• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2000.04a
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• pp.48-48
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• 2000

효율적인 wet-end시스템의 적용으로 중성 초지시스템의 이점을 최대한 구현하고 이에 따른 초지계의 안정성 및 원가절감 등을 얻기 위해서는 중성 초지 시스템에서 사용되는 사 이즈제 및 사이징 공정에 대한 연구가 매우 중요하다. 현재 중성 사이즈제로는 AKD와 A ASA가 가장 널리 사용되고 있는데, 유럽에서는 주로 AKD가 쓰이고 있으며, 미국에서는 A ASA가 50%정도 사용되고 있다 .. AKD에 비해서 ASA는 사이즈도의 발현이 매우 빨라 사이 즈 프레스에서 사이즈도가 발현되므로 사이즈 프레스에서의 픽엽 조절 및 지절감소에 유리 한 장점을 가지고 있다. 하지만 ASA는 AKD에 비해 반웅성 높아 습부에서의 가수분해되어 초지 조업성을 악화시키는 문제점을 지니고 있다. 이러한 문제를 극복하기 위해서는 ASA 유화액의 정착성을 개선시키기 위한 연구가 시급히 요청되고 있으며 여기에는 ASA의 유화 에 사용되는 양성전분의 최적화가 가장 핵심적인 기술로 평가된다. 현재 ASA용 유화제로는 양성전분이 가장 많이 사용되고 있다. ASA 에멀션 제조에 있 어서 양성전분의 역할은 음전하를 가지고 있는 ASA 입자에 홉착되여 양전하를 부여함으로 써 콜로이드 업자의 안정성을 부여할 뿐만 아니라 섬유와의 정전기적 인력을 유도하여 정착 을 증진시키는 효과를 나타낸다. ASA 유화용으로 쓰이는 양성전분 중에서는 감자전분이 가 장 효과적인 것으로 알려져 있으며 옥수수나 타피오카 둥도 쓰이고 있다. 그러나 국내의 경 우 감자전분은 옥수수전분보다 가격이 비싸다는 단점이 있으므로 저렴한 옥수수 전분을 이 용하여 ASA 유화용 변성전분의 개발이 국내 제지산업의 경쟁력 강화를 위해 시급히 요망 되고 있다. 본 연구의 목표는 옥수수 전분을 이용한 ASA용 유화안정제를 개발하고 그 효과를 극대 화시킬 수 있는 적용기술을 확립하는데 있다. 옥수수전분을 이용한 ASA 유화용 변성전분은 외국에서 소개된 바가 있기는 하지만 사이즈도 발현이 감자전분의 절반 수준으로 효과적이 지 못한 것이 문제점으로 지적된 바 있다. A ASA 유화용 전분으로는 감자전분과 옥수수전분으로 제조된 외국산 기존 제품과 본 연 구를 통해 개발된 옥수수 전분을 이용하였다. 먼저 실험실적으로 최적의 ASA 에멸션의 유 화가 가능하도록 유화조건을 설정하여 유화액의 입도가 1µm 정도가 되도록 하였다. 이들 A ASA 사이즈제를 Hw. Sw-BKP로 조성된 지료에 투입하여 수초한 후 Hercules 사이즈도 측정기를 이용하여 수초지의 사이즈도를 측정하였다. 또 사이정 효과를 극대화시키기 위한 방안을 모색하기 위해 ASA 에말션의 입도, 제타전위, 탁도 등의 평가를 병행 실시하였다. 실험 결과 기존의 방법으로 유화한 경우 수입감자양성전분이 가장 높은 사이즈도를 보였 다. 그러나, 적절한 전분변성법과 유화조건을 개선함으로써 옥수수전분을 이용하여 수입 감 자전분이나 수입 옥수수전분보다 더 우수한 ASA 사이정 효과를 나타내는 양성전분이 개발 될 수 있음을 확인하였다.

• Korean Journal of Food Science and Technology
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• v.20 no.1
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• pp.106-111
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• 1988

Comparative effects of oxidant, reductant treatment and its phosphorylation on qualities and functional properties of defatted rice bran protein isolates were investigated. Effects of oxidant and reductant treatment were that essential amino acid content of protein isolates was high and its color, pepsin digestibility were good. The phosphorylated defatted rice bran protein isolated was taken by incubating sodium trimeta phosphate in aqueous solution at pH 10.5 and $35^{\circ}C$ for 3 hours and its protein score was 55. Functional properties such as solubility, whipping activity and foam stability were much improved. But color, pepsin digestibility, bulk density and fat absorption were not affected by phosphorylation.

• Applied Chemistry for Engineering
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• v.4 no.2
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• pp.284-290
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• 1993

The soap-free emulsion polymerization was carried out for Styrene/Butadiene system with Acrylonitrile as hydrophilic comonomer and KPS as initiator. Under the condition of below 50% conversion, the dependence of Rp on $[AN]^n$ and $[KPS]^n$ was found to be n=1.617-1.050 and n=0.83-0.96 for [AN] and [KPS], respectively. The effect of $[AN]^n$ and $[KPS]^n$ on particle number density (Np) was determined to be n=1.533 and n=0.733, respectively. The highest conversion was obtained under the conditions of pH=5 and ratio of total monomer (g) to water (g)=0.5. The mechanical properties of SBR obtained in this experiment were shown to be inferior to commercial SBR in terms of tensile strength, 300% modulus and elongation. It was found that cure rate of SBR prepared in this experiment was faster than that of commercial SBR.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.3
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• pp.1252-1257
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• 2013

This study was used homomixer as one of the manufacturing method to establish optimal manufacturing condition with magnesium chloride emulsion as coagulant. The more rotational speed of homomixer was fast, the more particle size of magnesium chloride emulsion was minute. The particle size was distributed between 1 and $5{\mu}m$. The more minute particle size of emulsion had an effect on increasing viscosity of emulsion and delay of oil phase separation during storage period, so the quality of magnesium chloride emulsion had correlation with dispersed phase particle size. After all the experiments, when manufacturing magnesium chloride emulsion, it used more than 10,000 rpm of rotational speed of homomixer, it showed the best result as coagulant according to the state of texture and the water separation ratio of soybean curd.

• Applied Chemistry for Engineering
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• v.5 no.1
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• pp.99-104
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• 1994

Nonionic surfactants, monoglyceryl pyroglutamates, have been synthesized in a high yield by esterification of monoglyceride with pyroglutamic acid in the presence of sodium acetate catalyst. Their structures were confirmed by IR and $^1H-NMR$ studies. For these compounds surface active properties including interfacial tension and emulsifying power were measured. The interfacial tensions of their oil solution against water were decreased to 5~9dyne/cm and hydrophobic alkyl chain of monoglyceryl pyroglutamates. The experimental results indicated that emulsifying power of the nonionic surfactant was better in benzene than in soybean oil. Due to the good surface properties, the nonionic sutfactants, monoglyceryl pyroglutamates, are expected to be used as emulsifiers.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.39 no.3
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• pp.225-231
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• 2013

Oil in water nanoemulsion of astaxanthin was prepared by high pressure homogenization. The emulsifying conditions including emulsifier type, concentration and astaxanthin concentration were optimized. Stability of nanoemulsion was measured using zetasizer, freeze-fracture scanning electron microscope (FF-SEM), particle analyzer and colorimeter. The mean diameter of the dispersed particles containing astaxanthin ranged from 160 to 190 nm. Size distribution was unimodal and extended from 40 to 200 nm. The nanoemulsion prepared by glyceryl citrate/lactate/linoleate/oleate had smaller particle size and narrow size distribution. Stable incorporation of astaxanthin in nanoemulsion was performed and checked using high performance liquid chromatography (HPLC), freeze-fracture scanning electron microscope (FF-SEM). Physical stability of nanoemulsion was not significantly changed during storage at both light and thermal condition for a month with zeta potential value of -41 mV meaning stable colloid.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.20 no.1
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• pp.64-81
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• 1994

O/W emulsions with mixed nonionic surfactants(polyoxyethylene(20)sorbitan monostearate/sorbitan sesquioleate), liquid paraffin, water prepared by direct inversion emulisification method and continuous inversion emulsification Method. The one-step, two-step and three-step phase inversion emulsification method were used in experiments. Effect of added water on droplet size of final O/W emulsions which is prepared by phase inversion emulsification method were investigated. In direct inversion emulsification method(two-step emulsification method), fine and homogeneous droplets of OIW emulsions were formed after phase inversion steps i.e. ,W/O - (W/O) If double emulsion - O/W emulsion. In continuous inversion emulsification method(three-step emulsification method), fine and homogeneous O/W emulsion were formed after phase inversion steps i.e., W/O - pseudomicroemulsion - O/W. By latter method, more Fine and homogenuous droplets were formed than former method. 10-10, 8 HLB region of mixed non-ionic surfactants could produce most fine droplets. This HLB region had maximum values of solubilization water and This HLB value of mixed nonionic surfactants produced fine and homogenuous droplets.

• Microbiology and Biotechnology Letters
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• v.16 no.5
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• pp.384-388
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• 1988

A marine bacterium Achromobacter sp. M-1220 was isolated from enrichment culture for emulsification of Bunker-C oil. The bacterium can emulsify approximately 7.5g of Bunker-C oil per liter in sen water medium within 1 drys at 18$^{\circ}C$ and multiply from 8$\times$10$^5$ cells to 9$\times$10$^9$ cells per mi. Optimum pH and salt concentration were pH 7.5 and 3% for the emulsification of Bunker-C oil. Emulsification takes place actively in both high sulfur-containing Bunker-C oil and high sulfur-con-taming crude oil. The amount of emulsification depends on the exogenous addition of nitrogen and phosphate sources. The bacterium can also utilize n-hexndecane, n-paraffin me benzene among the petroleum compounds as a sole carbon source.

• Membrane Journal
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• v.31 no.1
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• pp.52-60
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• 2021

When preparing calcium alginate microspheres using rotating membrane emulsification that rotates SPG (Shirasu porous glass) tubular membrane in the continuous phase, the optimal conditions of rotating membrane emulsification process parameters for producing monodisperse microspheres were determined. We determined the effects of process parameters of rotating membrane emulsification (the rotating speed of membrane module, the transmembrane pressure, the ratio of dispersed phase to continuous phase, the alginate concentration, the emulsifier concentration, the stabilizer concentration, the crosslinking agent concentration, and the membrane pore size) on the mean size and size distribution of alginate microspheres. As a result, the size of the microspheres decreased as the rotating speed of membrane module, the emulsifier concentration, and the crosslinking agent concentration increased among the process parameters of rotating membrane emulsification. On the contrary, as the ratio of dispersed phase to continuous phase, the transmembrane pressure, and the alginate concentration increased, the size of the microspheres increased. In the rotating membrane emulsification using an SPG membrane with a pore size of 3.2 ㎛, it was possible to finally prepare monodisperse alginate microspheres with a particle size of 4.5 ㎛ through the control of process parameters.

• Analytical Science and Technology
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• v.21 no.3
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• pp.159-166
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• 2008

In this study, the characteristics of emulsified fuel and engine emissions were studied. Emulsified fuel which composed of water and diesel was manufactured by using homogenizer and ultrasonic generator. Engine emissions were studied whit engine dinamometer. In emulsified fuel, density and viscosity were increased with increasing water contents, but viscosity was decreased over 60% of water in emulsion fuel. The emulsion type of W/O changed to that of O/W over 60% of water in emulsion fuel. In the results of engine dinamometer test, NOx concentration and smoke density were reduced with increasing water contents in emulsified fuel but reciprocal in the case of THC, CO. Temperature and power were reduced with increasing water contents in emulsion fuel. In conclusion, it seemed that using emulsified fuel for diesel engine was effective for reducing NOx concentration and smoke density.