• Title/Summary/Keyword: 유리곡선

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$SnO_2$ 나노 입자가 분산된 Poly(methylmethacrylate) 박막 층을 사용하여 제작한 유기 쌍안정성 소자의 전기적 성질

  • Gwak, Jin-Gu;Yun, Dong-Yeol;Jeong, Jae-Hun;Lee, Dae-Uk;Son, Dong-Ik;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.210-210
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    • 2010
  • 저항 구조를 가진 유기 쌍안정성 소자는 비휘발성 기억 소자 중에서 구조가 간단하고 제작비용이 저렴하며 플렉시블이 용이한 장점 때문에 많은 연구가 진행되고 있다. 유기물/무기물 복합재료를 사용한 유기 쌍안정성 소자 제작에 대한 연구는 많이 진행되어 왔지만, 넓은 에너지 밴드 갭을 가진 $SnO_2$ 나노 입자가 삽입된 고분자 박막을 기반으로 제작한 유기 쌍안정성 소자에 대한 연구는 상대적으로 미흡하다. 본 연구에서는 Poly(methyl methacrylate) (PMMA) 박막 안에 분산된 $SnO_2$ 나노 입자를 사용하여 제작한 유기 쌍안정성 소자의 전기적인 특성을 관찰하였다. 소자를 제작하기 위해 나노 입자의 전구체인 Tin 2-ethylhexanoate (95%) 2.4 mmol을 dibutyl ether (99.3%) 10 ml에 용해시킨 후, 용매열 화학적 방법을 사용하여 용매 안에서 $SnO_2$ 나노 입자를 합성하였다. 용매 안에 들어있는 1 wt%의 $SnO_2$ 나노 입자와 100 mg의 PMMA를 2 ml의 클로로벤젠에 용해하여 고분자 용액을 제작하였다. 하부 전극 역할을 하는 indium tin oxide가 증착된 유리 기판 위에 고분자 용액을 스핀 코팅하고, 열을 가해 용매를 제거하여 $SnO_2$ 나노 입자가 분산되어 있는 PMMA 박막을 형성하였다. 그 위에 Al 전극을 증착하여 기억 소자를 완성하였다. 제작된 유기 쌍안정성 소자의 전류-전압 (I-V) 측정 결과에서는 동일한 전압에서 서로 크기가 다른 전류가 흐르는 I-V 곡선의 히스테리시스 특성이 나타났다. 그러나 $SnO_2$ 나노 입자가 없는 PMMA 박막으로 형성된 유기 쌍안정성 소자에서는 I-V 곡선의 히스테리시스 특성이 나타나지 않았다. 따라서 PMMA 박막 안에 삽입된 $SnO_2$ 나노 입자가 유기 쌍안정성 소자의 메모리 효과에 결정적인 영향을 준 것을 알 수 있었다. 전류-시간 측정 결과에서는 소자의 ON/OFF 비율이 시간에 따라 큰 변화 이 없이 1000 사이클 이상 지속적으로 유지 하고 있음을 보여 줌으로써 유기 쌍안정성 소자를 장시간 사용할 수 있음을 나타내 주었다.

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Metallic Damper Shape and Cyclic Behavior for the Seismic Capacity Improvement of Building Structures (건축구조물의 내진성능 향상을 위한 강재댐퍼 형상 및 이력 거동)

  • Lee, Hyun-Ho;Kim, Seh-Il
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.3
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    • pp.123-130
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    • 2010
  • The aim of this paper is a seismic performance evaluation of metallic damper devices which are efficient in workability and installation process. For this V shape and S shape dampers is considered. The strut figures of dampers are V shape and S shape and, the research parameters are strut height and angle of the dampers. ABAQUS program is used for nonlinear finite element analysis. The analysis is performed with the hysteretic curve that has maximum displacement with 50mm and has increased progressive. As a results of evaluating the yield strength, maximum strength and energy dissipation capacity of each device, V and S shape have a good strength capacity and the devices with strut angle $60^{\circ}$ and strut height 140 and 200mm are evaluated stable in seismic behaviors. The response of S shape is more efficient than that of V shape. In the yield strength estimation process, proposed formula can not estimate the yield strength of V and S shape dampers. Even though, the formula can not consider the variation of strut heights and strut angles. Finally the S shape damper is recommended in seismic performance than V shape damper.

Analysis on Running Safety for KTX Vehicle (KTX차량의 주행 안전성 해석)

  • Kim, Jae-Chul;Ham, Young-Sam
    • Journal of the Korean Society for Railway
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    • v.10 no.5
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    • pp.473-479
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    • 2007
  • Lateral vibration at the tail of KTX train was found during the acceptance test. In order to settle the problem of lateral vibration, the wheel conicity was changed 1/40 to 1/20. However, we should evaluate the running safety of vehicle with 1/20 wheel conicity because modification of wheel conicity may cause the running performance to be worse and critical speed to reduce. In this paper, we calculate critical speed of KTX bogie as wheel conicity increase and analyze the running safety for KTX that has 20 car trainset formation using VAMPIRE. and compare with the test results of KHST to validate analysis results on high speed line. A analysis results show that critical speed of 0.3 wheel conicity is over 375km/h and curving performance of 1/20wheel conicity is better than 1/40. Also, we examinate the running performance of KTX to check out possibility to increase speed of KTX on conventional line. A analysis results show that it is possible to increase up to 10% the speed of KTX on tangent line but KTX on a curved line should be operated with the speed of conventional train.

A Study on the Effects of Chemical Grout on the Shear Strength of Fresh Granite Joints (신선한 화강암 절리면에서 약액에 의한 전단강도의 변화에 대한 연구)

  • Chung, Hyung Sik;Lee, Seung Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.10 no.3
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    • pp.99-106
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    • 1990
  • This study was aimed to see the effect of chemical grout on fresh granite joint shear strength. The grouting chemical used in this study was composed of 25% water glass. Direct shear tests were performed on the chemical filled joints, which had been made artificially with granite. The test results show that chemical grouted rock jonts have markedly reduced shear strength comparing with the ungrouted fresh joints and they sheared within chemical grout before the rock to rock contact had been established, while the ungrouted joint sheared between rock surfaces from the beginning of shear deformation. With chemical grouted joints the shear stress slowly reached its maximum without showing distinct peak shear strength. Therefore the shear stiffness of joints were decreased with increasing thickness of grout. but the shear strain at failure was increased with it.

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$B_2H_6$량에 따른 p-layer의 특성변화에 관한 연구

  • Jo, Jae-Hyeon;Yun, Gi-Chan;An, Si-Hyeon;Park, Hyeong-Sik;Jang, Gyeong-Su;Lee, Jun-Sin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.228-228
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    • 2010
  • pin-형 비정질 실리콘 태양전지에서 p-층은 창물질로서 전기 전도도가 크고, 빛 흡수가 작어야 한다. p층의 두께가 얇으면 i층에서 충분한 내부전위를 얻을 수 없어 개방전압이 작아진다. 반대로 p-층 두께가 두꺼워지면 p-층 자체에서 빛 흡수가 증가하고, 높은 불순물 농도(> $10^{20}/cm^3$)에 의한 표면재결합이 문제가 되어 변환효율이 감소한다. 밴드갭이 큰 물질로 창층을 만들면 짧은 파장의 입사광이 직접 i-층을 비추므로 단락전류와 곡선인자를 증가시킬 수 있다. 본 실험에서는 비정질 실리콘 증착과 박막 특성 분석을 위하여, $5cm{\times}5cm$ 크기의 eagle 2000 glass(유리)와 p형 실리콘 wafer가 사용되었다. 투과도, 흡수도, Raman, 암전도도 와 광전도도 특성 측정에 유리 기판에 증착된 박막을, 두께 측정, FTIR 측정에는 실리콘 기판에 증착된 박막이 각각 사용되었다. p형 비정질 실리콘 증착에는 $SiH_4$, $H_2$, $B_2H_6$ 가스를 사용하였고, 플라즈마 형성에는 13.56MHz의 RF 소스가 사용하였다.p층은 $SiH_4$ 가스와 $H_2$ 가스비가 1:5인 조건에서 $B_2H_6$을 도핑하여 형성하였다. $B_2H_6$가스량을 변화시키며 형성하였으며, $B_2H_6$가스량이 증가함에 따라 암전도도가 증가하였으나, 광학적 밴드갭이 감소하였다. $H_2/SiH_4$ 가스 비가 0.001일 때 밴드갭은 1.76으로 i층보다 높게 형성되었으며, 암전도도는 $10^{-7}$이었다.

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Diffusion-controlled Cure Kinetics of High Performance Epoxy/Carbon Fiber Composite Systems (확산속도에 따라 한계경화도를 갖는 에폭시/탄소섬유 복합재료의 경화반응 속도 연구)

  • 박인경;금성우;이두성;김영준;남재도
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.105-112
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    • 2000
  • Using a commercial epoxy/carbon fiber composite prepreg (DMS 2224) as a model system, the cure kinetics of vitrifying thermoset system were analyzed by isothermal and dynamic-heating experiments. Focusing on the processing condition of high performance composite systems, a phenomenological kinetic model was developed by using differential scanning calorimetry (DSC) and reaction kinetics theories. The model system exhibited a limited degree of cure as a function of isothermal temperature seemingly due to the diffusion-controlled reaction rates. The diffusion-controlled cure reaction was incorporated in the development of the kinetic model, and the model parameters were determined from isothermal experiments. The first order reaction was confirmed from the characteristic shape of isothermal cure thermograms, and the activation energy wes 78.43 kJ/mol. Finally, the proposed model was used to predict a complex autoclave thermal condition, which was composed of several isothermal and dynamic-heating stages.

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A Case Study of the Habitat Changes due to the Restoration of Low-Flow Channel (저수로 물길 복원을 통한 서식처 공간 변화 연구)

  • Choi, Jonggeun;Choi, Heung Sik;Choi, Byungwoong
    • Ecology and Resilient Infrastructure
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    • v.6 no.1
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    • pp.58-68
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    • 2019
  • This present study conducted the impact of the restoration of low-flow channel on fish habitat in a reach of the Wonju Stream, Korea. The target species were Zacco koreanus, a dominant species in the middle- and upper-stream of Wonju Stream. The River2D model was used for the computation of the flow and the habitat suitability index model was used to estimate the quantity and quality of fish habitat using habitat suitability curves. In order to restore the study area, the low-flow channel was identified through the bankfull discharge of the study reach, and the best hydraulic section was designed. In addition, various restoration techniques were applied to the low-flow channel through rocks, pool/riffle structures, and the change of the channel width. Simulation results indicated that the restoration of the best hydraulic section effects decreased habitat suitability for the target species. However, when various restoration techniques were applied, the WUA (Weighted Usable Area) was improved by about 11%.

Studies on the Anodic Oxidation Behavior of Methanol and L-Ascorbic Acid by Using Glassy Carbon Electrodes Modified with Inorganic-Metal Polymeric Films (무기 금속 고분자 막을 도포시킨 유리질 탄소전극을 이용한 메탄올과 L-ascorbic acid의 양극 산화 거동에 관한 연구)

  • Yoo, Kwang-Sik;Woo, Sang-Beom
    • Analytical Science and Technology
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    • v.11 no.5
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    • pp.347-352
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    • 1998
  • A study was carried out on the elelctrochemical characteristics of chemically modified electrodes (CMEs) by cyclic voltammetry. Fabrication of CMEs was made by coating with mixed valence (mv) inorganic-metal polymeric films on the glassy carbon electrode surface by potential cycling. Anodic oxidation behavior of methanol and L-ascorbic acid was studied by using CMEs working electrode. Deposition of films such as mv ruthenium oxo/ruthenium cyanide film (mv Ru-O/CN-Ru), mv ruthenium oxo/ferrocyanide film (mv Ru-O/$Fe(CN)_6$), and mv ruthenium oxo/ruthenium cyanide/Rhodium film (mv Ru-O/CN-Ru/Rh) was obtained to coat by scan rate of 50 mV/sec within the specified potential range (-0.5V ~ +1.2V). Film thickness was controlled by the repeat of the potential cycling. Anodic oxidation behavior of methanol was as follow. Calibration graph by using mv Ru-O/CN-Ru film showed linearly from 10 mM to 80 mM MeOH with slope factor of $-7.552{\mu}A/cm^2$. Although slope factor by using mv Ru-O/$Fe(CN)_6$ film was $-5.13{\mu}A/cm^2$, yet linear range of calibration graph could be extended from 10 mM to 100 mM MeOH. Anodic oxidation behavior of L-ascorbic acid was studied by mv Ru-O/CN-Ru film on the glassy carbon electrode and the glassy carbon electrode with Rh film, Glassy carbon electrode modified with Ru polymeric film was showed better sensitivity than the Rh-glassy carbon modified electrode (mv Ru-O/CN-Ru/Rh). Calibration graph was linear from 0.1 mM to 5 mM L-ascorbic acid by using glassy carbon electrode modified with Ru polymeric film. Solpe factor and relative coefficient are $-84.78{\mu}A/mM$ and 0.998, respectively.

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Chungkook-jang Koji Fermentation with Rice Straw (볏짚을 이용(利用)한 청국장 제조(製造)에 관(關)한 연구(硏究))

  • Kim, Kyung-Ja;Ryu, Myung-Ki;Kim, Sang-Soon
    • Korean Journal of Food Science and Technology
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    • v.14 no.4
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    • pp.301-308
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    • 1982
  • Chungkook-jang Koji was fermented with rice straw at $40^{\circ}C\;and\;50^{\circ}C$ for 72 hours. The changes of proximate composition, pH, titrable acidity, nitrogen compounds, protease activity and free-amino acids during the fermentation were investigated. Moisture, lipid and protein contents remained essentially unchanged during the fermentation. The pH was gradually increased from 6.4 to 7.46 and 7.82 at $40^{\circ}C\;and\;50^{\circ}C$, respectively, after 72 hour fermentation. Amino type and water soluble nitrogen increased as fermentation progressed. however, the former slightly decreased after 60 hour fermentation. Chungkook-jang fermented at $40^{\circ}C$ showed somewhat higher protease activity than $50^{\circ}C$. However, protease activity at both fermentation temperatures showed the same trend; that is, it increased until 48 hour fermentation and thereafter decrease. Free amino acid content of Chung-kook-jang after 72 hour fermentation at $40^{\circ}C$ was 6 times greater than that of the steamed soybean, while it was 2.5 times greater at $50^{\circ}C$. Based on these results. it seems that the optimum fermentation conditions for Chungkook-jang were $40^{\circ}C$ and 72 hours.

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Growing Stage of Sugar Beet at Different Locations in Korea (지역별 사탕무우 생육과정에 대한 고찰)

  • Se-Ho Son
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.4 no.1
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    • pp.109-114
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    • 1968
  • In order to investigate the growth pattern of sugar beet in Korea, this experiment was conducted using variety GW 359 at Tae-kwan-ryong, Suwon and Cheju. The results are summarized as follows; 1. At Tae-kwan-ryong, early growth stage was relatively long and during higher growing stage plants showed resistance to leaf spot disease, and vegetative maturing started from about September 15th. Top and root growth showed normal curve but it is considered that the early maturing variety will reduce the early growing period and prolong the vegetative maturing period. 2. At Suwon, the growth of top part was favorable until late of July but hereafter leaf spot disease brought death to the 25-35 leaves of top part and regenerated again in October. Consequently, sugar content of root showed changes from decrease to increase. Root weight increased from July to harvest season continunousely but showed abnormal growing curve. This indicates that Suwon is not proper place for sugar beet cultivation. 3. At Cheju, early growing stage was shorter about 15 days than that of Tae-kwan-ryong. Normal growth and long-maturing days favored the sugar accumulation in roots. But it is necessary to introduce non-bolting variety in autumn-winter season culture. 4. Sugar beet could be cultivated economically at Tae-kwan-ryong with 600-800 meter altitude for summer crop and at Cheju for winter crop, but Suwon is considered to be unfavorable for sugar beet.

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