• Applied Chemistry for Engineering
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• v.20 no.1
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• pp.9-14
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• 2009

A zwitterionic surfactant shows not only detergency but also softening effect since it shows characteristics of a nonionic or an anionic surfactant above an isoelectric point, while showing characteristics of a cationic surfactant below an isoelectric point. Therefore, a zwitterionic surfactant can serve as a dual function surfactant by a single molecule through the interconversion of cleaning and softening effects depending on pH of the aqueous solution. In this study, the dual function characteristics of an amine oxide zwitterionic surfactant were investigated by measuring the zeta potential and the isoelectric point using quartz crystal microbalance (QCM). In addition, the physical properties of an amine oxide surfactant such as critical micelle concentration, surface tension, interfacial tension, contact angle and viscosity were measured and phase behavior study was also performed. The isoelectric point of an amine oxide surfactant determined by zeta potential measurement was near 7.35 and that obtained by QCM experiment was about 7.4, where both results were found to be close to the value reported in the literature.

• Journal of Energy Engineering
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• v.23 no.4
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• pp.160-168
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• 2014

In the present study, water vapor adsorption was evaluated at 298.15K for 9 different zeolites having LTA, FAU, CHA, and RHO frameworks, and then effect of framework type, Si/Al molar ratio, and alkali ion type on water up-take was investigated. Zeolites showed water up-takes which were increased in an order of $RHO<CHA{\approx}LTA<FAU$ frameworks. NaY zeolite having FAU framework showed a water up-take of 406 mg/g at p/po=0.5. The up-take was a little larger than that of 13X zeolite with the same framework. Among LTA zeolites, Ca-type 5A zeolite showed the highest water adsorption (282 mg/g at p/po=0.5) which could be explained by the large pore volume. Both CHA zeolite with a Si/Al molar ratio of 2.35 and RHO zeolite with a Si/Al molar ratio of 3.56 showed considerable water up-takes, even though the Si/Al molar ratio was much larger than that of LTA zeolite. In the present study, it is announced that in addition to FAU and LTA zeolites, CHA and RHO zeolites can be a promising dehumidification adsorbent.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.253-256
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• 2002

거제도는 남쪽에서 두 번째로 큰 섬으로써 총면적은 399.96$\textrm{km}^2$이며 총면적의 71.85%가 임야로 이루어져 있고 하천이 짧으며 유역면적이 좁은 관계로 지하수의 함양이 어려우며 해안으로 유출되는 지하수가 상당량이 될 것으로 사료되었다. 따라서 유출지하수의 특성을 연구하여 지하수의 유출가능성이 높은 지역을 찾을 수 있도록 여러 가지 분석을 통하여 알아보았다. 이를 위하여 기본적으로 기온, 강수량 등의 기상자료와 지하수온도, 지하수위등의 수문자료 및 해수표면온도 등의 해양관측자료를 이용하였으며, 해수와 지하수의 온도차가 많은 달의 Lanset 7 ETM+ 인공위성 영상자료와 NOAA 인공영상자료를 이용하여 온도자료를 비교하고, 각개 영사의 열분포도를 분석함으로써 유출지하수의 가능성이 높은 지역을 추출하였다. 추출한 지역에서 인구밀집지역, 공단지역, 기 공급지역을 제외하였으며, 수문지질학 적으로 유리한 지역을 선정하고, 평균해수분포차가 큰 지역을 추출함으로써 이후에 이루어질 현장조사시에 접근이 용이하도록 하였다. 연구결과 거제도 일대의 해안유출지하수 가능지점은 10개소 이상이며 자연적, 사회학석인 여건을 고려한다면 지하수개발가능 지역은 6개 정도로 예상된다. 또한 해수면의 온도와 지하수의 온도가 차이가 클 때는11~13$^{\circ}C$의 분포를 보이고 있어, 이후 이와 같은 연구에 충분히 활용할 수 있을 것이며, 해상도가 높은 자료와 연계하면 보다 정확한 자료의 추출이 가능해 앞으로의 국내에 활용되지 못한 수자원 개발에도 많은 도움이 될 것으로 판단된다.하게도 유기물과의 친화력이 높은 것으로 알려진 Cu 역시 F1과 F2에 대하여 높은 함량을 나타내어 오염원으로부터의 Cu의 확산을 지시하였다. 외국에 비하여, 그동안 국내에서는 사격장 주변의 자연환경변화에 관하여 연구된 결과가 거의 전무하였다. 본 연구 결과는, 이와 유사한 사격장 주변 환경에서의 중금속 분포와 거동 특성에 대하여 종합적인 모니터링(즉, 체계적인 환경지구화학적 조사ㆍ연구)이 시급함을 시사해 주고 있다.할 수 있었다.연구지역을 대상으로 추정한 함양율은 지하수이용에 따른 지하수위하강에 대한 보정을 할 필요가 있으며 지하수이용실태조사를 추가로 하여 그 이용량만큼을 지하수함양량에 더하여야 할것이다.의 특성 등을 고려하여 거기에 맞는 기술들을 복합적으로 또는 단독으로 사용하되 처리방법 채택 시 신중을 기할 것이 요망된다.정시에는 SeaWiFS 위성과 관련된 global algorithms 중에서 490nm와 555nm의 복합밴드를 포함하는 OC2 알고리즘(ocean color chlorophyll 2 algorithm)을 사용하는 것이 OC2 series 및 OC4 알고리즘보다 좋은 추정 값을 도출할 수 있을 것으로 기대된다.환경에서는 5일에서 7월에 주로 이 충체의 유충이 발육되고 전파되는 것으로 추측되었다.러 가지 방법들을 적극 적용하여 금후 검토해볼 필요가 있을 것이다.잡은 전혀 삭과가 형성되지 않았다. 이 결과는 종간 교잡종을 자방친으로 하고 그 자방친의 화분친을 사용할 때만 교잡이 이루어지고 있음을 나타내고 있다. 따라서 여교잡을 통한 종간잡종 품종육성 활용방안을 금후 적극 확대 검토해야 할 것이다하였다.함을 보

• Journal of the Korea Concrete Institute
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• v.29 no.2
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• pp.149-157
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• 2017

As the amount of construction wastes increase, reuse of recycled materials is being considered in research areas. While there are many experimental investigations focusing on development of mortar and concrete using the recycled materials, the studies regarding the fiber-reinforced cement composites (FRCCs) using recycled materials are still limited. In this paper, an experimental attempt has been made to investigate the effect of recycled fine aggregates and fly ash on the mechanical properties of PVA FRCCs. The cement and natural sand were respectively replaced by fly ash and recycled fine aggregates at two content levels, 25% and 50%. Ten types of PVA FRCCs mixes were fabricated and tested to investigate the flexural, compressive and direct tensile behaviors. The test results show that flexural, compressive and direct tensile strength were decreased with increase in fly ash content at all ages. In particular, flexural, compressive and direct tensile strengths of specimens, containing 50% recycled fine aggregates and 50% fly ash, showed the lowest values. The modulus of elasticity of specimens showed similar trend to the 28-day compressive strength. Poisson's ratio was increased with increase in fly ash and recycled fine aggregates content.

• Journal of the Korean Geotechnical Society
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• v.30 no.9
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• pp.19-28
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• 2014

It is necessary to understand the behavior of the soils for the dredging constructions. The objective of this study is to estimate void ratio and density changes of the dredged soils by using the geophysical testing methods. A series of laboratory tests is performed to obtain geotechnical index properties of the specimen, retrieved from the west coastal of Korea. The sedimentation and self-weight consolidation tests are carried out with observing changes of the interfacial height and the elastic wave velocities. The same amounts of the soils are poured into the testing column at intervals of 12 hours until the interheight reaches to a certain level. After the completion of the sedimentatation and self-weight consolidation tests, downward permeability test is performed to assess a tidal influence in the nearshore. The mini resistance cone is penetrated into the specimen to measure the electrical resistivity with depth. All tests are completely finished, the weight of specimens are measured to calculate the void ratio with the depth. Experimental results show that the aspects of the self-weight consolidation are invisible during dredging process because of rapid sedimentation characteristics of ML. However, the elastic wave velocities increase with increasing in the effective stresses. During permeability test, measured permeability and the elastic wave velocities maintain almost identical values. Void ratio based on the elastic wave velocities changes linearly with time during the step dumpings. Void ratio estimated by the electrical resistivity represents the repeatedly layered depositions according to the step-by-step dumpings. Void ratio determined by soil sampling is similar to those of elastic waves and electrical resistivity profiles. This experimental study demonstrates that the geophysical testing methods may be an effective method for evaluating the behavior of dredged soils.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.1
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• pp.760-767
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• 2020

Sustainable growth of hydroelectric power plants is expected in consideration of climate change and energy security. However, hydroelectric power plants always have a risk of water hammer damage, and safety assurance is very important. The water hammer phenomenon commonly occurs during operations such as rapid opening and closing of the valves and pump/turbine shutdown in pipe systems, which is more common in cases of emergency shutdown. In this study, a computational numerical model was developed using the MOC-FDM scheme to reflect the mechanism of water hammer occurrence. The proposed model was implemented in boundary conditions such as reservoir, pipeline, valve, and pump/turbine conditions and then applied to simulate hypothetical case studies. The analysis results of the model were verified using the analysis results at the main points of the pipe systems. The model produced reasonably good performance and was validated by comparison with the results of the SIMSEN package model. The model could be used as an efficient tool for the safety assessment of hydroelectric power plants based on accurate prediction of transient behavior in the operation of hydropower facilities.

• Journal of Korea Water Resources Association
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• v.41 no.9
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• pp.959-967
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• 2008

Disaggregation techniques are widely used to transform observed daily rainfall values into hourly ones, which serve as important inputs for flood forecasting purposes. However, an important limitation with most of the existing disaggregation techniques is that they treat the rainfall process as a realization of a stochastic process, thus raising questions on the lack of connection between the structure of the models on one hand and the underlying physics of the rainfall process on the other. The present study introduces a nonlinear deterministic (and specifically chaotic) framework to study the dynamic characteristics of rainfall distributions across different temporal scales (i.e. weights between scales), and thus the possibility of rainfall disaggregation. Rainfall data from the Seoul station (recorded by the Korea Meteorological Administration) are considered for the present investigation, and weights between only successively doubled resolutions (i.e., 24-hr to 12-hr, 12-hr to 6-hr, 6-hr to 3-hr) are analyzed. The correlation dimension method is employed to investigate the presence of chaotic behavior in the time series of weights, and a local approximation technique is employed for rainfall disaggregation. The results indicate the presence of chaotic behavior in the dynamics of weights between the successively doubled scales studied. The modeled (disaggregated) rainfall values are found to be in good agreement with the observed ones in their overall matching (e.g. correlation coefficient and low mean square error). While the general trend (rainfall amount and time of occurrence) is clearly captured, an underestimation of the maximum values are found.

• Journal of Korea Water Resources Association
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• v.41 no.8
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• pp.773-784
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• 2008

The present study was carried out to examine flow properties in linear drainage channels such as road surface drainage facilities. The finite difference formulation for the varied flow analysis was solved for flow profiles in the channels. Starting the first step at the control section, the Newton-Raphson method was applied for producing numerical solutions of the equation. We considered two types of linear drainage channels, a channel with one outlet at downstream end and a channel with two outlets at both ends. Moreover, the flow analysis for various channel slopes was performed. However, we considered channels with the two outlets of slopes satisfying the condition that the both ends are the control section. The maximum of those slopes was decided from the relation between the channel slope and the location of control section. The flow of a channel with one outlet was calculated upward and downward from the control section existing in channel or upward from the control section at downstream end. The flow of a channel with two outlets at both ends were calculated for upstream and downstream channel segments divided by the water dividend, respectively and the flow analysis was completed when the water depth at the water dividend calculated from upstream end was equal to that calculated from downstream end. If the slope was larger than the critical slope, the channel with two outlets was likely to behave like the channel with one outlet. The maximum water depth was investigated and compared with that calculated additionally from the uniform flow analysis. The uniform flow analysis was likely to lead a excessive design of a drainage channel with mild slope.

• Proceedings of the Korea Water Resources Association Conference
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• 2011.05a
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• pp.29-29
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• 2011

SWAT (Soil and Water Assessment Tool) 모형은 물리적 기반의 준분포형 강우-유출 모형으로서, 대규모의 복잡한 유역에서 장기간에 걸친 다양한 종류의 토양과 토지이용 및 토지관리 상태에 따른 유출과 유사 및 오염물질의 거동에 대한 토지관리 방법의 영향을 예측이 가능하여, 수자원 관리 계획 및 유역관리를 위한 의사결정 지원 등 그 적용 범위가 매우 광범위하다. 이러한 모형의 적용성 검증을 위해서는 매개변수 민감도 분석 및 검 보정, 예측 불확실성 분석을 필요로 한다. 최근 수문 모델의 불확실성을 분석하기 위한 다양한 기법들이 개발 되었는데, 본 연구는 충주댐 유역(6,581.1 m)을 대상으로 유역출구점의 실측 일 유출량 자료(1998~2003)를 바탕으로 SWAT 모형의 유출관련 매개변수(총 18개)에 대한 불확실성 분석을 실시하였다. 이때 사용된 분석 기법으로는 SUFI2 (Sequential Uncertainty FItting algorithm 2), GLUE (Generalized Likelihood Uncertainty Estimation), ParaSol (Parameter Solution)등을 적용 하였다. 이러한 기법은 모두 SWAT-CUP (SWAT-Calibration Uncertainty Program, Abbaspour, 2007) 모형에 탑재되어있으며, 모형의 결과로써 검 보정, 매개변수의 민감도 분석, 각종 목적 함수 및 불확실성의 범위 등이 자동으로 산출 되므로 모형의 사용자가 불확실성 평가 기법의 분석 및 비교를 손쉽게 할 수 있다. 그 결과 대표적인 목적 함수인 결정 계수( $^2$)와 NSE (Nash-Sutcliffe Model Efficiency)는 모두 0.65에서 0.92사이의 값을 나타내어 대체적으로 모의가 잘 이루어졌음을 알 수 있었다. 그러나 불확실성의 범위를 나타내는 지표인 p-factor 및 r-factor에서는 평가 기법 별로 그 차이가 확연하게 드러났다. 여기서 p-factor는 불확실성 범위에 실측치가 포함되는 비율이며, r-factor는 불확실성의 상대적인 범위로 각각 1과 0에 가까울수록 모의 기법의 성능이 우수함을 의미한다. 세 가지 알고리듬 중에서 SUFI2의 p-factor가 약 0.51로 가장 높게 나타났으며, ParaSol의 r-factor가 0.00으로 가장 작게 나타났다. 여기서 p-factor는 불확실성 범위에 실측치가 포함되는 비율이며, r-factor는 불확실성의 상대적인 범위를 의미한다. 본 연구의 결과는 SWAT 모형을 이용한 수문모델링에서 수문분석에 따른 예측결과의 불확실성을 정량적으로 평가함으로서, 모형의 적용성 평가 및 모의결과의 신뢰성 확보에 근거자료로 활용이 가능할 것으로 판단된다.

• Journal of the Mineralogical Society of Korea
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• v.19 no.4 s.50
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• pp.239-246
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• 2006

KAERI Underground Research Tunnel (KURT) was recently constructed through the site investigation from the yea. of 2003 at KAERI site, Dukjin-dong, Yuseong-gu, Daejeon city. The geo-logic setting of the site has been slightly metamorphosed. There are small fractures developed in the rock and several kinds of secondary filling minerals exist in the fractures. We examined mineralogical characteristics of fracture-filling calcite, which is not only largely distributed, but also can significantly affect the radionuclides migration. The calcite is found along fractures like other secondary minerals, forming thick veins in part. Most calcite-filled fractures contain quartz, iron oxides, and dolomite as minor minerals. The calcite crystals show an characteristic appearance with an uniformly oriented growth, coated with goethite on the edge and the etch-pit sites of their surface. Some calcite crystals have been newly formed by the precipitation of elements dissolved from the tunnel shotcrete wall, and their morphology changed according to the chemistry and flow of groundwater. The calcite can modify the groundwater chemistry and significantly affect the sorption behavior of radionuclides. The characteristic crystal structure and surface morphology of the calcite examined in the KURT site will be used as important basic data for the radionuclide migration experiment in the future.