• Applied Chemistry for Engineering
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• v.9 no.2
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• pp.300-305
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• 1998

Kinetics of termonomer emulsion polymerization during interval II (i.e, after completion of latex particle formation) were studied through pseudo-homopolymerization (PHP) method. Extended Smith-Ewart equation and equation of instantaneous polymer composition are respectively reduced to the corresponding equation for homopolymerization by defining average rate constants. Average number of radicals per particle and instantaneous polymer compositions were respectively predicted by varying termonomer composition within latex particles for systems containing no more than one growing radical per particle. Styrene-Methyl methacrylate-Acrylonitrile (SMA) system was used for model calculation.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.361-362
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• 2008

에폭시 메트릭스에 $10{\pm}5nm$ SiO2 입자를 함량별 (1,3,5,7,9wt%)로 혼합하여 초음파 및 균질기를 이용한 분산을 실시하여 나노콤포지트를 제조하였다. 엉킴이 있는 나노입자를 물리적분산법을 이용하여 분산시킬 수 있었고, 그 결과 여러특성을 연구하였다. 기계적 굴곡강도 특성은 나노입자 충진함량 증가에따라 증가되는 경향을 나타내었고, 무충진 에폭시수지에 비하여 상대적으로 높은 굴곡강도를 나타내었다. 나노입자의 충진함량 증가에따라 절연파괴강도는 1wt%에서 가장 높는 절연파괴강도를 기록하였고 함량증가에 따라 약간 감소되는 경향을 보이고 있다. 이는 여러 연구자의 경향과 대체로 유사함을 알 수 있었다.

• Proceedings of the Korean Society Of Semiconductor Equipment Technology
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• 2004.05a
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• pp.213-216
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• 2004

폐슬러지 실리콘과 흑연의 혼합물에 물을 주입하고 열처리하여, 마이크론 크기의 이산화 실리콘 구형입자를 제조하였다. 제조된 이산화 실리콘의 직경은 균일하고 약 $1.7\mu\textrm{m}$이다. 탄화 실리콘이 이산화 실리콘 구형입자와 함께 존재하였으며, 그 모양은 휘스커와 다면체였다. 폐슬러지 실리콘과 탄소의 혼합물을 고온에서 열처리하면 일산화 실리콘 기체가 생성된다. 물이 산소의 공급원으로 주입되면 일산화 실리콘 기체는 산소와 반응하여 이산화 실리콘 고체가 형성될 수 있다. 실리콘 공급원으로 일산화 실리콘이 반응기 내에 균일하게 분포하고 물을 주입하여 이산화 실리콘이 형성되는 메커니즘은 액상에서 수산화 실리콘 구형입자를 형성하는 메커니즘과 유사하다.

• Journal of the Korean Geotechnical Society
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• v.23 no.11
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• pp.49-58
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• 2007

Numerical experiments using a distinct element code (PFC3D) were carried out for the analysis of grout-material transfer in soil layers and also for the analysis of increase in mechanical strength after permeation grouting. For rapid analysis, up-scaling analysis in length scale was adopted, and the following observations were made from the numerical experiments. Firstly, the relative size of grout material with respect to the in situ soil particles controlled the transfer distance of the grout particles. When the size of grout particle was 0.2 to 0.25 times of the in situ soil particles, clogging of pore spaces among the in situ soil particles occurred, resulting in restricted propagation of grout particles. It was also found that there was a threshold value in the size of grout particle. Below the threshold value, the transfer distance of the grout particle did not increase with the decrease of particle size of the grout material. Secondly, the increase in cohesion and internal friction angle was observed in the numerical specimen with grouting treatment, but not with the untreated specimen.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.21-21
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• 2022

충적하천의 하상과 제방은 흐름에 의해 쉽게 침식되는 사립자들로 구성되어 있다. 흐름이 더욱 강해지면 커다란 입자들도 움직이게 되고 더욱 커지면 결국 모든 입자들이 움직인다. 이렇게 흐름에 의해 하상과 제방을 구성하는 사립자들이 움직이기 시작하는 상태를 한계운동이라 하며, 이때의 흐름조건을 한계조건이라 한다. 한계조건은 이동상 수리학의 시작으로, 이때부터 흐름은 물과 유사의 혼합이라는 이상류가 되어 순수한 물의 흐름보다 더 복잡하게 된다. 개수로는 관수로와 달리 반드시 자유수면이 있으며, 따라서 물과 공기와의 마찰은 상대적으로 매우 작으므로 개수로의 전단응력 분포는 관수로와 달리 근본적으로 비대칭이다. 따라서 전단응력은 수로 바닥이나 측벽에서만 작용하게 된다. 한계조건은 이러한 추상적인 의미에 앞서 바닥이 침식되지 않는 하도나 수로의 설계 등에 기본적인 자료가 된다. 개수로에서 경계면의 전단응력을 힘으로 표시하는 것을 통상 소류력이라 하며, 개수로 경계면에서 전단응력의 분포도; 이른바 단면의 평균 전단응력의 개념을 도입하여 해석하고 설계기준으로 제시되고 있다. 본 연구에서는 자연하천과 유사한 조건의 건설기술연구원 하천실험센터의 급경사수로에서 연구를 진행하였으며, 기존 연구를 바탕으로 제작된 소류력 측정장치를 이용하였다. 하천의 설계나 평가에 적용되는 평균 소류력 개념은 복잡한 난류흐름에서 평가지표로써 대표하기 힘들기 때문에 유사 하천환경의 바닥에서 발생하는 소류력을 직접 측정하고자 연구를 진행하였고, 연구결과를 기존의 소류력 산정방법과 비교하였다. 본 연구에 사용된 장치는 실규모 실험을 위해 제작되었으며, 실규모 적용성 검토를 위해 실험실에서 충분한 검증실험을 거친 후 실규모 실험에 적용하였다.

• The Korean Journal of Rheology
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• v.3 no.2
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• pp.117-123
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• 1991

현탁액에 대한 기본적인 유변학적 특성을 조사하기 위해 입자의 부피분율에 따른 점도의 변화를 측정하였고 현탁액의 Die Swell 현상에 대해 실험적으로 규명하였다. 뉴톤성 특성을 조사하기 위해 입자의 부피 분율에 따른 점도의 변화를 측정하였고 현탁액의 Die Swell 현상에 대해 실험적으로 규명하였다. 뉴톤성 특성을 갖는 Silicone 오일을 현탁 매질 로 사용하였고 미세한 유리 구슬이 filler로써 사용되었다. 현탁액의 점도는 Couette 점도계 와 모세관 점도계를 사용하였다. 관의 입구와 출구에 대한 보정을 위해서 Bagley의 방법을 이용하였으며 중력으로 인한 Swell의 감소효과를 제거하기 위해서 분사 유체와 유사한 밀 도를 지니며 분사 유체와 섞이지 않는 유체를 담은 부력용기가 사용되었다. Die Swell 현상 은 사진을 찍고 이를 정밀한 확대경을 통해 관찰함으로써 수치적으로 값을 얻었다.

• Journal of Korea Water Resources Association
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• v.49 no.10
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• pp.887-901
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• 2016

Cohesive sediments form flocs through the flocculation process. The size and density of floc are variable whereas those of a fine sediment are always assumed to be constant. The settling velocity, one of main factors of sediment transport, is determined by size and density of particle. Therefore, the flocculation process plays an important role in transport of cohesive sediment. It is of great difficulty to directly measure the density of floc in the field due to technical limitation at present. It is a popular approach to estimate the density of floc by applying the fractal theory. The main assumption of fractal theory is the self-similarity. This study aims to examine the applicability of fractal theory to cohesive sediment in small rivers of Korea. Sampling sediment has been conducted in two different basins of Geum river and Yeongsan river. The results of settling experiments using commercial camera show that the sediment in Geum river basin follows the main concept of fractal theory whereas the sediment in Yeongsan river basin does not have a clear relationship between floc size and fractal dimension. It is known from this finding that the fractal theory is not easily applicable under the condition that the cohesive sediment includes the high content of organic matter.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.8 no.8
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• pp.1732-1739
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• 2004

In this paper, we proposed a visualization system with ANN algorithm that traits the motion of particles that move colliding in the water, where we got a great deal of variable information and predicts the distribution of particles according to the flowing of water and the pattern of their precipitation. We adopted ART2 to detect sensitively the collision between particles in this visualzation. Various particles and their mutual collision influencing the force such as buoyancy force, gravitational force, and the pattern of precipitation are considered in this system. Flowing particles whose motion is changed with the environment can be visualized in the system presented here as they are in real water.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.9
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• pp.641-646
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• 2016

Soot particles generated by fossil fuel combustion normally have fractal morphology with aggregates consisting of small spherical particles. Thus, Rayleigh or Mie elastic light scattering theory is not feasible for determining the fractal properties of soot aggregates. This paper describes a detailed process for applying Rayleigh-Debye Gans (RDG) scattering theory to effectively extract the morphological properties of any nano-scale particles. The fractal geometry of soot aggregates produced from an isooctane diffusion flame was observed using ex situ transmission electron microscopy (TEM) after thermophoretic sampling. RDG scattering theory was then used to analyze their fractal morphology, and various properties were calculated, such as the diameter of individual soot particles, number density, and volume fraction. The results show indiscernible changes during the soot growth process, but a distinct decreasing trend was observed in the soot oxidation process. The fractal dimension of the soot aggregates was determined to be around 1.82, which is in good agreement with that produced for other types of fuel. Thus, it can be concluded that the value of the fractal dimension is independent of the fuel type.

• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.790-797
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• 2011

Hydrodynamic similarity was analyzed by employing scaling factor in three phase fluidized beds. The scaling factor was defined based on the holdups of gas, liquid and solid particles and effectivity volumetric flux of fluids between the two kinds of fluidized beds with different column diameter. The column diameter of one was 0.102 m and that of the other was 0.152 m. Filtered compressed air, tap water and glass bead of which density was 2,500 kg/$m^3$ were used as gas, liquid and solid phases, respectively. The individual phase holdups in three phase fluidized beds were determined by means of static pressure drop method. Effects of gas and liquid velocities and particle size on the scaling factors based on the holdups of each phase and effective volumetric flux of fluids were examined. The deviation of gas holdup between the two kinds of three phase fluidized beds decreased with increasing gas or liquid velocity but increased with increasing fluidized particle size. The deviation of liquid holdup between the two fluidized beds decreased with increasing gas or liquid velocity or size of fluidized solid particles. The deviation of solid holdup between the two fluidized beds increased with increasing gas velocity or particle size, however, decreased with increasing liquid velocity. The deviation of effective volumetric flux of fluids between the two fluidized beds decreased with increasing gas velocity or particle size, but increased with increasing liquid velocity. The scaling factor, which was defined in this study, could be effectively used to analyze the hydrodynamic similarity in three phase fluidized processes.