• Polymer(Korea)
• /
• v.36 no.4
• /
• pp.478-485
• /
• 2012

A series of transparent polyimide (PI) nanocomposite films was synthesized from bicyclo(2,2,2)oct-7-ene-2,3,5,6-tetracarboxylic dianhydride (BTDA) and 1,3-bis(3-aminophenoxy)benzene (BAPB) with various organoclay contents via solution intercalation polymerization to poly(amic acid)s, followed by thermal imidization. Varying organoclay loading in a range of 0 to 1.5 wt% produced variations in the optical transparency, morphology, and oxygen barrier property of the hybrids. An optimum oxygen barrier property was observed for the hybrids containing 1.0 wt% Cloisite 30B; these properties were degraded gradually by further increases in the clay content. The PI hybrid films were found to exhibit excellent optical transparency and almost no color. However, the transparency of the hybrid films decreased slightly with increasing organoclay content. Transparent PI hybrid films containing 1.0 wt% Cloisite 30B were stretched equi-biaxially with various stretching ratios in a range of 100-140% to investigate their optical transparency and oxygen permeability in detail; the variations of clay dispersion and morphology were also determined as a function of equi-biaxial stretching ratio. PI hybrid films with ${\geq}120%$ stretching were found to contain homogeneously dispersed clay in the polymer matrix and exfoliated nanocomposites. The highest barrier to oxygen permeation was found at an equi-biaxial stretching ratio of 130%.

• Journal of Korean Society of Coastal and Ocean Engineers
• /
• v.27 no.1
• /
• pp.9-13
• /
• 2015

Field experiment were carried out to investigate the formation of ground water flow and remediation of muddy tidal flat by installation of porous pile at the tidal flat of brackish river located in Hiroshima City, Japan. After the installation of porous pile, the concentrations of Dissolved Oxygen (DO) in the interstitial water in the porous pile increased with maximum concentration of 4 mg/L due to a formation of groundwater flow. It was observed that a increase in Oxidation Reduction Potential (ORP) and a decrease in Ignition Loss (IL) in the porous pile site and these must be caused by the increase of dissolved oxygen in the interstitial water. From these results obtained above, it is concluded that the porous pile is an effective technology for remediation of muddy tidal flats.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2005.05a
• /
• pp.317-317
• /
• 2005

• Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
• /
• 1992.08a
• /
• pp.188-191
• /
• 1992

최근 해양공간의 이용 및 개발과 관련해서 하구역이나 연안해역의 개발이 활발하게 진행됨에 따라 연안해양환경의 예측과 제어에 관한 기술 개발이 중요한 과제로 대두되고 있다. 하구역이나 연안해역에 분포하는 물질 가운데 상당부분이 점토나 실트와 같은 점착성토사와 유기성 현탁입자로 구성되어 있다.(중략)

• Economic and Environmental Geology
• /
• v.36 no.3
• /
• pp.171-176
• /
• 2003

The fate and behavior of polycyclic aromatic hydrocarbons(PAHs) and heavy metals in the environment are mainly controlled by their interactions with various components of soils and sediments. Due to their large surface area and abundance in many soils, smectites may greatly influence the fate and transport of the contaminants. In our experiment, PAH sorption by hexadecyltimethylammonium(HDTMA)-modified smectite linearly increased in proportion to the amount of HDTMA added on the clay. However, trimethylammonium(TMA)-modified smectite did not show superiority in its sorption of PAH compared with the HDTMA-smectite or dodecyltrimethylammonium(DTMA)- smectite. Meanwhile, the smectites modified with the same cationic surfactants adsorbed Cd$^{2＋}$(heavy metal) significantly from water at low surfactant loading level, but the Cd$^{2＋}$ adsorption linearly decreased as the loading of surfactant increased. The result shows that the sorption tendency of organoclays for organic or inorganic contaminants was significantly influenced by the amount and size of the surfactants added on the clay. This reveals that the stabilization and configuration of cationic surfactant formed on the clay interlayer of different sizes may be an important factor in controlling the sorptive capacity of each pollutant in the environment.

• 한국해양학회지
• /
• v.24 no.1
• /
• pp.39-51
• /
• 1989

A total of 139 surface sediment samples, collected from the continental shelf and slope off the southeastern coast of Korea, were analyzed in order to understand their grain-size, mineral composition and organic carbon content. Based on the grain-size characteristics, five surface sedimentary facies were distinguished: sand, clay, mud, sand-mud mixed, and sand-clay mixed facies. The sand facies appears to be composed mostly of relict sand. For mud, most of which seem to be of recent origin, two different sources were suggested, based principally on their areal distribution pattern and the local hydrographic conditions. Heavy mineral composition of the fine-sand size fraction allowed us to distinguish different sand populations from the study area. On the whole, the Hupo Bank sediments showed a high content of garnet, while the sediments from the northern part of the continental shelf were characterized by a relatively high content of metamorphic minerals (kyanite, sillimanite, andalusite, staurolite). Among clay minerals, the most abundant was illite, with chlorite, kaolinite and smectite following in decreasing order. Organic carbon contents in the sediments of the study area were generally high and showed an average value of 1.94%. The sediment grain-size exerted a strong influence on the organic carbon content. The highest organic carbon content, on the other hand, was found in the continental slope sediments.

• Journal of Korean Society of Water and Wastewater
• /
• v.26 no.6
• /
• pp.747-756
• /
• 2012

The purpose of this study was to investigate adsorption characteristics of organo-clays for removal of p-xylene. As part of efforts to examine the adsorption capacities of some organo-clays for p-xylene, batch isotherm tests were carried out. Organo-clay minerals were synthesized under hydrothermal conditions using Na-montmorillonite as host clay and dimethyldioctadecylammonium (DMDA) bromide and benzyldimethyldodecylammonium (BDDA) chloride as organic surfactants, respectively. All synthetic organo-clay minerals were characterized by powder x-ray diffraction (XRD), scanning electron microscope (SEM) and energy-dispersive x-ray spectroscopy (EDX). The modification using dimethyldioctadecylammonium (DMDA) bromide showed the higher adsorption ability for p-xylene than benzyldimethyldodecylammonium (BDDA) chloride. On the other hand, the maximum adsorption capacity, $Q_{max}$ of DMDA modified montmorillonite estimated by Langmuir model was 27.0 mg/g, which was the higher value than other organo-clays.

• Polymer(Korea)
• /
• v.25 no.6
• /
• pp.876-883
• /
• 2001

A thermotropic liquid crystalline polyester (TLCP) containing a side group was, synthesized from ethoxyhydroquinone and bromoterephthalic acid. Intercalation of TLCP in layered clays is accomplished by heating the polymer with hexadecyl ammonium-montmorillonite ($C_{16}$) above melting transition temperature ($T_m$). Liquid crystallinity of the TLCP/$C_{16}$-hybrid was observed up to 6 wt% $C_{16}$-MMT. Some of the $C_{16}$-MMTs in TLCP were highly dispersed in a nanometer scale, but some of them were agglomerated. Thermal and morphological properties of the nanocomposites were examined by differential scanning calorimetry (DSC), thermogravimetric analyzer (TGA), polarized optical microscope, and electron microscopes (SEM and TEM).

• Journal of the Korean GEO-environmental Society
• /
• v.6 no.4
• /
• pp.13-26
• /
• 2005

In this study, research results on organic and inorganic pollutant migration through single and composite liner were summarized. On the basis of these summarized research results, a design program for landfill liner, which can be used to optimize the liner thickness based on the allowable ground water criteria around the landfill subsurface, was developed. A reasonable liner thickness was obtained from the program output results, in the case of the migration of $Cl^-$ ion through a single clay liner. Therefore, the developed program could be used to carry out a preliminary design for landfill liners with respect to organic and inorganic pollutants.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2020.06a
• /
• pp.196-196
• /
• 2020

토양은 육상생태계에 있어 가장 많은 탄소를 저장하고 있으며, 대기 중 CO₂를 토양탄소로 전환하여 쉽게 방출되지 않고 토양 내에 저장하는 역할을 한다. 이렇듯 토양 유기탄소 배출관리는 기후변화에 있어 중요한 문제로 대두되고 있다. 하지만 토지이용의 변화와 무분별한 관리로 인하여 토양내에 저장되어 있는 토양 탄소배출이 지속적으로 증가 하고 있다. 따라서 토양탄소 배출로 인한 경제적 피해를 수치적으로 표현하는 가치평가가 필요하다. 현재 토양에 저장된 토양유기탄소 함량을 토양통별로 토양정보시스템에서 제공하고 있지만 국내 토양 토양탄소 저장량의 산정에 관한 연구는 미비한 실정이다. 따라서 본 연구에서는 토양 특성을 이용하여 토양 유기탄소 저장량을 산정하고, 산정된 토양 유기탄소 저장량과 정밀토양도를 이용하여 남한의 토양 유기탄소 가치평가를 실시하였다. 토양의 특성은 물리적 특성인 모래(Sand), 이토(Silt), 점토(Clay), 자갈(Gravel)함량과 화학적 특성인 유기물함량(Organic Matter)를 사용하였다. 토양 유기탄소저장량 산정의 검증을 위하여 전라남도 진도군의 토양유기탄소 저장량을 산정한 결과 486,696t으로, 선행연구와 유사한 결과를 나타내었다. 이러한 검증 결과를 바탕으로 남한의 토양 유기탄소 저장량을 산정한 결과 305.54Mt의 유기탄소가 저장된 것으로 나타났으며, 단위 면적당 유기탄소 저장량의 경우 3.11kg/㎡으로 나타났다. 또한 2019년 상반기 기준 평균 탄소거래권 가격(27,500원/톤)을 이용하여 우리나라 국토의 토양탄소 저장량 가치평가를 실시한 결과, 약 8조 4천억원의 경제적 가치가 있는 것으로 나타났다. 본 연구는 토양의 물리적·화학적 특성을 이용하여 토양의 유기탄소 저장량을 산정하였으며, 토양에 저장되어 있는 유기탄소의 가치평가를 수행하였다. 본 연구결과는 농업, 수문, 기후변화 등 다양한 분야에서 필요로 하는 기초자료로 활용될 수 있을 것으로 판단된다.