• Applied Chemistry for Engineering
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• v.5 no.3
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• pp.385-394
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• 1994

Numerical solutions were obtained to the model equations for various of the parameters characterizing the pore structure, effective internal diffusion, and the chemical reaction constant. The conversion was decreased with the cause of pore closure at the surface of reacting particles, reduction of porosity, surface area of reaction and effective diffusion coefficient in the solid with the progress of reaction. Total conversion was strongly dependent on the local conversion at surface. According to the decreasing of impregnated concentration of the copper oxide and the increase of the flue gases concentration, total conversion was increased. The conversion was affected by gas flow rate and pore size distribution in the reacting solid.

• The Journal of Engineering Geology
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• v.29 no.1
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• pp.23-35
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• 2019

Landslides occur due to heavy rainfall in the summer season. Some of water may infiltrate into the ground; it causes a high saturation condition capable of causing a landslide. Soil properties are crucial in estimating slope stability and debris flow occurrence. The main study areas are Gwanaksan, Suraksan and Bukhansan (Mountain) in Seoul. A total of 44 soil samples were taken from the study area; and a series of geotechnical tests were performed. Physical and mechanical properties were obtained and compared based on region. As a result, among well-graded soils, they are classified as a clayey sand. Coarse-grained and fine-grained contents are approximately 95% and 5%, respectively, with very low amount of clay content. Density, liquid limit and dry unit weight are ranged in $2.62{\sim}2.67g/cm^3$, 27.93~38.15% and $1.092{\sim}1.814g/cm^3$. Cohesion and internal friction angle are 4 kPa and $35^{\circ}$ regardless of mountain area. Coefficient of permeability is varied between $3.07{\times}10^{-3}{\sim}4.61{\times}10^{-2}cm/sec$; it means that it results in great seepage. Permeability is inversely proportional to the uniformity coefficient and is proportional to the effective particle size. In the formal case, there was a difference by mountain area, while in the latter, the tendency was almost similar.

• Nuclear Engineering and Technology
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• v.14 no.2
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• pp.86-91
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• 1982

In 1977, spent fuel storage capacity of Ko-Ri Unit 1 was raised to contain 4-2/3 core, by reducing the center-to-center spacing between fuel assemblies from 53.34cm to 36cm. In this paper the adequacy is discussed in detail by examining the previous design analysis report. According to the analytic method presented by Core Performance Branch, study on credible abnormal moderator density condition is performed by using KENO-IV for the redesigned spent fuel storage facility. Result shows that 36cm for the center-to-center spacing between fuel assemblies is not enough to keep the storage safe at water density of 0.1143g/㎤, which gives the maximum $K_{eff}$ 0.9958$\pm$0.0048, which exceeds the CPB regulation limit 0.98. From sensitivity study regarding to the center-to-center spacing, it should be maintained to space greater than 43cm in order to meet the CPB requirements.s.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.17 no.4 s.107
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• pp.393-399
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• 2006

In this paper we applied a ray tracing method to estimate the scattering characteristics from large scale random rough surfaces. For the electromagnetic field evaluation, we have used the diffracted coefficient of the knife edge diffraction for the diffracted rays and Fresnel's reflection coefficients in connection with reflected rays. In addition, we examine to search for the traced rays using the imaging method which can be obtained all rays to arrived at receivers accurately and the diffracted field from rough surfaces is considered. Numerical examples have been carried out for the scattering characteristics of an ocean wave-like rough surface and delay spread characteristics of a building-like surface. In the present work we have demonstrated that the ray tracing method is effective to numerical analysis of a rough surface scattering.

• Solar Energy
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• v.17 no.3
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• pp.13-21
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• 1997

In this study, the theoretical equation of thermal storage efficiency was established to applied long term hot water storage system. The, effective thermal diffusivity and storage efficiency were, measured through the experiment to predict the degree of mixture in thermal storage tank. The effective thermal diffusivity was inversely preportional to the storage efficiency. The most effective storage efficiency was obtained under condition of low flow rate and using the perforated distributor.

• Journal of the Korean Society of Clothing and Textiles
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• v.27 no.11
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• pp.1300-1306
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• 2003

Cotton fibers were treated, with 1, 2, 3, 4-butanetetracarboxylic acid (BTCA) which is formaldehyde-free reagent to impart durable press performance. The dyeability, dyeing rate, and diffusion coefficient, of BTCA treated cottons were compared to prove the changes of pore size structure using direct dyes and disperse dyes. Diffusion coefficients of BTCA treated cotton fibers were determined at acidic conditions to figure out the effect of swelling. Since the dyeability of BTCA treated cotton fibers dyed with direct dyes were reduced, it is considered that the dyeability to direct dyes is related to the quantity of residual large pores. But, the dyeability to disperse dyes were increased due to the less reduction of small pore sizes and the increase of hydrophobicity in BTCA treated cotton cellulose. The dyeability to direct dye and disperse dye were decreased more at acidic conditions than at neutral conditions. It seemed that the swelling of pores in the fiber were inhibited.

• Proceedings of the Korean Nuclear Society Conference
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• 1998.05a
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• pp.70-75
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• 1998

한·러 공동으로 수행한 BFS-73-1 임계실험의 측정자료 일부를 대상으로 하여 1차 구축된 액체금속로 노심설계용 종합전산체계인 K-CORE 시스템의 정당성을 입증하기 위하여 계산 결과와의 비교 분석을 수행하였다 계산적 분석에서 육각주모델을 사용한 노달확산근사계산을 주 계산방법으로 사용하였다. 비교 분석 결과, 유효증배계수는 계산치가 실험치와 1% 범위 내로 예측되었다. 우라늄 핵분열을 분포의 경우, 노심영역에서 C/E가 7% 차이 내로 구하여졌으며, 노심/블랑켓 접경영역과 블랑켓 영역에서는 보다 큰 차이를 보였다. 노심중앙에서의 반응률비 계산에서는 C/E가 2 % 차이 내로 예측되었다

• The Journal of Engineering Geology
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• v.18 no.3
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• pp.257-262
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• 2008

In the study it was investigated the diffusion characteristics of heavy metal pollutions such as Cu, Pb, Hg and As which was the main pollution sources of soils from abandoned mines. The pollution of Cu and Pb was caused by Mine A, that of Hg was caused by Mine 3, that of Pb was caused by Mine C and that of Cu, Pb, As was caused by Mine D. Though the high concentration was detected within 100m from abandoned mines, the low concentration was detected over than 100m from abandoned mines in all heavy metals investigated except As. It means that it was very difficult to estimate the pollution level of As caused abandoned mines. The results were discussed in the concentrations of Cu, Pb and distances showed a good relationship with 0.71 and 0.68 as the coefficient of correlation, respectively. In particular the relativity of Cu to Pb as very strong with 0.84 as the coefficient of correlation. It was consistent with the chemical behavior in soils in the case of Cu and Pb. Therefore it will be a promising approach to remove Cu and Pb with estimated values in the study.

• Clean Technology
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• v.7 no.3
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• pp.187-194
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• 2001

The desulfurization process which belongs to the gas refining part is the unit process that eliminates $H_2S$ and COS in the coal gas formed by the coal gasification part in the integrated gasification combined cycle(IGCC). In this study, natural manganese ores were selected as the raw material of the desulfurization sorbent due to economical efficiency. Initial rates for the reactions between $H_2S$ and desulfurization sorbent using natural manganese ores were determined in a temperature range of $400{\sim}800^{\circ}C$ using a thermobalance reactor. All reactions were first order with respect to $H_2S$ and were in accord with the Arrhenius equations. When sulfidation reaction was controlled by diffusion, the temperature dependence of the effective diffusivity was given by the Arrhenius equation. Activation energies and frequency factors were obtained from the product layer diffusion coefficient of various sorbents by plotting as Arrhenius equation form.

• Journal of the Microelectronics and Packaging Society
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• v.13 no.1 s.38
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• pp.7-15
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• 2006

In-situ observation of electromigration in thin film pattern of 63Sn-37Pb solder was performed using a scanning electron microscope system. The 63Sn-37Pb solder had the incubation stage of electromigration for edge movement when the current density of $6.0{\times}10^{4}A/cm^2$ was applied the temperature between $90^{\circ}C\;and\;110^{\circ}C$. The major diffusion elements due to electromigration were Pb and Sn at temperatures of $90-110^{\circ}C\;and\;25-50^{\circ}C$, respectively, while no major diffusion of any element due to electromigration was detected when the test temperature was $70^{\circ}C$. The reason was that both the elements of Sn and Pb were migrated simultaneously under such a stress condition. The existence of the incubation stage was observed due to Pb migration before Sn migration at $90-110^{\circ}C$. Electromigration behavior of 63Sn-37Pb solder had an incubation time in common for edge drift and void nucleation, which seemed to be related the lifetime of flip chip solder bump. Diffusivity with $Z^*$(effective charges number) of Pb and Sn were strongly affect the electromigration-induced major diffusion element in SnPb solder by temperature, respectively.