• Journal of the Korean Applied Science and Technology
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• v.32 no.3
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• pp.386-393
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• 2015

The rheological properties of complex materials such as colloid dispersion show complicated non-Newtonian flow phenomena when they are subjected to shear flow. These flow properties are controlled by the characteristics of flow units and the interactions among the flow segments. The rheological parameters of relaxation time $({\beta}_2)_0$, structure factor $C_2$ and shear modulus $X_2/{\alpha}_2$ for various thixotropic flow curves was obtained by applying thixotropic equation to flow curves. The variations of rheological parameters are directly related to non-Newtonian flows, viscosities and activation energies of flow segments.

• Journal of the Korean Applied Science and Technology
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• v.36 no.4
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• pp.1050-1059
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• 2019

The self diffusion, hole volume, and flow thermodynamic parameters of polyamide fibers were calculated from rheological parameters and crystallite size in order to study of flow segments in amorphous region. The stress relaxation of polyamide filament fibers were carried out in air and various solvents at various temperatures using the tensile tester with the solvent chamber. The rheological parameters were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model. It was observed that the rheological parameters of these polyamide filament fibers are directly related to the relaxation spectra, self diffusion, viscosities, and activation energies of flow segments.

• Journal of the Korean Chemical Society
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• v.50 no.6
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• pp.447-453
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• 2006

of synthetic conditions and water content on rheological properties of polyacrylamide hydrogels were studied. The non-Newtonian flow curves of polyacrylamide hydrogels were obtained by using a cone-plate rheometer. The rheological parameters were obtained by applying non-Newtonian equation to the flow curves for polyacrylamide hydrogels. The polyacrylamide hydrogels are shear thinning under increasing shear rate modes which result in thixotropic behavior. These flow properties are controlled by the characteristics of flow units and the interaction among the flow segments.

• Elastomers and Composites
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• v.47 no.3
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• pp.223-230
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• 2012

The rheological parameters of poly(methyl acrylate)-poly(acrylonitrile) copolymers were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Eyring-Halsey non-Newtonian model. The experimentals of stress relaxation were carried out using the tensile tester with the solvent chamber. The determination of rheological parameters was performed from computer calculation. It was observed that the rheological parameters of these copolymer samples are directly related to the self diffusions and viscosities and activation energies of flow segments.

• The Korean Journal of Rheology
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• v.7 no.1
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• pp.28-34
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• 1995

고체가 아닌 계인 마요네즈에 대해 Couette형 점도계를 사용하여 일정한 전단속도에 서 시간과 더불어 전단응력이 감소하는 응력완화 곡선을 온도 2$0^{\circ}C$, $25^{\circ}C$, 3$0^{\circ}C$, 34$^{\circ}C$, 4$0^{\circ}C$ 에서 얻었다 이현상을 설명하기 위하여 구조가 형성되는 flow unit 2와 구조가파괴되는 flow unit 3에 대한 fraction (X2, X3)사이의 평형을 생각하고 X2 와 X3 에 해당하는 항에 실 험적 조건인 s=p(t0+t)의 관계를 적용하여 다음과 같은 응력완화에 관한 식을 구하고 이식을 실험결과에 적용하여 유동파라메타를 구하였으며 그 파라메타중의 평형상수 k와 실험 온도 를 이용하여 열역학 파라메타를 구하였다.

• Elastomers and Composites
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• v.44 no.3
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• pp.323-328
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• 2009

The rheological properties of complex materials such as polymer melts show complicated non-Newtonian flow phenomena when they are subjected to shear flow. These flow properties are controlled by the characteristics of flow units and the interactions among the flow segments. The non-Newtonian flow curves of poly(vinyl alcohol) hydrogel were obtained in various concentrations and temperatures by using a cone-plate rheometer. By applying non-Newtonian flow equation to the flow curves for PVA hydrogel samples, the rheological parameters were obtained. The PVA hydrogel samples are shear thinning under increasing shear rate modes which result in thixotropic behavior.

• Journal of the Korean Chemical Society
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• v.50 no.3
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• pp.196-202
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• 2006

The self diffusion distributions of viscoelastic molten polyurethanes were determined from the relationship between the relaxation spectra and the distribution of self diffusion. The relaxation spectra of ester, PCL and PCL dyed type molten polyurethanes were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model(REM model) from computer calculation. The experiments were carried out at various temperatures using the physica rheometer with the temperature controller. The self diffusion and hole distance of amorphous region of polyurethane samples were investigated by experiments of stress relaxation. The diffusion coefficients and hole volumes were calculated from rheological parameters and crystallite size in order to study the diffusion of flow segments in amorphous region. It was observed that the relaxation spectra and self diffusions of these polymer samples are directly related to the distribution of molecular weights, viscosities, hole volumes and activation energies of flow segments.

• Elastomers and Composites
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• v.44 no.4
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• pp.423-428
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• 2009

The non-Newtonian flow curves of polyurethane melts were obtained by using a Physica cone-plate rheometer at various temperatures. The rheological parameters were obtained by applying non-Newtonian flow equation to the flow curves for polyurethane samples. When the polyurethane samples are under increasing-decreasing shear rate modes, the hysteresis loop and thixotropic behavior were shown. Polyurethane melts behave as strong gels when they are subjected to shear flow, but when the applied stress surpasses the yield stress, they exhibit non-linear viscoelasticity. Upon decreasing shear rate, its shear stress remains smaller than the values measured in the increasing shear rate mode, because of broken of its structure.

• Journal of the Korean Society of Mechanical Technology
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• v.13 no.2
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• pp.85-91
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• 2011

Computational results with pseudoplastic fluid flows for fully developed non-Newtonian laminar flows have been obtained. Those consist of the product of friction factor and Modified Reynolds number and Nusselt numbers with respect to the shear rate parameter in an annular pipe. The numerical results of the product of friction factor and Reynolds numbers and the Nusselt numbers for both Newtonian region and the power law region were compared with previously published asymptotic results, respectively. In the present calculations, the product of friction factor and Newtonian Reynolds numbers for pseudoplastic fluid at power law region in annular pipe is 180% less than that for Newtonian fluid. For power law fluids with different power law flow indices, the difference of the product of friction factor and power law Reynolds number between previous and the present results at the power law region is within 0.20%. The solutions also show the effect of the shear rate parameter on the Nusselt number and about 11% increase of Nusselt number at the power region.