• Korean Journal of Heritage: History & Science
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• v.35
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• pp.160-184
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• 2002

The composition analysis of mural pigments at Daeungjeon Hall of Bongjeongsa Temple(Treasure No. 55) and ancient tomb with mural pigments in Goadong(Historic site No. 165) were carried out by XRF and MXRD. The analytical result showed that red pigments were Red Lead($Pb_3O_4$), Cinnabar(HgS) at Daeungjeon Hall of Bongjeongsa Temple and Cinnabar(HgS) in Goadong. The main composition identified in white pigments were Lead Carbonate Hydroxide[$PbCO_3{\cdot}Pb(OH)_2$]. Green pigments were basic copper chloride[Paratacamite $CuCl{\cdot}Cu(OH)_3$], celadonite[$K(Mg,Fe,Al)_2(Si, Al)_4O_{10}(OH)_2$] at Daeungjeon Hall of Bongjeongsa Temple and were basic copper chloride or basic copper carbonate in Goadong. Therefore it proved that mural pigments painted in use the mineral materials.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.205-208
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• 2005

최근 열선 화학 기상 증착법(HWCVD)은 낮은 온도에서 TFT용 Poly Si 중착을 할 수 있다는 점과 실리콘 박막을 빠른 속도로 증착할 수 있다는 점에서 각광을 받고 있다. 본 연구에서는 HWCVD를 이용하여 태양전지를 제조하고 그 특성을 평가하였다. 조건에 따른 실리콘 박막의 특성 변화를 알기 위해 corning glass 및 실리콘 wafer에 다양한 조건에서 단위 박막(intrinsic layer)을 증착하였고 이 결과를 바탕으로 p/i/n 구조의 태양전지를 제조하였다. Ta 열선 온도는 1700-2000도였고 가스 원료인 $SiH_4$와 수소의 비율을 조절하면서 그 영향을 관찰하였다. 태양전지의 경우 p충과 n충은 PECVD로 증착하였으며 단위박막 및 태양전지 i충 증착시 기판과 열선간의 거리는 7cm, 기판 온도는 $200^{\circ}C$와 $250^{\circ}C$로 고정하였고 작업압력은 30mTorr였다. 단위 박막 특성 평가를 위해 암/광 전도도, SEM, Raman Scattering, FT-IR등을 사용하였으며 태양전지 특성 평가를 위해 I-V 및 Spectral response를 측정하였다. 열선 온도가 증가함에 따라 증착속도 및 결정화 분율은 증가하였다. 특히 비정질에서 결정질로 전이되는 구간은 매우 좁았으며 여러 분석 방법에서 일치되는 결과를 보였다. $SiH_4$ 유량이 늘어날수록 비정질이 결정질로 바뀌는 열선 온도가 증가하였으며 기판 온도가 낮을 경우 또한 결정으로 바뀌는 열선 온도가 증가하였다. 태양전지의 경우 열선 온도가 증가함에 따라 $V_{oc}$ 및 W가 낮아졌으며 $J_{sc}$, 는 증가하는 경향을 보였으며 결정질 비율이 증가하는 것을 관찰할 수 있었다. 이러한 경향은 quantum efficiency 결과에서도 확인할 수 있었다.용을 반복하면서 석재 내부와 외부의 암석 및 결정에 균열과 미세열극 등이 생성되어 석재 자체의 구조적 안정성에 영향을 주고 있다. 따라서 감은사지 석탑은 지리적 환경 차이로 인해 일반적인 환경의 석조물들과는 다른 형태의 풍화양상을 보이고 있어서 풍화양상 및 풍화형태에 대한 정확한 연구와 이해를 바탕으로 보존대책이 마련되어야 한다.되었다. 이런 모든 시편들을 각 탈염방법에 따라 탈염처리한 후 XRD와 SEM-EDS으로 분석한 결과 인철광과 침철광은 어떠한 변화도 보이지 않았고, 다만 적금광으로 동정된 시편만이 잔존하지 않았다. 철기 제작별 $Cl^-$ 이온 추출량과 탈염효과에 대한 비교 실험은 이온 크로마토그래피 분석 결과와 마찬가지로 단조 철제유물이 주조 철제보다 $Cl^-$ 이온을 많이 가지고 있었으며, 탈염 처리 후에는 $Cl^-$ 이온은 전혀 발견되지 않았다. 이상의 결과 $K_2CO_3$와 Sodium 용액은 탈염처리에서 가장 적합한 탈염처리 용액으로 알수가 있었으며 특히 어떠한 탈염 용액으로 유물을 처리한다 해도 철제유물에 생성된 부식물은 제거되지 않는다는 것을 알게 되었다. 따라서 보존처리자는 유물 표면의 부식 상태만을 보고 처리하기 보다는 철기제작물로 고려하여 처리하는 것이 필요하다. 또한 금속에 부식을 야기시키는 $Cl^-$ 이온과 부식물을 완전하게 제거하여 탈염처리를 하는 것이 유물 부식을 최대한 지연시킬 수 있는 것이라 생각된다.TEX>$88\%$)였다.(P=0.063). 결론: 본 연구에서는 MTHFR C/T & T/T 유전자 다형성이 위암의 발생과 그 위치에 대해 관련이 있는 것으로 여겨지고, 흡연력, 음주력과는 관련이 없는 것으로 여겨진다.험이 커지는 경향을 보였으나, 나이 및 병기, 종양의 크기, MD-BED $Gy_{10}$ 등의 예후 인자를 보정한 다변

• Korean Journal of Heritage: History & Science
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• v.56 no.3
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• pp.118-135
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• 2023

Hanging boards of the Joseon royal court are hung on buildings related to the royal family, such as palaces and Jongmyo Shrine, to show the hierarchy and character of the building. In addition, the manufacturing method and materials are recorded in the royal protocols of the Joseon Dynasty, so it is an important material for studying the manufacturing method and material changes at that time. However, the hanging boards were restored several times due to fire or war, and it is presumed that there is a change in the original form and material of the hanging boards. In particular, many hanging boards of the Joseon royal court were written with calligraphy by kings, so there are many forms consisting of gold letters on a black background. This study tried to analyze the pigments remaining in the letters of 44 of the Joseon royal hanging boards, which are presumed to be gold letters, and to find out the changes in the hanging board production method and materials by referring to the analysis results. The letters of the hanging boards studied were classified according to the current state of the gold pigment and the detected components. As a result of the analysis of character pigments, 24 embossing techniques and 5 intaglio techniques were mainly detected with gold (Au), but 15 embossing techniques were detected with brass (Cu, Zn). Only blue-green substances, not gold pigments, remain in some of the hanging boards in which brass components were detected. A reproduction experiment was conducted because the pigments of the brass component were not recorded in the literature and were not currently used as Dancheong pigments. In the reproduction experiment, it was difficult to confirm the application and use of brass pigments due to the limitations of materials, but it is judged that research on the timing and method of using brass pigments is needed in the future.

• 보존과학연구
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• s.35
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• pp.25-44
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• 2014

In this study, measured annual year and seasonal concentrations of VOCs by Active type and Passive type using the measurement and analysis method in the exhibition hall and outdoor. It was compared with the correlation between the methods according the comparison of methods to measured concentrations. As a results, the annual average concentrations of TVOC in exhibition room($906.5{\mu}g/m^3$) was greater than for most of the study period, more than 1.8 times the standard in the Ministry of Environment. ${\Sigma}VOCs$ concentration of exhibition room by Active type was higher than Passive type. Some VOCs was decreased with the lapse of time a temporary increase tendencies was. The annual average I/O ratio of TVOC was 9.0, ${\Sigma}VOCs$ was confirmed to occur in a large amount inside the exhibition hall ${\Sigma}VOCs$ was studied to 34.0. Correlation coefficient of ${\Sigma}VOCs$ was 0.367. Toluene was 0.567 that the survey was the largest analysis to the relationship between the two methods.

• Journal of the Korean Society of Costume
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• v.49
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• pp.49-63
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• 1999

This research utilized the Energy Dispersive X-ray Spectroscopy(EDS) and the Inductively Coupled Plasma Mass Spectrometry in the analysis of chemical elements present among the textiles exhumed from Kupori Hwasung-kun Kyunggi-do. The two research objectives were: first to examine the elements present and their percent presence in Kupori samples: second to investigate whether the elements are part of mordant substances which could have been used when dyeing the KUpori textiles in the past. To meet such research purposes standard silk fabric was dyed with Sophorajaponica using alum and iron mordants. For alum mordant unpurified general alum and potassium aluminum sulfate(AlK(SO4)2). iron sulfate(FeSO4·7H2O) were used, From the results of EDS and ICP-Mass analysis the following conclusions were drawn. 1 According to the EDS analysis 9 elements Ca, S, Al, Si, K, Fe, P, Mg and Na were detected. 2. ICP-Mass result of the mordant chemicas showed high amount of A, Al and k present in alum mordants and S and Fe present in iron mordants. 3. Comparison of the ICP-Mass results of the mordant chemicals and those of the standard dyed samples suggested that the amount presence of Al and Fe is a strong indication of the usage of alum and iron mordants respecticely in an unknown dyed textile. 4, In the washed Kupori textiles Fe showed a relatively higher rate of presence in the samples Therefore it can be conjectured that those Kupori textiles were dyed with iron mordant based on the result of the above number 3. 5. It is probable that the other elements detected from the Kupori samples were incorporated into the textiles as part of the soil debris produced from the degradation of the dead within the coffin or the earth debris. They can also be part of the inorganic compounds inherent in the silk textiles themselves before dyed. 6. Among the elements it is likely that Ca which showed a high degree of presence among the unwashed samples was part of the inorganic compound inferent in the silk textiles.

• Journal of Conservation Science
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• v.30 no.3
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• pp.277-286
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• 2014

This is the scientific analysis of lacquered pottery cup and lacquered pottery plate excavated from Pyongyang Tomb No.53 at Namjeong-ri, Nangnang Tomb, which were under conservation treatment as a part of the Project of Unregistered Artefacts Uncovered in the Japanese Colonial Era. It is very rare to have a lacquered pottery cup and plate, lying on a lacquered pottery table, as a set of grave goods. In particular, they are not wooden but pottery items. Of that on this analysis Lacquered pottery cup and lacquered pottery plate use red pigment and black pigment mixed with lacquer. Analysis results of red pigment is cinnabar(HgS) and black pigment is estimated carbon-based pigment.

• Conservation Science in Museum
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• v.18
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• pp.77-92
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• 2017

This study is based on a scientific analysis of the production method of the wooden seated Bodhisattva statue from Gwaneumsa Temple in Wando, which is currently housed at Chonnam National University Museum. The purpose was to investigate the characteristics of the statue's production through an X-ray inspection of the wooden timbers that make up its base material, a composition analysis of the surface layers, and microscopic observation. The votive prayers found together with the statue allowed the precise dating of the artifact to the sixteenth century, during the Joseon Dynasty. The X-ray transmission identified the statue as being made using the "ilmokjo"(一木造) technique, which means that the entirety of the statue excluding the right hand was produced using a single block of wood. The specimen analysis of the naturally exfoliated surface layer revealed that the current surface was coated with brass to restore the original gilt layer. These research findings added an interesting case to the existing related research and reaffirmed the academic value of this statue.

• Conservation Science in Museum
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• v.29
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• pp.133-152
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• 2023

This study references preceding studies to examine the history of paint application techniques using various paints in the past, with the aim to contribute to the long-term preservation of large military cultural heritage assets situated outdoors. To this end, the study compared the findings of preceding research with the findings of an analysis conducted on a H-13 helicopter housed at the War Memorial of Korea. Upon collecting and analyzing samples from three grounded WWII aircraft from above-ground by preceding studies, it was confirmed from each sample that the various chemical properties of chrome ensured the effectiveness of the protective coating. The compound was first tested as a corrosion-inhibiting pigment in the early 1940s and proved its excellent moisture-resistant properties over the course of 80 years, despite the deterioration of the paint layer and long-term exposure to the natural environment. For this reason, it has been widely used as a corrosion inhibitor for aluminum alloys in the aviation industry. In other word, the most widely-used material for preventing corrosion was an organic primer containing chromate. In this study, based on the paint analysis of a H-13 helicopter operated in the Korean War, it was shown that the second layer, consisting of the primer, contains chromium oxide (Cr₂O₃). In addition, it was estimated that red lead tetraoxide (Pb₃O₄) was used for the vehicle. Analysis results and data from previous studies can help to confirm the continued effectiveness of corrosion prevention function provided by chromate. Meanwhile, the result of infrared spectroscopy analysis confirmed the use of alkyd resin. In the future, comparisons with a more diverse range of artifacts will allow the identification of changes in the manufacturing technology of paints used to protect alloys from corrosion.

• Journal of the Korean Chemical Society
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• v.55 no.6
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• pp.1074-1077
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• 2011

• Proceedings of the KAIS Fall Conference
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• 2007.11a
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• pp.378-381
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• 2007

박물관은 과거의 단순한 유물의 수장과 전시라고 하는 전통적 개념에 더하여 일반 대중에게 휴식과 교양을 제공하는 문화시설로서 현대인의 심리를 충족시키는 사회교육기관으로까지 그 기능이 확대 되고 있다. 이러한 요구에 비하여 현존하는 지역 박물관은 기능을 충족하기 어려운 현실이고 이를 해결할 방안이 모색되어야 할 시점이다. 따라서 본 연구는 이러한 기존 박물관의 현황을 조사, 분석하여 문제점을 파악하고, 이를 바탕으로 기존 박물관의 건축 디자인적 개선점을 제안하고자 한다.