• Title/Summary/Keyword: 유기용매

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Supercritical $CO_2$ Extraction of Genistein from Soybean (초임계 $CO_2$를 이용한 대두 Genistein의 추출)

  • Bu, Seong-Jun;Byeon, Sang-Yo
    • KSBB Journal
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    • v.14 no.4
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    • pp.490-494
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    • 1999
  • This study was carried out to examine some factors affecting the supercritical carbon dioxide extraction of genistein from soybean. The factors investigated in this study were pressure, temperature, flow rate of carbon dioxide, and concentration of modifier. It was foumd out that genistein is not extracted in the absence of modifier. Ethanol was found to be more effective modifier than methanol. 70% of genistein was extracted at 35$^{\circ}C$, 300bar and ethanol 15% (w/v) as compared with the performances of organic solvent extraction.

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Comparison of Toxic Response of Cladocerans to Organic Solvents to Establish the Standard Test Guidelines Using Korean Native Species (한국산 물벼룩 표준생태독성시험법 확립을 위한 10종 용매대조물질에 대한 독성반응 비교)

  • Kim, Byung-Seok;Park, Yoen-Ki;Yang, Yu-Jung;Hong, Soon-Sung;Park, Kyung-Hun;Jeong, Mi-Hye;Kim, Se-Ri;Park, Kyeong-Hun;Yeh, Wan-Hae;Kim, Doo-Ho;Yun, Jong-Chul;Hong, Moo-Ki;Kyung, Kee-Sung;Ahn, Young-Joon
    • The Korean Journal of Pesticide Science
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    • v.14 no.1
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    • pp.10-15
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    • 2010
  • Most pesticides are poorly soluble in water and must be dissolved in a solvent carrier before being added to the test medium on aquatic toxicity test. The concentration of solvent is critical to the success of a test. This study were conducted to recommend possible organic solvents which have good solubility for pesticides and low toxicity to Korean native water flea to establish new standard toxicity test methods using Korean native water flea for ecological risk assessment of pesticide. Four Korean freshwater cladocerans, Daphnia obtusa, Daphnia sp., Moina macrocopa and Simocephalus vetulus were exposed to 10 different organic solvents during 48 hours to evaluate their toxic response to solvents. Ethyl acetate was the most toxic to cladocerans tested. Although ethyl ether was the least toxic to cladocerans tested, it may not adequate as possible solvent in aquatic toxicity test due to high volatility and low water solubility. In conclusion, acetone, methanol, ethanol and acetonitrile which has low toxicity as well as good water solubility are recommended as optimal organic solvent to use in aquatic toxicity tests with Korean native cladocerans tested.

Synthesis and Characteristics of Organic Soluble Polyaniline by Emulsion Polymerization (유화 중합법에 의한 유기 용매 가용형 폴리아닐린의 합성 및 그 특성)

  • 김진열;권시중;한성원;김응렬
    • Polymer(Korea)
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    • v.27 no.6
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    • pp.549-554
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    • 2003
  • Emeraldine salt of polyaniline-dodecylbenzenesulfdnic acid (PANI-DBSA) in organic solvents such as toluene and xylene was obtained by a direct one-step emulsion polymerization technique. When the molar ratio of DBSA to aniline monomer was 1.5:1, its solubility and electric property showed a maximum value and then the solid contents of PANI-DBSA was 8 wt% in toluene. The cast film of PANI-DBSA with no binder was obtained on glass or plastic substrates under ambient conditions. PANI solution can be also easily blended with polyurethane and polystyrene polymers in toluene. Improved electrical performance up to 5 S/cm was achieved with good light-transmittance up to 70% at 500 m thickness. They also showed more homogeneous morphology than that prepared with PANI-DBSA kom aqueous dispersion polymerization. The partially dispersed PANI-DBSA showed particles sizes of 50-400 m in organic solvents and their XRD pattern were observed from the powder sample.

Simultaneous Determination of Various Pesticides (I): Analysis by GC with ECD and NPD Dual Detectors (잔류농약 다성분 동시분석법에 관한 연구(I): GC-ECD 및 NPD를 병렬 사용한 분석)

  • Rho, Kyoung-Ah;Kim, Jin-Ho;Kim, Hyeon-Wee;Lee, Yoon-Kyoung;Park, Ki-Moon
    • Korean Journal of Food Science and Technology
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    • v.29 no.3
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    • pp.427-431
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    • 1997
  • A simultaneous and rapid gas chromatographic determination of organophosphorus, organo-chlorine, carbamate, and pyrethroid pesticides in polished rice was developed. The pesticides were extracted from samples with acetone by automated soxhlet apparatus and this extract was evaporated to dryness. The residue was dissolved in hexane, the solvent was applied to a Sep-Pak florisil catridge, was eluted with 50% ethyl acetate in n-hexane, and was injected to dual GC-ECD/NPD system. This simple method affords a high recovery of hydrophilic pesticides, allows rapid analysis, and is cheap to perform. Except for dichlorvos and captan, recoveries of 46 pesticides were over 60%.

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Solvent Extraction of Tanshinone IIA from Salvia Miltiorrhiza Bunge (Salvia Miltiorrhiza Bunge로부터 Tanshinone IIA의 용매추출)

  • Wan, Xiaolong;Jung, Yong An;Row, Kyung Ho
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.660-664
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    • 2008
  • In this work, analytical HPLC was utilized to obtain Tanshinone IIA (TIIA) from Salvia Miltiorrhiza Bunge (SMB). The optimum operating conditions were experimentally determined to analyze the TIIA in the pretreated extract. SMB was extracted with the various organic solvents of methanol, ethyl acetate, and ethanol, then the extract was analyzed to compare the amount of TIIA. From the results, the methanol showed the best extraction efficiency of TIIAd. The analysis by $C_{18}$ column was performed. The mobile phase was composed of methanol and water, and the isocratic elution mode was mainly applied. $2.154{\mu}g$ of TIIA/mg of SMB powder was extracted with methanol.