• Title/Summary/Keyword: 유기지화학

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Deodorization of Swine Wastewater by Rhodospirillum rubrum N-1 (Rhodospirillum rubrum N-1을 이용한 양돈폐수의 악취제거)

  • Choi, Kyung-Min;Kim, Jong-Seung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.6 no.1
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    • pp.13-20
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    • 1998
  • Rhodospirillum rubrum N-1 was inoculated to manipulated swine wastewater of 20,000 mg/L as Biochemical Oxygen Demand (BOD) to study the effect of aeration on swine wastewater deodorization. Biological and physico-chemical parameters were determined at 1 day interval for 9 days. Removals of BOD, volatile fatty acids (VFAs), and phosphate were 54.6%, 87.0%, and 54.5%, respectively. No significant changes were observed in the concentrations of total nitrogen, total phosphorus, nitrate, nitrite, hydrogen sulfide, and mercaptane.

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Soil Management Practices Affected Nutrient Use Efficiency on Chinese Cabbage (Braccica campestris) in the Alpine Region of Korea (시비 방법이 고랭지 배추와 토양 환경에 미치는 영향)

  • Kim, Su-Jung;Yang, Jae-E;Shin, Young-Oh
    • Korean Journal of Organic Agriculture
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    • v.15 no.2
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    • pp.219-228
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    • 2007
  • 강원도 고랭지는 채소 재배지로 그 이용 면적이 매년 급속히 증가하고 있다. 금한 경사와 집중적으로 발생하는 장마철의 폭우는 토양 유실은 물론이고 토양 비옥도의 심각한 저하를 초래할 위험이 경작의 강도와 범위가 넓어짐에 따라 더욱더 증가하고 있다. 또한 험한 지형에 따른 기계화 영농의 어려움과 이에 수반하는 노동력의 낭비로 문제점을 제기한다. 채소 작물 재배를 위해 많이 사용하는 요소 비료, 황산암모늄 비료와 함께 특별히 수지(resin)를 피막 처리한 복합비료를 가지고 배추의 생장과 토양에 미치는 영향을 조사하였다. 수지 피막처리는 각각 7, 10, 15%의 비율로 혼합했다. 배추의 수량은 실험에 사용된 비료간에 큰 차이가 없었다. 요소와 황산암모늄은 기본 시비와 함께 2차례 추비를 하였고 수지 피막 복합 비료는 단 한번 초기에 시비하였다. 따라서 이 경우 노동력 절감과 토양 환경 교란의 최소화를 달성할 수 있었으므로 완효성의 수지 피막 처리 비료가 바람직한 것으로 나타났다. 토양에 미치는 효과는 비료의 종류간에 별다른 차이가 없었으나 인산$(P_2O_5)$의 토양내 축적 현상이 t지 피막 처리 복합 비료 시용 구에서 뚜렷하게 조사되었다. 일반적으로 화학 비료의 시용은 토양 반응(pH)의 저하를 초래하였다.

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Long-term Changes in Soil Chemical Properties in Organic Arable Farming Systems in Korea (작물의 지속적인 유기 재배가 토양의 이화학적 특성변화에 미치는 영향)

  • Lee, Yun-Jeong;Choe, Du-Hoi;Kim, Seung-Hwan;Lee, Sang-Min;Lee, Yong-Hwan;Lee, Byung-Mo;Kim, Tae-Wan
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.4
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    • pp.228-234
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    • 2004
  • In organic farming, nutrients for the crop production are mostly supplied by compost containing various organic materials. The long-term organic cultivation would result in continuous changes of soil chemical properties and fertility. The aim of this study was to investigate the contribution of long-term organic cultivation to the soil fertility in Korea focusing on the chemical properties of soil. Soil samples were collected from organic farms that had been cultivated for 8-10 years after certification of organic product through the conversion periods of 2-3 years. Thereby each organic farm had acquired optimal cultivating techniques and soil condition. We separated organic farms into three groups by cultivating crops, i.e. leaf vegetables, fruit vegetables and fruit trees. In each group, five representative farms were chosen in order to investigate the relationships between application rate of compost and nutrient contents in soil. The application rate of compost was approximately $10-15Mg\;10a^{-1}$ for the first 2-3 years at the beginning of organic farming and then reduced to a rate of $3-4Mg\;10a^{-1}$ after stabilization of organic matter content in soil with $30-50g\;10a^{-1}$. However, the continuous organic farming for 8-10 years resulted in accumulation of nutrients, especially of P, in soil probably due to the excessive amounts of compost applied. In conclusion, we suggest that the application rate and organic sources of compost should be decided on the basis of P content in soil by soil testing and thereafter the lack of soil N content for crop cultivation should be compensated by crop rotation with such as legumes. This might be an approach to the original meaning of organic farming as an environmental friendly agriculture.

Thermal Characteristics of Waste Organic Sludges Discharged from an Chemical Product Manufacturing Industry (화학제품제조업에서 배출되는 폐 유기성슬러지의 열적 특성)

  • Kim, Min-Choul;Lee, Gang-Woo;Lee, Man-Sig;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.6
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    • pp.1745-1753
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    • 2008
  • We analyzed the physical and chemical properties such as proximate analysis, ultimate analysis, heating values, thermogravimetric analysis, and combustion test for the organic sludge discharged from chemical and petrochemical product manufacturing industries in the industrial complex. The average combustible and ash content of organic sludges from chemical and petrochemical product manufacturing industries were 17.42%, 7.45%, and 18.25%, 4.22%, respectively. The C, H, O, N, and S compositions for chemical and petrochemical product manufacturing industries were 33.06, 4.34, 24.81, 5.18, and 0.72%. And those compositions for petrochemical product manufacturing industries were 36.58, 4.74, 26.79, 5.09, and 0.49%, respectively. From the TGA test, the minimum temperature for combustion of the sludge discharged from B company was $700^{\circ}C$ for direct use for energy and 2 sludges(F and N companies) were about $600^{\circ}C$. According to the basic combustion test, high concentration of CO was formed because oxidation and pyrolysis reaction take place in the batch type reactor at the same time. From this phenomena we could obtain the significant data for the overheating and breakage of furnace.

Integral Pest Management of the Western Flower Thrips, Frankliniella occidentalis: Optimal Time to Introduce a Natural Predator after Chemical Insecticide Treatment (꽃노랑총채벌레 종합방제 - 화학농약 처리 후 안정적 천적 투입 시기)

  • Chulyoung, Kim;Donghyun, Lee;Donghee, Lee;Eunhye, Ham;Yonggyun, Kim
    • Korean journal of applied entomology
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    • v.61 no.4
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    • pp.519-528
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    • 2022
  • The western flower thrips, Frankliniella occidentalis, infests the hot pepper cultivated in greenhouses and has been considered to be controlled by a natural enemy, Orius laevigatus. However, sporadic outbreaks of the thrips due to fast population growth occasionally need chemical insecticide treatments. This study was designed to develop an optimal integrated pest management (IPM) by using selective insecticides along with a safe re-introduction technique of the natural enemy after the chemical insecticide treatment. First, chemical insecticides were screened to select the high toxic commercial products against F. occidentalis. Five insecticides containing active components (pyriproxyfen+spinetoram, abamectin, spinosad, acetamiprid, and chlorpyrifos) were selected among 17 commercial products. These five selected insecticides gave different toxic properties to the natural enemy, O. laevigatus. Especially, abamectin and spinetoram gave relatively low toxicity to the natural enemy compared to organophosphate or neonicotinoid. Furthermore, the five selected insecticides were assessed in their residual toxicities against O. laevigatus. Organophosphate and neonicotinoid insecticides showed relatively longer residual toxicity compared to abamectin and spinosads. Indeed, abamectin or spinetoram did not give any significant toxicity to O. laevigatus after 3 days post-treatment. These residual effects were further supported by the assessment of the chemical residue analysis of the insecticides using LC-MS/MS. These results suggest an IPM technology: (1) chemical treatment of abamectin or spinetoram against sporadic outbreaks of F. occidentalis infesting hot pepper and (2) re-introduction of O. laevigatus to the crops after 3 days post-treatment to depress the equilibrium density below an economic injury level.

Growth and Fruiting Characteristics, and Nut Qualities of Castanea crenata by Low-Concentrated Liquid Fertilizer (저농도 액비처리에 따른 밤나무 생장 및 결실특성과 과실품질)

  • Lee, Uk;Hwang, Suk-In;Kim, Mahn-Jo;Kim, Ji-Hye
    • Journal of Korean Society of Forest Science
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    • v.100 no.3
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    • pp.432-440
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    • 2011
  • The objective of this study was to investigate growth and fruiting characteristics (e.g., nut qualities) of chestnut (Castanea cerenata) after applying various fertilizer treatments at the cultivation site in Suncheon. Fertilizer treatments were designed as follow: liquid fertilizer, chemical fertilizer, organic fertilizer, and control. Both liquid and chemical fertilizer treatments provided the best growth in height and basal diameter. In addition, these two treatments were very effective for crown width of the trees between both east-west and north-south orientation. The liquid fertilizer treatment was effective on total length of the fruiting branch and length of the bearing to terminate part. Both liquid and chemical fertilizer treatments produced the longest length of basal to bearing part compared to the other two treatments. The liquid fertilizer treatment showed the most thickened basal diameter of the fruiting branch and the greatest diameter of above and below the bearing burr part. Elongation Index of the fruiting branch (EI) was the highest with liquid fertilizer treatment and the remaining four indices (Production Index of fruiting branch, PI; Ratio of Diameter between below and above bearing burr part, RD; Growth Index of fruiting branch diameter, GI; Thickness Index of fruiting branch or dormant branch, TI) were the highest with the chemical fertilizer treatment. Total number of produced branch per fruiting mother branch and number of small and weak branches per fruiting mother branch were highest on the control and liquid fertilizer treatment; however, all treatments produced similar numbers. The chemical and organic fertilizer treatments produced a high number of fruiting branches per fruiting mother branch, while organic and liquid fertilizer treatments produced a high number of burr per fruiting branch. The rate of commercializing on the basis of nut weight and quantity was higher on control (87.5%) than chemical fertilizer treatment (84.6%); however, the rate was even lower on liquid fertilizer treatment (84.3%) and organic fertilizer treatment (82.7%). The liquid fertilizer treatment showed the highest average of nut weight, while chemical fertilizer treatment showed the highest average number of fruiting burr. There was no significant difference in average number of normal nuts per burr among treatments. The yield per tree was high on chemical (8.2 kg) and liquid (8.0 kg) fertilizer treatments, but there was no significant difference among treatments. In the rate of nut grade on the basis of nut weight and quantity, the liquid fertilizer treatment, 43.5% and 34.3% more than large nut respectively, produced higher value chestnuts compared to other treatments.

Characterization of Fluorocarbon Thin Films deposited by PECVD (PECVD로 증착된 불화 유기박막의 특성 평가)

  • 김준성;김태곤;박진구;신형재
    • Journal of the Microelectronics and Packaging Society
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    • v.8 no.2
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    • pp.31-36
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    • 2001
  • Teflon-like fluorocarbon thin film was deposited by using difluoromethane$(CH_2F_2$) added with Ar, $O_2$, and $CH_4$ on Si, $SiO_2$, TEOS, and Al substrate. The deposited thin film was characterized by static contact angles for measuring hydrophobicity in various additive gas ratio. temperature, and working pressure. In case of addition with Ar, the static contact angles decreased as additive gas ratio and power increased. But the static contact angles increased as working pressure increased. Specially, super-hydrophobic surface was obtained using the powder-like fluorocarbon thin film above 2 Torr. Added with $O_2$, the static contact angles decreased as the $O_2$ ratio and working pressure increased. And the static contact angles did not change in 100W, but hydrophilic surface was obtained at 200W. In case of addition of CE$_4$, static contact angles dramatically increased in $CH_4/CH_2F_2$ ratio 5. And continuous static contact angles obtained above ratio 5. As compare with previous experiments by thermal evaporation, the fluorocarbon thin film by plasma polymerization was obtained very low hysteresis. This results shows more homogenous surface by plasma polymerization than thermal evaporation process.

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Effect of Landfill Site Characteristics on Siloxane Production in Landfill Gas (매립지 특성이 매립가스 내 siloxane 발생에 미치는 영향)

  • Nam, Sangchul;Kang, Jeong-Hee;Hur, Kwang-Beom;Lee, Nam-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.3
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    • pp.44-53
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    • 2011
  • Siloxane, organo-silicon compound, is used in the various forms of products such as cosmetics and detergents due to its quality physical chemistry attributes. Siloxane included in landfill gas which is caused in the process of decomposing of such products after landfill has imposed negative impacts on the operation of landfill gas utility facilities. The objective of this study was to investigate the siloxane production characteristics depending on the features of various landfill site in Korea so that the analysis was made on the landfilling age and landfill waste by in terms of its concentration, structure and composition. As for the concentration of siloxane depending on time passage, 12 landfill sites were reviewed by landfilling age. As for production attributes change of siloxane by landfill wastes, the source of wastes, physical production ration and siloxane concentration were compared in 6 landfills. The average concentration of total-siloxane within LFG is $6.75mg/m^3$ and cyclic-siloxane out of it occupies over 93%. By element, D4 and D5 in order take the highest proportion regardless of total-siloxane concentration and landfilling age. Even though this study is not able to verify the different impact of each kind of wastes on the generation of siloxane, it is confirmed that total-siloxane and cyclic-siloxane decrease in line with the increase of landfilling age as it does in the first order decay model for landfill gas.

Application of Geographic Information System for Synthetic Analysis of Multidisciplinary Data in Seawater Intrusion Assessment (해수침투 조사자료의 통합적 해석을 위한 GIS의 적용)

  • Choi Sun-Young;Hwang Seho;Park Kwon Gyu;Shin Je-Hyun;Yoon Wang-Jung
    • Spatial Information Research
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    • v.12 no.3
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    • pp.275-283
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    • 2004
  • In order to effectively, and accurately assess seawater intrusion in coastal area, multidisciplinary data including geophysical, well logging, and hydrogeochemical data should be managed in systematical way. Such systematical management of data is critical key to improve the re-usability of the data as well as the accuracy of the assessment by means of providing a method of synthetic analysis. Therefore, for systematical management of multidisciplinary data in seawater intrusion problem, we have developed a database management system and 3-D visualization interface based on geographic information system in this, study. All geophysical survey, well logging, hydrochemical, as well as drilling, data are classified as attribute data using Microsoft Access, and joined with spatial information based on ArcView. The database management system and 3-D visualization interface to handle these data, also, developed using the script language of ArcView. We think the development of database and 3-D visualization system will improve the efficiency of data management, user-friendliness of data access, and accuracy of data analysis.

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Effect of Cultivation Activity in Daecheong Lake Flood Control Site on Water Quality (대청호 홍수조절지 내 경작활동이 수질에 미치는 영향)

  • Choi, Hyeseon;Jeon, Minsu;Kim, Leehyung
    • Journal of Wetlands Research
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    • v.22 no.1
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    • pp.49-58
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    • 2020
  • The excessive use of fertilizer and compost in agricultural land increases the accumulation of nutrients in soil. The surplus nutrients in soil transported through surface and sub-surface flow can lead to water pollution problems and algal bloom. Moreover, nutrient accumulation and continuous crop cultivation changes the physical structure of the soil, which increases the potential of nutrient. The cultivation in the Daecheong Lake reservoir area may have a direct effect on the lake's water quality due to leaching and releasing of nutrients when water level rises. This research was carried out to analyze the physical and chemical properties of soil in the agricultural areas surrounding Daecheong Dam reservoir to provide basic data available for the establishment of Daecheong Lake water quality management measures. The soil of the Daecheong Lake reservoir was classified as sandy Loam, where surplus nutrients can be transported. Chemical compositions in the soil were found to be significantly affected by use of different fertilizer amounts. Nutrient outflow occurred during spring rainfall events from the rice paddy fields, whereas excess nutrients from summer to fall seasons originated from dry paddy fields. Nutrient outflow from dry paddy fields is mainly from sub-surface flow. Organic agricultural wastes from agricultural land and excessive vegetation inside the river was also evaluated to contribute to the increase in organic matter and nutrients of the river. The results can be used to select the priority management area designation and management techniques in the Daecheong Lake for water quality improvement.