• Journal of Korean Society of Environmental Engineers
• /
• v.22 no.10
• /
• pp.1881-1891
• /
• 2000

Cenosphere particles of different fly ash formed at the pulverized coal power plant were hollow sphere or filled with small particles inside solid particles. And size was relatively larger than other fly ash particles as well as specific gravity was small to suspend in the water. In this paper, it was demonstrated to contain a variety of morphological particle type, and the physical and chemical properties related to the cenosphere and fly ash particles. Furthermore it was estimated the possibility to reuse the cenosphere particles on the base of cenosphere properties. Cenosphere formation resulted from melting of mineral inclusion in coal, and then gas generation inside the molten droplet. As the aluminosilicate particle was progressively heated, a molten surface layer developed around the solid core. Further heating leaded to cause the formation of fine particles at the core. The mass median diameter(MMD) of cenosphere particles was $123.11{\mu}m$ and the range of size distribution was $100{\sim}200{\mu}m$ with single modal. It was represented that specific density was $0.67g/cm^3$ fineness was $1135g/cm^3$. The chemical components of cenosphere were similar to other fly ash including $SiO_2$, $Al_2O_3$, but the amount of the chemical component was different respectively. In the case of fly ash, $SiO_2$ concentration was 54.75%, and $Al_2O_3$ concentration was 21.96%, so this two components was found in 76.71% of the total concentration. But in the case of cenosphere, it was represented that $SiO_2$ concentration was 59.17% and $Al_2O_3$ concentration was 30.16%, so this two components was found in 89.33% of the total concentration. Glassy component formed by the aluminosilicate was high in the cenosphere, so that it was suitable to use insulating heat material.

• Journal of the Mineralogical Society of Korea
• /
• v.22 no.4
• /
• pp.307-312
• /
• 2009

Motukoreaite and quintinite-3T, Mg-Al layered double hydroxides, were found in the Sinyangri Formation of Jeju Island. They fill the pores of basaltic volcaniclastic sediments in globular and botryoidal aggregates of fine platy particles. Globular aggregates of quintinite-3T were crusted with the parallel overgrowth of motukoreaite plates. X-ray diffraction data and chemical composition are consistent with those reported in literature, while the Mg/Al ratio of motukoreaite is higher. Structural formula of motukoreaite and quintinite-3T derived from electron microprobe analysis are $Na_{1.6}Ca_{0.1}Mg_{40.7}Al_{20.7}Si_{0.9}(CO_3)_{13.6}(SO_4)_{7.4}(OH)_{108}56H_2O$, and $Mg_{3.7}Al_{1.9}Si_{0.2}(OH)_{12}(CO_3)_{0.8}(SO_4)_{0.2}3H_2O$, respectively. Motukoreaite and quintinite-3T were formed by reaction between seawater and basaltic glass, and contributed to the cementation and lithification of the volcaniclastic sediments.

• Journal of the Korean Ceramic Society
• /
• v.35 no.2
• /
• pp.151-162
• /
• 1998

ZnO-BaO-$SiO_2-Al_2O_3$계 유리 및 결정화 유리 시편들을 제조하여 평판형 고체산화물 연료전지 봉착재로의 이용가능성을 조사하였다 구성층과 일치되는 열팽창 계수 및 화학적 안정성을 봉착재로의 적용에 있어 판단 기준으로 정하였다 실험된 다양한 조성의 유리 및 결정화 유리 시편들중 7.79ZnO-58.52BaO-$28.69SiO_2-5Al_2O_3$(ZBS3-A5) 결정화 유리의 측정된 열팽창 계수값은 $11.02\times10^{-6/^{\circ}C}$로써 YSZ 및 LSC의 평균 열팽창 계수 값과의 차이가 $0.07\timestimes10^{-6/^{\circ}C}$로 매우 작아 봉착시 열응력 발생의 최소화를 기대할수 있었다 이런 ZBS3-A5+LSC 접합 couple의 경우는 ZnCr2O4 의 dis-crete한 입자가 결정화 유리 부위에 형성되었고 역시 시간의 증가에 따라 이러한 입자의 성장은 없었다 특히 ZBS3-A5 구성 성분인 Ba, Zn, Sil 그리고 Al의 YSZ 및 LSC로의 확산은 없어 봉착후에 YSZ 및 LSC의 전기적 특성에 악영향을 미치지 않으리라 판단되었다.

• Economic and Environmental Geology
• /
• v.36 no.3
• /
• pp.225-232
• /
• 2003

Three piston cores. obtained from the northwestern Ulleung Basin of the East Sea, are analyzed to study the tephrostratigraphy of the late Quaternary core sediments and to reveal the comparative characteristics of the tephra layers. The cores consist mainly of the muddy sediments that are partly interbedded with lapilli tephra and ash layers. The muds are further divided into hemipelagic and turbiditic mud facies. The hemipelagic facies is dominated by bioturbated mud and crudely laminated mud, whereas the turbiditic facies includes mainly thinly laminated mud and homogeneous mud, and often alternates with non-turbiditic muds. According to microscopic observation and EDX analysis, three tephra layers of the Ulleung-Oki (U-Oki; ca. 9.3 ka), Aira-Tanzawa (AT: ca. 22~24.7 ka) and Ulleung-Yamato (U-Ym; ca. 25~33 ka) are identified in the study cores. Among these, the U-Oki and U-Ym layers, originating from the Ulleung Island, consist mainly of massive-type glass shards with alkali feldspar. Both of the tephra layers contain a lower content of SiO$_2$ (57~66.5 wt.%) and a higher content of Na$_2$O+K$_2$O (11~16 wt.%) than the AT layer (SiO$_2$=75~78.5 wt.%, Na$_2$O+K$_2$O=6.5~9 wt.%) that consists of typical plane-type and/or bubble-wall glass grains. Compared with that of the U-Ym layer, a sedimentary facies of the U-Oki layer is very thick and contains three stratigraphic units, probably due to relatively large and different supplies of pyroclastic sediments. Thus, the eruption of Ulleung Volcano (ca. 7,300 B.C.) is thought to have had a more powerful effect on depositional environment than the U-Ym eruption.

• Journal of Bio-Environment Control
• /
• v.13 no.2
• /
• pp.81-89
• /
• 2004

This study was conducted in a commercial plug glasshouse in Sacheon to examine the possibility of producing tomato plug seedlings using various growing media containing cellular glass foam (CGF)and carbonized chestnut woodchips (CCW) as medium components. Plug seedlings of 'Seogun' tomato were grown in media containing 50% CCW＋50% peatmoss, 33% CGF＋67% peatmoss, and 50% peatmoss＋50% granular rockwool. A commercial plug medium (Tosilee) was used as the control. All seeds were sown in 200 cell plug trays on November 28, 2001. Seedling growth was measured at 31 days after sowing. Each treatment showed a similar growth result as compared to the control. Plant height, root grade, fresh weight, and air space and bulk density of the medium were significantly greater in the 33% CGF＋67% peatmoss treatment than those in the other media. However, growth was slightly suppressed in the 50% CCW＋50% peatmoss. pH and EC of the media were the highest in the control treatment, although no toxicity symptoms had been observed. The results suggest that perlite can be replaced with a new material such as CGF in the commercial scale production of plug seedlings of 'Seogun' tomato.

• Journal of the Korean Ceramic Society
• /
• v.41 no.12 s.271
• /
• pp.939-945
• /
• 2004

Glasses of $SiO_2-B_{2}O_3-Al_{2}O_3-CaO-La_{2}O_3$ with various amounts of $La_{2}O_3$ were infiltrated into a porous alumina to make an alumina-glass composite. The infiltration characterization and bending strength of the composite were examined in terms of glass composition. $La_{2}O_3$ in the glass decreased the high temperature viscosity and this enhanced the wetting behaviour of this glass to alumina, and made glass infiltration easier. The infiltrated glass dissolved the alumina skeleton, and $Al_{2}O_3$ component in the glass melt reprecipitated on the alumina. The grain growth occurred to a specific crystal direction. The glass containing $20mole\%$ of $La_{2}O_3$ was crystallized after infiltration, and this enhanced the bending strength of the composite.

• Resources Recycling
• /
• v.28 no.6
• /
• pp.96-105
• /
• 2019

Automobile shredder residue (ASR) is the final waste produced when end-of-life vehicles (ELVs) are shredded. ASR can be separated using mineral-processing operations such as comminution, air classification, magnetic separation, and/or electrostatic separation. In this work, trajectory analyses of conductors (copper) and non-conductors (glass) in the ASR have been carried out using induction electrostatic separator for predicting or improving the ASR-separation efficiency. From results of trajectory analysis for conductors, the trajectories of copper wire by observation versus simulation for coarse particles of 0.5 and 0.25 mm showed consistent congruity. The observed 0.06 mm fine-particles trajectory was deflected toward the (-) attractive electrode owing to the charge-density effects due to the particle characteristics and relative humidity. In the case of non-conductors, the actual trajectory of dielectric glass deflected toward the (-) electrode, showing characteristics similar to those of conductive particles. The analyses of stereoscopic microscope and SEM & EDS found heterologous materials (fine ferrous particles and conductive organics) on the glass surface. This demonstrates the glass decreasing separation efficiency for non-ferrous metals during electrostatic separation for the recycling of ASR. Future work will require a pretreatment process for eliminating impurities from the glass and advanced trajectory-simulation processes.

• Bulletin of the Korea Photovoltaic Society
• /
• v.5 no.1
• /
• pp.38-45
• /
• 2019

건물 일체형 태양광 발전시장의 증가에 따라 미적(Aesthetic) 요소가 결합된 태양광 모듈에 대한 수요가 증가하고 있다. 이런 시장의 요구에 따라 다양한 색상을 가지고 있는 컬러 태양광 모듈에 대한 연구 및 개발이 활발하게 진행되고 있다. 여러 제안된 컬러 태양광 모듈 기술 중 결정질 실리콘(crystalline-silicon) 기반 태양광 모듈에 컬러 유리 혹은 컬러 층을 도입하는 기술은 기존 실리콘 모듈의 장점인 신뢰도와 가격 측면에서 다른 방식 대비 큰 장점이 있다. 결정질 실리콘 모듈에 컬러를 구현하기 위해서는 현재 크게 세가지 방식이 제안되고 있다. 가장 먼저 제안된 방식은 태양전지 전면에 반사 방지막 형성 시 특정 파장만 반사할 수 있는 층이 도입된 컬러 태양전지(color photovoltaic cell)를 이용하여 색상을 구현하는 방식이다. 다른 한 방식은 일반 검정색 태양전지에 반사가 가능한 입자 혹은 박막층을 태양광 모듈 전면에 도입하는 반사형(Reflective) 컬러 태양광 모듈 기술이다. 마지막으로 특정 파장을 흡수하여 다른 파장으로 발광하는 염료 혹은 안료를 이용한 발광형(Luminescent)방식에 대한 연구도 진행 중이다. 본고에서는 각 방식의 동작 특성 및 기술 동향에 대해 논의하고자 한다.

• Journal of the Mineralogical Society of Korea
• /
• v.24 no.2
• /
• pp.111-118
• /
• 2011

Hydrated halloysite was formed by the low temperature alteration of trachytic tuff in onion-like spherical or curly platy forms. The Si content was higher than that of ideal kaolin minerals, indicating the possible presence of amorphous materials. The high Fe content is responsible for the platy morphology of halloysite. The leached ions precipitated as halloysite filling the interparticle pores, while trachytic glass was replaced by Si-rich amorphous materials in an hemispherical form, which was further evolved into spherical halloysite. Halloysite is one of the major alteration products of the volcanic ash in Ulleung Island underwent intense trachytic volcanism.

• Journal of the Mineralogical Society of Korea
• /
• v.28 no.2
• /
• pp.147-163
• /
• 2015

Chemical and mineralogical properties of coal ash samples from the nine thermal power plants of Korea were investigated to acquire basic data for estimating the potential of rare metal recovery. Chemical compositions of coal ash were consistent with those of average shale and foreign coal ashes. However, there were small differences between the metal contents of domestic anthracitic and imported bituminous coal ashes. Unburned coal particles were much abundant in the ash of domestic anthracitic coal. Chalcophile elements were relatively enriched in the fly ash compared to bottom ash. Silicate glass was the major component of coal ash with minor minerals such as quartz, illite (muscovite), mullite, magnetite, lime, and anhydrite. Al and Si were the major components of the glass with varying contents of Ca, Fe, K, and Mg. Glass occurred in a form of porous sphere and irregular pumace-like grain often fused with iron oxide spheres or other glass grains. Iron oxide spheres were fine intergrowth of fast-grown iron oxide crystals in the matrix of silicate glass. Chemical, microstructural, and mineralogical properties would guide successful rare metal recovery from coal ash.