• Title/Summary/Keyword: 유류 오염

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Chemical Oxidation Treatment of Hydrocarbon-Contaminated Eine Soil by ${H_2}{O_2}$/$Fe^0 System (${H_2}{O_2}$/$Fe^0시스템을 이용한 유류오염 미세토양의 화학적 산화처리)

  • 지원현;김지형;강정우;김성용;장윤영
    • Journal of Soil and Groundwater Environment
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    • v.6 no.3
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    • pp.13-20
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    • 2001
  • In this Study, application of ${H_2}{O_2}$/$Fe^0 oxidation System (Fenton-like oxidation) for the oxidative treatment of high-level soil contamination with hydrocarbon was suggested. The characteristics of Fenton-like oxidation of diesel-contaminated fine soil was experimentally probed in a batch system varying initial pH, zero valent iron and hydrogen peroxide levels, and initial diesel concentration. Contaminant degradation was identified by total petroleum hydrocarbon(TPH) concentration with gas chromatography. The batch experiments showed that the optimal ${H_2}{O_2}$and $Fe^0 dosage, 10% ${H_2}{O_2}$+ 20% $Fe^0 removed 65% of initial TPH concentration (10,000mg/kg) at a retention time of 24h. And the TPH removal in the ${H_2}{O_2}$/$Fe^0 system effectively proceeded only within a limited pH range of 3-4. The zero valent iron-catalyzed Fenton-like oxidation of diesel-contaminated soil was more competitive to the $FeSO_4-catalyzed system (Fenton oxidation) in removal efficiency and cost especially for the treatment of high level contamination.

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A Feasibility Study on Joining "The Supplementary Fund Protocol" (2003 추가기금협약 가입에 대한 경제적 타당성 분석)

  • Cho, Dong-Oh;Mok, Jin-Yong;Baek, Kwang-Shik
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.15 no.3
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    • pp.213-216
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    • 2009
  • Since adopting 1969 CLC and 1971 FC, IMO increased maximum amount of compensation by adopting protocols of 1969 CLC and 1971 FC. Recently IMO adopted 2003 Supplementary Fund by which the compensation limits increased dramatically to 750 million SDR. Korea government has only entered 1992CLC/FC. However, since the Hebei Spirit incident in 2007, there have been strong claims that Korea government should enter 2003 Supplementary Fund. In this article, feasibility study was carried out to help Korea government decide whether or not entering the Convention. The quantitative analysis has been carried out using data of the past oil spill accidents and contribution fee to IOPC Fund and showed that the benefit was much bigger than costs. The qualitative analysis in relation to resources fix compensation to victims, benefits of consignee, and the status of Korea in IMO also showed that Korea should ratify the 2003 SF.

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Establishment of Korean Environmental Sensitivity Index Map (ESI Map 구축 연구)

  • Sung H. G.;Lee H. J.;Lee M. J.;Kang C. G.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.6 no.4
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    • pp.3-12
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    • 2003
  • Due to the high demand on energy resources accompanied by continuing industrialization and urbanization, the world marine transportation of crude and product oils is being gradually increased. In Korea, we are exposed to the large-scale marine oil spill accidents because a very large oil tanker of 300,000 tonnage must enter Korean Ports every day to meet the domestic demand on oils. Although we are exerting our strength to reduce the probability of marine oil pollution accidents, a unrestorable oil spill is to occur owing to human errors, severe weather conditions, or combined causes. Thus, area contingency plan equipped with appropriate management system for response and restoration for the worst case discharge scenario must be entirely prepared to protect mine environments and coastal resources. In particular, we are focusing on the Environmental Sensitivity Index Map(ESI Map) to reduce the environmental consequences of both spills and clean-up efforts by specifying protection Priorities in advance and identifying in-situ response strategies. In this paper, Korean ESI Map is introduced with brief definition of sensitivity to oiling and main features of the software developed hitherto.

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Status of Government Supports to Overcome the Hebei Spirit Oil Pollution Accident and Suggestion of Responsive Policies (허베이스피리트호 유류오염사고 극복을 위한 정부지원 현황 및 대응정책 제언)

  • Chung, Kwang-Yong;Lee, Seung-Hwan
    • Journal of Digital Convergence
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    • v.10 no.7
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    • pp.153-159
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    • 2012
  • The Hebei Spirit oil pollution accident which occurred in Tae-an in 2007 has brought considerable impacts on the surrounding environment such as struggles among the regions and the residents in the damaged area as well as devastation of local economy and ocean environment. The majority of the impact was related with economic problem. Also, the main factor to cause the regional community conflict was found to be firstly economic problems and secondly the insufficiency of government's management system and policy measures for the community conflicts. Therefore, the government's policy to overcome oil accidents should focus on improvement of the economic support systems and conflict resolution. In this study, the support policies taken by government after the Hebei Spirit accident was examined and responsive policies which can be used by government in future accidents are suggested.

토양세척공법을 적용한 유류오염토양 정화 사례

  • Sin Jeong-Yeop;Gong Jun;Kim Geon-U;Jeon Gi-Sik;Hwang Jong-Sik
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.45-48
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    • 2006
  • 혼합유류(등,경유)로 오염된 대상부지의 토양특성을 파악하여 세척공법의 적용성을 판단하고, 적용성시험을 통하여 장치별 설계인자를 도출하였다. 시험결과 본 세척대상토양의 경우 계면활성제와 같은 첨가제를 주입하지 않고 물리적인 탈착공정만을 거쳐도 90%이상의 오염물질이 토양입자표면으로부터 탈착됨을 알 수 있었으며, 이를 반영하여 장치를 제작, 설치하였다. 세척대상 오염토량은 총 $12,225m^3$, 사업수행기간은 약 6개월, 세척장치에 주입된 세척토양의 평균오염농도는 약 3,152ppm 이었으며 세척 완료된 토양의 평균농도는 약 150ppm으로 약 97%의 제거효율을 보여 복원목표인 800ppm을 만족시킬 수 있었다. 그리고, 세척토양의 입도분포를 정확히 파악하고 분리시킬 토양입자 크기를 결정하여 현장 적용한 결과 세척공법으로부터 배출되는 응집슬러지를 최소화할 수 있었으며, 발생되는 세척폐수 또한 세척수 처리시스템을 거쳐 재활용 할 수 있도록 하였다. 이런 결과를 통하여 세척공법이 다른 Ex-situ 공법과 비교하였을 경우 현장의 적용성, 경제성, 복원기간 등을 감안하였을 경우 성공적인 세척공법의 적용사례라 할 수 있다.

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Prediction of Distribution for Five Organic Contaminants in Biopiles by Level I Fugacity Model (Level I Fugacity Model을 이용한 Biopile 내 유기화합물 5종의 분포 예측)

  • Kim, Kye-Hoon;Kim, Ho-Jin;Pollard, Simon J.T.
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.3
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    • pp.228-234
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    • 2008
  • The purpose of this study was to predict environmental distribution of anthracene, benzene, benzo[a]pyrene, 1-methylphenanthrene and phenanthrene in a four phase biopile system - air, water, soil and non aqueous phase liquid (NAPL) phase using level I fugacity model. Soil samples used for this study were collected from three sites in the United Kingdom which were historically contaminated with petroleum hydrocarbons. The level I fugacities (f) for the five contaminants were markedly different, however, the fugacities of each contaminant in three soil samples did not show significant difference. NAPL and soil were the dominant phases for all five contaminants. Results of this study indicated that difference in percentage of organic carbon strongly influenced the partitioning behavior of the cntaminants. The presence of benzene calls for an urgent need for risk-based management of air and water phase. Whereas insignificant amount of chemicals leached in the water phase for other organic contaminants showing greatly reduced potential of groundwater contamination. Furthermore, this study helped us to confirm the association of risk critical contaminants with the residual saturation in treated soils. They also can be used to emphasize the importance of accounting for the partitioning behavior of both NAPL and soil phases in the process of the risk assessment of the sites contaminated with petroleum hydrocarbons.

측정불확도를 응용한 오염토양부지 조사의 최적화 방안

  • 이종천
    • Proceedings of the KSEEG Conference
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    • 2003.04a
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    • pp.39-42
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    • 2003
  • 중금속으로 오염된 폐광산 주변부나 유류누출로 인한 토양오염 등과 같은 오염부지에 대한 환경조사는 그 결과를 토대로 환경계획이나 정책이 수립되므로 의사결정의 기초가 된다. 이때, 의사결정의 타당성은 오염부지 조사결과 오염도가 얼마나 정확하게 측정되었느냐에 따라 달리 평가되어 진다. 그러므로 이와 같은 환경조사는 측정결과의 불확실성이 감소되도록 정밀한 시료채취방법이나 분석방법을 고안하여 적용해야 한다. (중략)

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Effect of Surface Condition of Soil Particles According to Water Content on Spectral Information of Soils (지반의 함수비에 따른 흙 입자의 표면조건이 분광정보에 미치는 영향)

  • Kim, Ju-Hun;Hong, Gigwon;Park, Jeong-Jun
    • Proceedings of the Korean Society of Disaster Information Conference
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    • 2022.10a
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    • pp.345-346
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    • 2022
  • 본 논문에서는 유류오염사고 발생에 의해 지반 내에 오염물이 유출되었을 때, 오염물 확산방지를 목적으로 차수재의 차수성능 평가를 위한 수치해석을 수행하였다. 해석결과, 차수재의 차수효과에 의해 동일한 투수계수 및 관측위치 조건에서 오염물 접촉시간 경과에 따른 농도가 크게 감소한 것을 확인하였다.

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