과 집단응집성을 중심으로)

  • Gil-Hwan Kim ;Ju-Hyun Kim ;Dong-Gun Park
    • Korean Journal of Culture and Social Issue
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    • v.23 no.4
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    • pp.527-556
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    • 2017
  • The purpose of this study was to examine the effect of group success on organizational commitment in organizational situations. It also aimed to investigate the dynamics in the relevance of motivational attitudes to the individual and group level variables(collective efficacy, group cohesiveness). This study used a multi-level model and tested a series of hypotheses through meso-mediation procedure. The results from 613 naval officials in 36 groups provided evidence that; (1) collective efficacy mediated the relationship between group success and group cohesiveness, (2) the cross-level main effects of group success and collective efficacy were shown on vocationa[l self-efficacy, (3) group cohesiveness exerted positive influence on organizational commitment and (4) the meso-mediation effects among the variables at the multi-level were revealed. It was found that the degree of work motivation and motivational attitudes depended on the group's contextual factors, and that each group's shared perceptions on group performance outcomes could be an important motivational source and cornerstone leading to group cohesiveness. The implications and limitations of these study as well as the direction for future study were discussed.

Cohesion and Coupling Metrics for Component Design Model (컴포넌트 설계에 대한 응집도와 결합도 메트릭스)

  • Ko, Byung-Sun;Park, Jai-Nyun
    • The KIPS Transactions:PartD
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    • v.10D no.5
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    • pp.745-752
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    • 2003
  • The component-based development methodology becomes famous as the reuse technology for independence and productivity of software development It is necessary component metrics for component-based systems, because It should be measurable to improve the quality of the software. Hence, in this paper, we propose component cohesion and coupling metrics which is reflected in characteristics of component. The operation use value is calculated by the information of classes interface commonly uses to offer the component's service. And, the operation similarity value is calculated by the operations use value. Component cohesion and coupling is calculated by the operation similarity and based of the information which is extracted in the analysis phase. And, we examine the necessity of component metrics in comparison with object-oriented metrics.

Effects of Academic Emotion Regulation and Group Cohesiveness on Learning Satisfaction and Learning Interest in the University Flipped Learning (대학 플립러닝 수업에서 학업적 정서조절과 집단응집성이 학습만족도와 학습흥미도에 미치는 영향)

  • Lee, Jeongmin;Jung, Yeonji;Park, HyeonKyeong;Cho, Boram
    • Journal of The Korean Association of Information Education
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    • v.20 no.4
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    • pp.341-356
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    • 2016
  • The purpose of this study is to investigate the effects of academic emotion regulation and group cohesiveness on learning satisfaction and learning interest in the flipped learning at the university. In order to examine the purpose, this study applied a problem-solving classroom model to the flipped learning. 33 university students participated in the flipped learning activities for 9 weeks, and the data from them were used for multiple regression analysis. The results indicated that learners' academic emotion regulation did not affect learning satisfaction, and subjects' group cohesiveness influenced on learning satisfaction. Second, learners' academic emotion regulation did not affect learning interest, but their group cohesiveness had an impact on learning interest. This research has several implications with regard to suggesting the guidelines and conditions for the design and implementation of the flipped classroom at the university.

A Study on the Applicability of Torrefied Wood Flour Natural Material Based Coagulant to Removal of Dissolved Organic Matter and Turbidity (용존성 유기물질 및 탁도 제거를 위한 반탄화목분 천연재료 혼합응집제의 적용성에 관한 연구)

  • PARK, Hae Keum;KANG, Seog Goo
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.4
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    • pp.472-487
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    • 2020
  • With the emergence of abnormal climate due to the rapid industrialization, the importance of water quality management and management costs are increasing every year. In Korea, for the management of total phosphorus and total nitrogen, the major materials causing the water quality pollution, coagulants are injected in sewage treatment plants to process organic compounds. However, if the coagulant is injected in an excessive amount to PAC (Poly Aluminium Chloride), a secondary pollution problem might occur. As such, a study on the applicability of natural material-based coagulant is being conducted in Korea. Thus, this study aimed to evaluate the applicability of a mixed coagulant developed by analyzing water quality pollutants T-P, T-N as well as their turbidity, in order to derive the optimum mixing ratio between PAC and torrefied wood flour for the primary settling pond effluent. Under the condition where the content of PAC (10%) and torrefied wood flour is 1%, T-P showed the maximum removal efficiency of 92%, and T-N showed approximately 22%. This indicates that removal of T-N which includes numerous positively charged organic compounds that are equivalent to mixed coagulant is not well accomplished. Turbidity showed the removal efficiency of approximately 91%. As such, 1% of torrefied wood flour was determined to be the optimum addition. As a result of analyzing the removal efficiency for organic compounds by reducing PAC concentration to 7%, T-P showed a high maximum removal efficiency of 91%, T-N showed 32%, and turbidity showed the maximum of 90%. In addition, a coagulation process is performed by using the mixed coagulant based on 1% content of torrefied wood flour produced in this study by performing a coagulation performance comparative experiment with PAC (10%). As a result, PAC concentration was reduced to 30-50%, a similar performance with other coagulants in market was secured, PAC injection amount was reduced that an economic effect can be achieved, and it is considered to perform a stable water treatment that reduces the secondary pollution problem.