• Title/Summary/Keyword: 유기지화학

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A Study on Effect of Forest Fire on Change of Soil Properties (산화에 의한 토양특성 변화에 관한 연구)

  • Park, Gwan Soo;Lee, Sung Woo
    • Korean Journal of Agricultural Science
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    • v.27 no.2
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    • pp.95-100
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    • 2000
  • This study was carried out to estimate the effect of forest fire on physical and chemical properties of soil. The forest fire was in April 1997 in pinus densiflora dominant forest at Chungju of Chungbuk. After forest fire, dead trees were not cut. Soil samples were collected at 0-5, 5-10, and 10-20cm soil depths in November 1998 from the burned and unburned sites. The analyzed factors were soil organic matter, total N, available P, exchangeable K, Ca, and Mg, and CEC, pH, bulk density, and moisture content. There was no forest floor in burned site, but unburned site has the forest floor of 4cm thick. There were no differences in soil organic matter, total N, available P, exchangeable K, Ca, and Mg, and CEC, pH, bulk density, moisture content in all soil depth, between burned and unburned sites, except in available P in 5-10cm soil depth. Forest fire had not changed the physical and chemical soil properties in this study. However, burning of vegetation and forest floor organic matter may have adverse influence on long-term site productivity.

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The Impact of o-Toluidinyl Structure of 2-Methyl-4-(2-methylphenyldiazenyl)phenyl picolinamide on the AHR Antagonistic Activity (2-Methyl-4-(phenyldiazenyl)phenyl picolinamide의 o-toluidinyl 구조가 AHR 길항저해 활성에 미치는 영향)

  • Lee, Hyosung
    • Journal of the Korea Convergence Society
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    • v.8 no.1
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    • pp.115-121
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    • 2017
  • AHR is a transcription factor activated by aryl hydrocarbons, regulating the expression of XMEs (xenobiotics Metabolizing Enzymes). Even though the role of AHR in human physiology has been intensively investigated for the past decades, our understandings are still largely limited due to the deficiency of adequate chemical agents. In addition, it has been demonstrated that AHR correlates to pathogeneses for some diseases. Furthermore, emerging data suggest that the study on the AHR may provide a valid therapeutic target. Classical antagonists in current use are reported to be partial agonistic whereas a pure antagonist is demanded. In this study, o-toluidinyl ring structure of 2-methyl-4-(2-methylphenyldiazenyl)phenyl picolinamide has been modified into various structures to optimize the AHR antagonistic activity by means of convergence study of organic synthesis and molecular biology.

Correlation analysis between TOC and organic matter indices in influent and effluent of public sewage treatment facilities (공공하수처리시설 유입수 및 방류수에서 TOC와 유기물질 관리지표간의 상관성 분석)

  • Son, Dong-Jin;Jeong, Dong-Hwan;Park, Kyoo-Hong
    • Journal of Convergence for Information Technology
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    • v.11 no.4
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    • pp.122-129
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    • 2021
  • As the total organic carbon (TOC) becomes a new water quality standard as an organic matter (OM) index for public sewage treatment facilities (PSTFs) in Korea from 2021, a comparison study needs to be conducted by examining the correlation between TOC and the existing OM indices (DOC, BOD5, CODMn, CODCr). 500 PSTFs were categorized by process configuration and capacity, and correlation between OM indices in influent and effluent was analyzed. The CODMn/TOC showed higher correlation than other OM indices. This results can be used to basic data for various research associated with TOC.

Holocene sea-level rise and paleoenvironmental changes in Korea Strait shelf (대한해협 대륙붕 해역의 홀로세 해수면 상승과 고환경변화)

  • 남승일;장정해;공기수;김성필;유동근
    • The Korean Journal of Quaternary Research
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    • v.17 no.1
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    • pp.7-16
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    • 2003
  • A 31m-long sediment core (SSDP-102) was taken from the inner shelf (about 40m water-depth) off the northwestern coast of the Korea Strait. Detailed lithofacies and organic-geochemical analyses were performed to establish a high-resolution stratigraphy in the Korea Strait shelf and to reconstruct the paleoenvironmental changes associated with the Holocene marine transgression. The stratigraphic framework of the core was primarily established using 6 AMS $^{14}C$ ages. The sedimentary record of the core SSDP-102 allows for the reconstruction of the paleoenvironmental changes during the last 12.1 ka BP. According to the high-resolution seismic reflection profiles, lithofacies and organic-geochemical data, the core SSDP-102 can be divided into three units (III to I in ascending order) above the acoustic basement. The three units reflect distinct changes of depositional environments resulted from the post-glacial marine transgression. Therefore, it is suggested that three phases of sea-level change have occurred within the inner shelf of the Korea Strait following the Holocene marine transgression. (1) estuarine environments from ca. 12.1 to 6.2 ka BP; (2) near-shore environments with a period of decreased rising of sea level between 6.2 and 5.1 ka BP; (3) near-shore to modem marine environments after 5.1 ka BP. In particular, the present marine conditions influenced by the warm Tsushima Current have been gradually established after ca. 5.1 ka BP.

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Characteristics of Benthic Invertebrates in Organic and Conventional Paddy Field (논 생태계 내 유기농법 재배 지역과 관행농법 재배 지역의 저서무척추동물군집의 특성)

  • Han, Min-Su;Nam, Hyung-Kyu;Kang, Kee-Kyung;Kim, Miran;Na, Young-Eun;Kim, Hye Rim;Kim, Myung-Hyun
    • Korean Journal of Environmental Agriculture
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    • v.32 no.1
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    • pp.17-23
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    • 2013
  • BACKGROUND: Today, environmentally friendly farming has become an important feature of agricultural policy. It promotes or sustains farming systems which protect and enhance the environment. This study was conducted to compare benthic invertebrate communities in an organic and a conventional paddy field in South Korea. METHODS AND RESULTS: Benthic invertebrates were collected at 11 regions of a rice paddy from June to August, 2009, 2010 and 2011. These comparisons undertaken using a community assessment approaches such as the number of individuals and species and community composition. Generally, the larger number of individuals and species of benthic invertebrates was observed in an organic paddy than in a conventional paddy field. Organic paddy fields could supported the wider range of species and abundance in aquatic invertebrates comparing to conventional paddy fields. Carrying capacity to support larger numbers of invertebrates also tends to be higher in organic paddy than in conventional paddy field. Specially, organic farming regions surrounded by forests were high quality habitat for benthic invertebrates than other surrounded regions such as grassland. CONCLUSION(S): We concluded that organic farming was more advantaged to benthic invertebrates than conventional farming. In order to improve biodiversity in rice paddy field, farming regimes without agricultural chemicals are recommended. The effect of organic management on biodiversity and abundance of benthic invertebrates could be maximized across highland farmland.

Measurements of HCHO during ozone intensive study in Seoul, 2001 (2001년 서울시 오존 집중 측정 시기 HCHO의 측정)

  • 홍상범;김규수;이재훈
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.319-320
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    • 2002
  • 포름알데하이드(HCHO)는 보건학적인 영향과 광화학 스모그 형성과정의 중요한 역할로 인해 많은 연구의 대상이 되어왔다. 포름알데하이드(HCHO)의 도심지 대기 환경에서 가장 중요한 인위적인 발생원은 산업활동 및 자동차의 배기가스이며 식물의 연소과정(biomass burning)에서도 방출되는 것으로 알려져 있다. 또한 대기환경에 존재하는 휘발성 유기화합물들과 OHㆍ과의 광 화학적 산화과정을 통하여 2차적으로 형성된다. 한편, 주요 소멸과정으로는 광분해(photolysis) 과정과 OHㆍ과의 반응이다. (중략)

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Chemical characteristics of Soils Cultivated by the Conventional Farming, Greenhouse Cultivation and Organic Farming and Accumulation of $NO_3^-$ in Chinese Cabbage and Lettuce (관행농법, 시설재배 및 유기농법 재배지 토양의 화학적 특성과 배추, 상추의 $NO_3^-$ 집적량 차이)

  • 손상목;한도희;김영호
    • Korean Journal of Organic Agriculture
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    • v.5 no.1
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    • pp.149-165
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    • 1996
  • In order to get some basic datas on environmental friendly funtion against soil and water pollution and safe vegetable production by organic farming, chemical characteristics of soils cultivated by the conventional farming, greengouse cultivation and organic farming and acumulation of NO3--N in chinese cabbage and lettuce were analysed. The highest value of NO3--N in 0-30cm subsoil of organic farming was found among the 3 different farming systems, and it was 3.6 and 6.6 times higher than those of conventional farming in chinese cabbage and lettuce respectively. P2O5 also show high accumulation in the rhizosphere of organic farming compared to convnetional farming. The accumulation of NO3--N and P2O5 in the rhizosphere of organic farming were simial to those of greenhouse cultivation. The NO3- accumulation in chinese cabbage and lettuce by organic farming reach 3224ppm in chinese cabbage and 2543ppm in lettuce and it were 4.7 and 6.4 times higher than those of convnetional farming. It is urgently necessary to introduce the basic standard of IFOAM, EU and FAO/WHO Codex on organic agriculture into korean organic agriculture for operation of environmental friendly system and production of safe vegetable in terms of NO3-.

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Cultivation Environment in Relation to Good Agricultural Practices in the Major Cultivation Area of Disocorea batatas (우리나라 주요 산약 재배지 GAP와 관련된 재배환경 실태)

  • Cho, Jae-Young
    • Journal of Applied Biological Chemistry
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    • v.54 no.4
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    • pp.290-295
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    • 2011
  • This study was carried out to investigate the quality of soil, irrigation water, and status of agrochemicals application in relation to good agriculture practices system in the major cultivation area of Disocorea batatas. The concentrations of heavy metals as Cd, Pb, Cu, and Zn in soils and irrigation waters were lower than those of standard level for Environmental Conservation Act of Soil and Water in Korea. The dominant weed have been appeared Digitaria sanguinalis and Portulaca oleraceamite. The dominant insect pests and plant pathogens have been appeared aphid and anthracnose. Average yearly application of pesticide was 2 to 4 times for herbicide and 4 to 6 times for plant pathogens and insect pests. In order to safety production of medicinal crops could be achieved by proper cultivation management such as minimum application of agro-chemicals, effective use of by-product fertilizer, and technology development of organic farming.

Composting Methods for Pig Sludge and the Stabilized Investigation of Crop Cultivation (돈분의 자원화 퇴비 제조 방법 및 작물 재배 안전성 검정)

  • Oh, Tae-Seok;Kim, Chang-Ho
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.29 no.1
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    • pp.51-62
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    • 2009
  • This study was carried out development a new composting system to lower copper and zinc concentration in plg sludge compost and conduct an inquiry into the possibility of crop cultivation. The concentrations of nitrogen, phosphorus and pH averaged 4.4%, 6.3% and 7.57, respectively, which were higher concentrations than in commercial organic fertilizers, and the concentrations of copper and zinc averaged 805 and 1,704 mg/kg, respectively, which were beyond the heavy metal concentration limit in byproduct compost. Hydrated citric acid I lowered the concentrations of copper and zinc by 58% and 97%, respectively and hydrated oxalic acid II lowered the concentrations of copper and zinc by 48% and 56%, respectively in pig sludge compost. Lower concentrations of copper and zinc in pig sludge resulted from the enhanced hydrated-citric acid concentration in organic acid solution mixed with distilled water. The concentrations of copper and zinc were 330, and 41 mg/kg in the pig sludge treated with 100% hydrated citric acid. Agitation composting system stabilized the compost earlier than the stationary composting system, in which the stabilization condition was confirmed by higher temperature by $4^{\circ}C$ at highest temperature and 7 days earlier cooling down after highest temperature. The levels of germination index (G.I) 80 were obtained 15 and 20 days after composting in agitation and stationary composting system, respectively. The concentrations of copper and zinc were 2.4 and 4.26 mg/kg respectively in soils amended with pig sludge compost after removing process of heavy metals by citric acid, but 8.0 and 22.37 mg/kg, respectively in soils amended with Pig Sludge. The concentrations of heavy metals was highest in com cultivated in soils amended with pig sludge. The copper and zinc concentrations In corn leaves were 75.2 and 50.56 mg/kg respectively, which were 4 and 2 fold higher than the com cultivated in soils amended with pig sludge compost after heavy metal removing process by hydrated citric acid.

Organic Chemical Characteristics and Its Paleoceanographic Implications of the Holocene Sediments on the Continental Shelves Off the Southern Coast of Korea (남해 대륙붕 홀로세 퇴적물의 유기지화학적 특성과 고해양학적 의미)

  • Kong, Gee-Soo;Han, Hyun-Chul;Kim, Seong-Pil;Kim, Ji-Hun;Stott, Lowell
    • Economic and Environmental Geology
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    • v.42 no.2
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    • pp.107-120
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    • 2009
  • Spacial variation in organic components and temporal variation in the origin was examined through the organic geochemical (TC, TN, TS, $CaCO_3$, TOC, C/N, and $\delta^{13}C$) and pyrolysis analysis (HI, OI, and Tmax) in the core sediments which were acquired in the continental shelf of the South Sea close to Seomjin River. Levels of TC, TN, and TS show relatively low and constant in the core SJ03 located close to the Seomjin River mouth, while those are increased a little with being varied with low amplitude in the core SJ02 and SJ04 acquired at the middle of inner shelf area. They fluctuated with high amplitude in the core SJ01 and SJ05 near to the outer boundary of inner shelf. The vertical characteristics of organic components in the core SJ01 acquired at the outer boundary show that the area has undergone distinctly the environmental change at 9.0 kyr B.P. After 9.0 kyr B.P., Levels of TC, TOC, TN, $CaCO_3$, $\delta^{13}C$, HI, and Tmax are rapidly increased, while C/N and or are significantly decreased. Even though the contents of organic components are not high, such a changes reflect that the terrigenous organic matters were predominant before 9.0 kyr B.P due to the influence of Seomjin River, but after then, the marine organic matters have dominated due to the inflow of the Tshusima current.